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SEDIMENT PROPERTIES 5.9
However, as a result of Brownian motion, individual clay particles may be very stable
even in quiescent water, and remain dispersed for months. Short-distance van der Waals
forces cause all particles to be attracted to one another and are responsible for the aggre-
gation of clays and other minute particles into flocs large enough to settle at appreciable
velocities. At near-neutral pH values, most particles suspended in water, including clays
and organics, are characterized by negative surface charges. In a neutral suspension, each
particle with a negative surface charge must be surrounded by a cloud of positively
charged ions to achieve electroneutrality. The concentration of the positively charged
particles is greatest at the particle surface and becomes more diffuse as a function of
distance from the particle, giving rise to an electrical double layer around each particle.
Because the charges in the diffuse cloud surrounding the suspended particles are of like
sign, when particles approach one another the like-sign charges in the diffuse double
layer tend to repel each other, thereby impeding the particles from approaching to within
the short distances required for attractive van der Waals forces to dominate.
The facility with which clay particles can combine to form flocs depends on the bal-
ance between the attractive van der Waals and the repulsive electrostatic forces, and one
of the principal mechanisms for destabilization of clays and other colloids is to compress
the double layer thickness by increasing the ionic strength of the solution. The greater the
concentration of ions in the solution, the smaller the thickness of the diffuse layer around
the charged particle necessary to maintain electroneutrality (Fig. 5.8). The use of trivalent
aluminum or iron salts (A1
+3
, Fe
+3
) as coagulants in water filtration plants, and the
destabilization of riverine colloids when discharged into seawater, are two examples of
destabilization by double-layer compression. The rate of destabilization is also a function
of the rate of interparticle collisions resulting from Brownian motion, turbulence, or
differential settling velocities. In quiescent water, floc particles may agglomerate by
differential settling rates, with larger particles sweeping downward, overtaking, and
enmeshing smaller slower-settling particles, causing settling velocity to increase over
time as a result of floc growth. Ultimate floc size is limited by the turbulent shear stress
that tears the larger floc particles apart. Destabilization of clays and other colloids can
also occur as a result of adsorption to produce charge neutralization, enmeshment in a
precipitate, and interparticle bridging caused by certain organic polymers (Amirtharajah
and O'Melia,1990).
Most clays do not exist in aquatic systems as individual platelets, but instead are
flocculated by naturally occurring salts. Coagulation refers to the process of destabilizing
the particles in a solution, and flocculation refers to the process of continued mechanical
contact between particles which enables them to adhere to one another to create larger
particles. Flocculated clay particles can settle several orders of magnitude faster than
individual clay platelets and may exhibit sedimentation velocities characteristic of silts.
Clay flocculation is a common phenomenon and is responsible for the rapid clarification
of most natural waters. The grain size distributions in Fig. 5.4 show two curves for a
single sample corresponding to settling analysis with and without a dispersant to
deflocculate the clay fraction. For sedimentation studies, the grain size distribution for
conditions of natural flocculation would normally be used.
5.3 BULK PROPERTIES OF SEDIMENT
5.3.1 Sediment Density and Weight
The mass density of a solid particle
s
is the mass per unit volume and is expressed in
units of g/cm
3
or kg/m
3
(slugs/ft
3
). The specific weight of solid particles
s
is the weight