
OPHICALCITES
507
origin was proposed: water reached the ultramafic part of an
oceanic crust and transformed it to serpentine resulting in
density inversion and diapiric rise of the serpentinite. Breccia-
tion and carbonatization follow as the serpentine diapir
reaches the ocean floor (Bonatti etal.,
\911).
Rock record of ophiealeite
Paleozoic ophiealeite
In the Canadian Appalachians, ophicalcites have been
reported in Ordovician ophiolitic melanges located along
major terrane-bounding faults (Cousineau, 1991). The
melanges consist of serpentinized ultramafics locally brecciated
and carbonatized (ophicalcites) as well as metasedimentary
and igneous rocks fragments. An oceanic transform-fault
setting has been proposed for the formation of the Ordovician
ophiolitic melange (Cousineau, 1991).
The ophiealeite is a breccia; it is composed of angular,
millimeter- to meter-size, clast- to matrix/cement-supported
carbonatized ultramafic blocks. The ultramafics were first
intensely serpentinized and variably deformed and carbonati-
zation of ultramafic material followed. The degree of
carbonatization ranges from faintly fractured serpentinite with
carbonatized phenocrysts and some micrite infills, up to
intensely brecciated material showing various carbonates with
few preserved indicators of the protolith including chromite
grains and serpentinite minerals. The relative chronology
between the various void fillings is obscured by complex
crosscutting patterns of fractures. In many cases, fractures
with the complete spectrum of sediments and cements (see
below) cut through older ones totally occluded by a similar
succession. Meter-sized fragments of well-cemented ophical-
cites are found in the micrite. All these suggest a complex
history of sedimentation—cementation—fracturing.
Carbonate sediments in the ophiealeite
Besides the pervasive initial metasomatic carbonatization of
brecciated ultramafics, discrete cavity-filling carbonates
are recognized. The most important consists of laminated
micrite interlayered with graded coarser-grained lithic (serpen-
tinite, chromite, mafic minerals) calcarenite. In the most
carbonatized cases, the sediments can constitute up to
50 percent of total carbonates, tn the least altered ultramafics,
it commonly is the only carbonate phase.
Carbonate eements in the ophiealeite
Isopachous layers of calcite cement coat micrite and were
precipitated either over undisturbed infills or on clasts of
indurated ^sediment, suggesting synchroneity with some frac-
turing. Remaining void spaces are healed, as seen under
cathodoluminescence, by multiple generations of blocky
carbonate cements (calcite and minor dolomite). These
cements are volumetrically important in large fractures and
voids that were not totally occluded by the previous
carbonates.
Geoehemistry of earbonate elements
For the Appalachian ophiealeite, the oxygen and carbon stable
isotope ratios of the micrite fall in the range of values for
Ordovician marine carbonates. Based on oxygen stable isotope
and fluid inclusions microthermometry, following cements
were precipitated by hot saline fluids. The carbon isotopic
values for cements indicate marine waters with input of
hydrothermal-derived fluids as also suggested from low radio-
genic strontium isotopic ratios of cements (Lavoie and
Cousineau, 1995; Lavoie, 1997; Chi and Lavoie, 2000).
Proposed origin for Paleozoie ophiealeite
Crosscutting relationships between sediments, cements, and
clasts of cemented ophiealeite together with carbonate
geochemistry provide evidence for complex early seatioor
f'racturing, sedimentation/cementation, and tluid circulation.
For the Paleozoic ophiealeite, a tectonically active seafloor
hydrothermal vent system was proposed to explain the
synchroneity of micrite sedimentation, fracturing, and cemen-
tation (Lavoie and Cousineau, 1995).
The Mesozoie ophiealeites
Detailed studies of Mesozoic ophicalcites have documented a
similar complex pattern of crosscutting relationships between
micrite, carbonate cements, and ophicalcite/ophiolite clasts
altogether with multiple fracturing events. Repetitive micrite
and serpentinite arenite infills coeval with diverse carbonate
cements is documented. Based on these observations and
stable isotope geochemistry, a similar scenario of early
tectonosedimentary origin on the deep seafloor was also
proposed for Jurassic ophicalcites (Friih-Green etat., 1990).
Life on the deep seafloor
Methane-based bacterial chemosynthesis associated with
ophicalcites is reported from the Mesozoic of North America
(Carlson, 1984). Limited biological activity occurred around
the hydrothermal vents responsible for the formation of the
Paleozoic ophiealeite (Lavoie, 1997). Peloidal mats coated
clasts and are followed by bacterially mediated botryoidal
calcite precipitation. Carbon stable isotope ratios of peloidal
mats and botryoidal cements indicate that the exhalatives were
hydrocarbon-free. The lack of corrosion of carbonates
suggests minimal rate of H2S venting and indicates that the
venting system was similar to H2S-poor white smokers.
Thermophilic bacterial sulfate reduction was active around
these Ordovician vents.
Denis Lavoie
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