JONATHAN HORNER
390
during this period, reflecting increasing use of gas rather than coal for heating and further
introductions of smoke control areas. The EC LCP Directive required the UK, taking 1980
as the baseline, to have reduced emissions of SO
2
from LCPs by 20 per cent by the end of
1993, by 40 per cent by the end of 1998 and by 60 per cent by the end of 2003. The latter
target is already close to being attained, with recent reductions having been achieved by
commissioning new gas-burning power stations. However, with natural gas supplies in
relatively short supply it might be difficult to maintain this reduction as the next millennium
progresses.
With declining UK concentrations of smoke and SO
2
, increasing attention has been
paid to other air pollutants. The recent Dobris Assessment, referred to in the previous section
of this chapter, identified four problems in its list of twelve ‘prominent European
environmental problems’ which are specifically caused by atmospheric pollutants. These
are ‘tropospheric O
3
and other photochemical oxidants’, ‘acidification’, ‘climate change’
and ‘stratospheric O
3
depletion’; each will be considered in turn. Other problems identified,
notably ‘urban stress’ caused partly by motor vehicle emissions, ‘major accidents’, ‘forest
degradation’ and ‘chemical risks’ also have atmospheric pollutants as major contributing
causes or as being the cause of resulting effects. There have been increasing episodes of
poor urban air quality, characterised by elevated concentrations of nitrogen oxides (NO
x
),
CO and VOCs, and of tropospheric O
3
formation, both of which are largely caused by
motor vehicle emissions. These pollutants are now more appropriate than black smoke and
SO2 as indicators of air quality. Concentrations of NO and CO shown in Figure 18.2, each
of which is emitted in significant quantities by motor vehicles, have declined to a much
lesser extent between 1980 and 1995 compared with black smoke and SO
2
. During this
period total NO
x
emissions, for which road transport is now responsible for about half of
total emissions, decreased by just 5 per cent. Oxides of nitrogen irritate the respiratory tract
(for example triggering asthma attacks), cause damage to vegetation (reducing crop yields)
and contribute to photochemical smog and acid rain formation. The EC LCP Directive
required the UK to reduce NO
x
emissions from LCPs, taking 1980 as the baseline, by 15 per
cent by 1993 and by 30 per cent by 1998. The latter target had already been achieved by
1995, with a 45 per cent reduction. However, the decrease in emissions from LCPs during
this period was almost matched by an increase in emissions from other sources, notably
road transport.
Carbon monoxide emissions, for which road transport now accounts for about three-
quarters of total emissions, decreased by 21 per cent, and ‘VOC’ emissions, which almost
exactly matched NO
x
emissions, declined by just 3 per cent between 1980 and 1995. Carbon
monoxide emissions are only a health threat in poorly ventilated confined situations, as
reviewed by Horner (1998). This invisible and odourless gas preferentially binds with
haemoglobin in the red blood corpuscles, reducing the amount of oxygen which can be
transported. Road transport accounts for about 30 per cent of total VOC emissions, the
remainder coming from solvent use and industrial processes. VOCs contribute to
photochemical smog formation and some are known carcinogens. The decline in CO and
VOC emissions has been partly due to increasing numbers of diesel cars on the road which
emit less of these pollutants than do petrol-engined vehicles. Increasing use of catalytic
converters on petrol-engined vehicles has also reduced emissions. However, diesel-powered
vehicles have been linked with emissions of carcinogenic organic compounds, so increasing
use of diesel-engined vehicles in the UK should be carefully considered.