Ijb\aZbfh^_ckl\bb_]hk hkgh\gufbhdkb^Zfbb hkgh\Zgbyfbhg
^Z_lkheb
J
2
H
5
0JH 0J
3
JH
4
)
2
;
J
2
H
5
DHG D
3
JH
4
G
2
H
<ukrbc]b^jhdkb^nhknhjZ ²nhknhjgZydbkehlZG
3
JH
4
,
jZkl\hjdhlhjhcijhy\ey_l\k_lbibqgu_k\hckl\Zdbkehl
\aZbfh^_ckl\b_khkgh\Zgbyfbb hkgh\gufbhdkb^Zfb
G
3
JH
4
+ 3NaOH = Na
3
PO
4
G
2
H G
3
JH
4
KD2 KD
3
(PO
4
)
2
↓
G
2
H
Nhknhjh[jZam_le_lmq__kh_^bg_gb_G
3
J ²nhknbg
;OZjZ dl_jbklb dZdZ eby
DZebcbf__lihjy^dh\ucghf_j = b hlghkbl_evgmx
ZlhfgmxfZkkm $
r
(K
Khhl\_lkl\_gghaZjy^y^jZ_]hZlhf Z
jZ\_gqbkemijhlhgh\Ke_^h\Zl_evghqbkehg_cljhgh\\ y^j_
jZ\gh LZddZdZlhfwe_dljhg_cljZe_glhqbkehwe_dljhgh\
kh^_j`Zsboky\Zlhf_dZebylh`_jZ\gh
We_f_gldZebcgZoh^blky\ q_l\_jlhfi_jbh^_i_jbh^bq_kdhc
kbkl_fuagZqbl\k_we_dljhgujZkiheZ]ZxlkygZq_luj _o
wg_j]_lbq_kdbomjh\gyoLZdbfh[jZahfkljh_gb_Zlhf ZdZeby
aZibku\Z_lkylZd
+19
D
Bkoh^ybakljh_gbyZlhfZfh`ghij_^kdZaZlvkl_i_gvhdbke_gby
dZeby\_]hkh_^bg_ gbyoLZddZd\ obfbq_kdboj_ZdpbyoZlhfdZeby
hl^Z_lh^bg\g_rgbcwe_dljhgijhy\eyy\hkklZgh\bl_evgu_
k\hckl\Zke_^h\Zl_evghhgijbh[j_lZ_lkl_i_gvhdbke_gby
<hkklZg h\b l_e vgu _ k\hckl\Z mdZeby \ujZ`_gu kbevg__ q_f m
gZljbyghkeZ[__q_fmjm[b^byqlhk\yaZghk jhklhfjZ^bmkh\hl 1Dd
Rb.
DZebc ²ijhklh_\_s_kl\h^e yg_]hoZjZdl_jgZf_lZeebq_kdZy
djbklZeebq_kdZyj_r_ldZb f_lZeebq_kdZyobfbq_kdZyk\yavZ
hlkx^Z ²b\k_lbibqgu_^eyf_lZeeh\k\hckl\Z
F_lZeebq_kdb_ k\hckl\Z m dZeby \ujZ`_gu kbevg__ q_f m
gZljbyghkeZ[__q_fmjm[b^byldZlhfdZebye_]q_hl^Z_lwe_dljhg
q_fZlhfgZljbyghljm^g__q_fZlhfjm[b^by
F_lZeebq_kdb_k\hckl\ZmdZeby\uj Z`_gukbevg__q_fm
dZevpbyldh^bgwe_dljhgZlhfZdZebye_]q_hlhj\Zlvq_f^\Z
we_dljhgZZlhf ZdZevpby
Hdkb^dZ ebyD
2
H y\ey_lkyhkgh\gufhdkb^hfb ijhy\ey_l\k_
lbibqgu_k\hckl\Zhkgh\guohdkb^h\<aZbfh^_ckl\b_k dbkehlZfb
bdbkehlgufbhdkb^Zfb
D
2
H G&O .&O+
2
O; K
2
O + SO
3
= K
2
SO
4
.