Because the selection of an alloy begins with performance requirements even before formability is considered, this
section offers a brief discussion of alloy effects relative to the performance of copper alloys. When these factors are
matched with the best formability considerations, optimal material selection is attained.
Electrical Conductors. High conductivity is a primary requisite for many conductors, but not all conductors require
high conductivity. Strength and resistance to creep or softening can be traded for some loss of conductivity. Thermal
conductivity goes hand in hand with electrical conductivity and is usually required in all conductors operating in the high-
amperage range.
Terminals and connectors are used in both electronic and electrical applications. Electrical circuits require greater
current-carrying ability than electronic circuits, for which low-to-moderate conductivity will often suffice. Good
formability at the required strength level, well-defined load deflection characteristics, and resistance to stress relaxation
are usually required for both electrical and electronic connectors. Corrosion and stress-corrosion resistance and
solderability are also often demanded.
Other Electronic Applications. The primary electronic application for copper and copper alloys, other than
connectors and printed circuits, is as leadframes for semiconductor devices. Transistors, diodes, and integrated circuits
can be fabricated on a semiconductor chip often less than 5 mm (0.2 in.) square. The chip is bonded to a substrate or
leadframe, which serves both structurally and electrically to connect it to the outside world. Where copper alloys can be
used, the materials requirements are expressed in terms of cost, conductivity, strength, softening resistance, formability,
low-cycle fatigue resistance, and surface characteristics (such as plating, wire bonding, and plastic molding compound
adherence).
Hollow Ware, Flatware, and Decorative Applications. The production of hollow ware products requires
materials with good drawability. In addition, the material must have good solderability, corrosion resistance, sufficient
strength to resist denting during manufacture or use, and good buffing and plating characteristics; most hollow ware
products are silver or gold plated. The least expensive alloys that meet these criteria are the 10 to 30% Zn brasses. The
lower zinc levels are used for multiple-redrawing applications, and the higher zinc levels are for parts demanding higher
strength and/or deep-drawing capability. Copper and phosphorus-deoxidized copper are significantly softer and are
primarily used for decorative applications without plating, where the red color of the metal is considered appealing. They
have adequate drawability for parts that do not require sidewall ironing and a high work-hardening rate. Phosphorus-
deoxidized copper is required where brazing is needed.
Flatware items are generally produced by roll forming. In addition to good formability, flatwork alloys must have good
solderability, corrosion resistance, good buffing and plating characteristics, and low cost. Embossed items use annealed
tempers of materials with sufficiently low work-hardening rates to give faithful reproduction of detailed patterns. Copper-
zinc and copper-nickel-zinc alloys offer the required combination of properties; the zinc content is varied to suit the work
hardening needed. A copper-nickel-zinc alloy that has a silvery color is generally used for silver-plated flatware, and Cu-
30Zn is used for gold-plated flatware to minimize the color contrast between base metal and plate if damage to the plate
occurs.
Heat exchangers require good thermal conductivity, corrosion and stress-corrosion resistance, joinability, and strength
at modest cost. These requirements vary in importance for each application. Copper and copper alloys offer good
combinations of these properties. The two major heat exchanger applications are steam condenser tubing and automotive
radiators.
Condenser tubing must withstand potentially corrosive cooling water as well as the volatile components carried by the
steam, which condense on the tubing. Corrosion requirements are paramount, but strength at elevated temperature and
thermal conductivity are also required.
The copper alloys commonly used in power utility condensers include arsenic-, antimony-, or phosphorus-inhibited
brasses; aluminum bronzes; or copper-nickels, depending on corrosion and stress-corrosion requirements. For automotive
radiators, corrosion resistance, thermal conductivity, and fabricability are the primary requisites. Certain applications
require strength at elevated temperature. Fabricability demands the ability to solder and to braze. Resistance to both
atmospheric corrosion and corrosion by heat-transfer media and their decomposition products is required. Cooling fins are
made of pure copper or high-copper copper alloys.