856
FEET
the atmospheric relative humidity as well
as
the periodic presence of free moisture such
as
rain or dew. Water repellents provide protection against liquid water but are ineffective
against water vapor (humidity). Film-forming finishes such
as
paint and varnish are effec-
tive against water vapor provided the films are thick enough. Because film-forming wood
finishes like paint will last longer on stable wood, it
is
desirable to stabilize the wood by
finishing it with
a
paintable water-repellent preservative
as
the first step in the finish
system.
The protection of wood from moisture through applying
a
finish or coating depends
on
many variables. Among them are the thickness of the coating film, absence of defects
and voids in the film, type of pigment (if any), chemical composition
of
the vehicle or
resin, volume ratio of pigment to vehicle, vapor pressure gradient across the film, and
length of exposure period. Regardless of the number of coatings used, the coating can
never be entirely moisture proof. In the absence of wetting by liquid water, the moisture
content
of
the wood depends on the ambient relative humidity. How quickly the wood
achieves equilibrium with the ambient relative humidity depends on the properties of the
coating. There is no way to eliminate completely the changing moisture content of wood
in response to changing relative humidities. The coating simply slows down the rate at
which the wood changes moisture content.
Film-forming finishes slow both the absorption of water vapor and the drying
of
the wood. In fact, the rate of drying is slowed more by the coating, and
in
cyclic high
and low relative humidities, the moisture content
of
the wood increases with time. This
retardation of drying can have a drastic effect
on
the durability of painted wood fully
exposed to the weather. Paint coatings usually crack at the joint between two pieces of
wood, particularly
if
they have different grain orientations (i.e., different dimensional
stabilities). Water enters the wood through these cracks and is trapped by the coating. The
wood moisture content can quickly reach the range at which decay fungi can prosper.
For a coating to be effective in minimizing moisture content changes of the wood,
it must be applied to all wood surfaces,
prticulurl~~ the
erld
grl1in.
The end grain
of
wood
absorbs moisture much faster than does the face grain, and finishes generally fail
in
this
area first. Coatings having good moisture excluding effectiveness that are applied to only
one side, will cause unequal sorption
of
moisture, increasing the likelihood of wood cup-
ping.
3.1
Natural Weathering
The simplest finish for wood is created by the natural weathering process. Without paint
or treatment of any kind, wood surfaces gradually change
in
color and texture and then
stay almost unaltered for
a
long time if the wood does not decay. Generally, the dark-
colored woods become lighter and the light-colored woods become darker. As weathering
continues. all woods become gray, accompanied by photodegradation and gradual loss of
wood cells at the surface. As a result, exposed unfinished wood will slowly wear away
in a process called erosion (Fig.
4).
The weathering process is
a
surface phenomenon and is
so
slow that most softwoods
erode at
an
average rate of about
!l4
inch per century. Dense hardwoods erode at
a
rate
of
only
!l8
inch per century. Very low density softwoods, such as western redcedar. may
erode at
a
rate as high
as
v'-
inch per century. In cold northern climates, erosion rates as
low
as
!+
inch per century have been reported.