
15.1
Forms of Atmospheric
Energy
493
juxtaposed horizontally (Fig. 15.3). Hydrostatic equilibrium implies a pressure
gradient force directed from the heavier fluid to the lighter one. Motion will
then develop internally to alleviate the mechanical imbalance. The nonrotating
system in Fig. 15.3 accomplishes this by rearranging mass so that heavier fluid
undercuts and eventually comes to rest underneath lighter fluid, so the system's
final state is hydrostatically stable. By lowering the center of gravity of the
system, this process releases potential energy, which is converted into kinetic
energy and eventually dissipated by viscosity to increase the system's internal
energy.
In the atmosphere, horizontal rearrangement of mass is inhibited by ro-
tation, which deflects air motion parallel to isobars (e.g., into the page in
Fig. 15.3). Nevertheless, the pressure gradient along 0 surfaces enables air
motion to develop and, although more complex, to neutralize the mechanical
imbalance. The Coriolis force makes those motions highly rotational, which
favors horizontal mixing (Fig. 12.4). This process is illustrated by interleav-
ing swirls of tropical and polar air in the cyclone off the coast of Africa in
Fig. 1.15. By mixing air horizontally, extratropical cyclones homogenize the
distribution of mass along isentropic surfaces, which drives isobaric surfaces
back into coincidence with isentropic surfaces and restores the thermal struc-
ture to barotropic stratification. Those motions also result in a net poleward
transfer of heat and moisture because air drawn poleward from low latitudes
has greater moist static energy than air drawn equatorward from high lati-
tudes. In making the horizontal mass distribution uniform, air motions lower
the overall center of gravity of the atmosphere. Potential energy is therefore
converted into kinetic energy, which in turn is dissipated by viscosity, converted
into internal energy, and finally rejected to space as heat.
Air motions responsible for this redistribution of mass are fueled by a
conversion of potential energy to kinetic energy. They are termed
baroclinic
instability
because their source of energy is directly related to the baroclinicity
of the stratification. Since temperature then varies along isobaric surfaces,
thermal wind balance implies that those motions are also related to vertical
shear of the flow.
ADIABATIC ADJUSTMENT
The potential energy available for conversion to kinetic energy is reflected
in the departure from barotropic stratification. Consider an adiabatic redis-
tribution of mass from a given baroclinic state. Because air must move along
0 surfaces, horizontal mixing will eventually render the distributions of mass
and pressure uniform over those surfaces, restoring the thermal structure to
barotropic stratification. In that limiting state, the atmosphere has no more
potential energy available for conversion, so ~ = ~min.
The
available potential energy d
(Lorenz, 1955) is defined as the difference
between the total potential energy for the state under consideration and the