
SEDIMENT YIELD FROM WATERSHEDS 7.42
erosion whereas the delivery of deeper soils or parent material can indicate channel
erosion sources.
Properties used for fingerprinting include clay mineralogy, sediment color, sediment
chemistry, mineral magnetic properties, and radionuclide concentrations. The three
radionuclides with the greatest promise for use as indicators are the artificial isotope
137
cesium, and atmospherically derived (i.e., nonnatural or "unsupported")
210
1ead and
7
beryllium isotopes. All are gamma emitters with different fallout histories and decay
rates and have been dispersed at relatively uniform rates over wide geographic areas. On
all, simultaneous nondestructive activity measurements can be made relatively easily by
modern high-resolution gamma spectrometry equipment. Because fallout rate is unrelated
to parent soil material, radionuclide concentration can be used to differentiate between
sediment sources in basins of otherwise homogeneous soils. Fingerprinting techniques
using radionuclides are described by Walling and Woodward (1992).
Fingerprinting techniques were used by Peart and Walling (1986) to analyze sediment
sources in the small 9.3-km
2
Jackmoor Brook watershed in the United Kingdom with
multiple tracers: pyrophosphate iron, dithionite iron, manganese oxide, magnetic
susceptibility, saturation isothermal remanent magnetization (SIRM), total P, total N,
organic carbon, and
137
cesium. Over 100 samples of surface and streambank soils were
collected and the fines (d < 0.06 mm) were separated and analyzed. Suspended sediment
from multiple runoff events was also collected from the stream by pumped sampler,
centrifuged, and analyzed. The values of all tracer parameters except one were higher in
the suspended sediment compared to the soil samples because of enrichment in the fine
fraction. Particle size analysis determined that enrichment was primarily restricted to the
smaller than 0.010 mm fraction. The enrichment factor for this size fraction was about
1.5 for both channel and surface material but was higher for organic material. Following
correction for enrichment, the relative contribution of surface and bank material to the
composite suspended load was determined by using a simple mixing model:
100
bs
br
s
PP
PP
C
(7.8)
where C
s
= percent contribution from surface soil sources, P
r
= value of selected property
for suspended sediment, P
s
= value of selected property for surficial soil, and P
b
= value
of selected property for bank material.
To check the error introduced by enrichment calculations, property ratios were also
analyzed (e.g., carbon/phosphorus). If property ratios from each source are consistent
across all size fractions, this eliminates the need to correct for enrichment computations.
The enrichment computations were generally confirmed.
By further subdividing the soil sample dataset into cropland and permanent pasture, it
was possible to differentiate between these two sources of surface sediment based on
137
cesium activity. Radioactive cesium is tightly sorbed at the soil surface and penetrates
insignificantly into deeper soil layers. Thus, the highest levels of activity corresponded to
topsoil in permanent pasture which had been continuously exposed to fallout,
intermediate levels of activity occurred in arable soils mixed by ploughing, and the
lowest levels were in the deep deposits along channel banks. On the basis of
fingerprinting it was concluded that suspended sediments at the gage station were derived
from the following sources: 6 percent from channel banks, 24 percent from permanent
pasture topsoil, and 70 percent from arable topsoil.
Fingerprinting can potentially be applied to sediments deposited in reservoirs.
However, the reconstruction of stratigraphic histories and application of source tracing or
fingerprinting techniques to reservoir sediment profiles is complicated by the high
variability in sediment deposition patterns. Foster and Charlesworth (1994) analyzed core
data from four small (less than 7-ha pool area) artificial impoundments in the United