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128 4 Amplification of Ionization
Table 4.1 Common quench gases
Methane CH
4
Ethane C
2
H
6
Propane C
3
H
8
Butane C
4
H
10
Pentane C
5
H
12
Isobutane (CH
3
)
2
CHCH
3
Carbon dioxide CO
2
Ethylene (C
2
H
2
)
2
Methylal CH
2
(CH
2
OH)
2
A similar consideration applies also to photons from the avalanche that reach the
conducting surfaces of the cathodes, where they may create free electrons by the
photoelectric effect.
It is because of these far-travelling photons that an organic ‘quench gas’ needs
to be present. Its effect is to reduce q allowing larger values of n
e
, and hence larger
gain. Organic molecules, with their many degrees of freedom, have large photoab-
sorption coefficients over a range of wavelengths that is wider than that for noble
gas atoms. Some examples are given in Fig. 4.3a,b, which also contains a picture of
the most prominent emission lines of the argon. The photoabsorption spectrum of
argon was shown as a graph in Fig. 1.4 in the context of a calculation of particle ion-
ization. Table 4.1 contains a list of common quench gases. Inorganic quench gases
have been studied by Dwurazny, Jelen, and Rulikowska–Zabrebska [DWU 83].
4.2 Beyond the Proportional Mode
If the avalanche amplification is increased beyond the region of proportionality, the
space charge of the positive ions reduces appreciably the field near the head of the
avalanche, that is the field experienced by the electrons between the wire and the
positive cloud. The amplification is smaller for any subsequent increment and we
are in the regime of ‘limited proportionality’.
Near the tail of the avalanche, however, we have an increase of the electric
field owing to the positive ions, especially once the fast-moving electrons have
disappeared into the wire. This situation leads to two different kinds of multiplica-
tive processes, depending on the behaviour of the photons:
• If the UV absorption of the quench gas is very strong, the photons in the
avalanche produce ionization near their creation point, including the region near
the tail of the avalanche where the electric field is particularly large. This starts
the phenomenon of the ‘limited streamer’, which is a backward-moving multipli-
cation process in the sense of a series of avalanches whose starting points move
further and further away from the wire. In a paper by Atac, Tollestrup, and Potter
[ATA 82], it is suggested that energetic photons are created by the recombination
process with cool electrons when the field at the avalanche head is sufficiently