Acetylene (C
2
H
2
) combustion produces a hot, short flame with a bright inner cone at each cutting-tip port; the hottest
point is at the tip of this inner cone. Combustion starts in the inner cone and is brought to completion in a cooler, blue,
outer flame. The sharp distinction between the two flames helps to adjust the ratio of oxygen to acetylene.
Depending on this ratio, the flame may be carburizing (reducing), neutral, or oxidizing. A neutral flame results when just
enough oxygen is supplied for primary combustion, yielding carbon monoxide (CO) and hydrogen (H
2
). These products
then combine with oxygen in ambient air to form the blue, outer flame, yielding carbon dioxide (CO
2
) and water (H
2
O).
The neutral ratio of oxygen to acetylene is about 1 to 1, and the flame temperature at the tip of the inner cone is about
3040 °C (5500 °F). This flame is used for manual cutting.
When the oxygen-to-acetylene ratio is reduced to about 0.9 to 1, a bright streamer begins to appear, and the flame
becomes carburizing, or reducing. A carburizing flame is sometimes used for rough cutting of cast iron.
When the oxygen-to-acetylene ratio is increased to more than 1 to 1, the inner cones are shorter, "necked in" at the sides,
and more sharply defined; this flame is oxidizing. Flame temperature increases until, at a ratio of about 1.7 to 1, the
temperature is maximum, or somewhat over 3095 °C (5600 °F) at the tip of the cones. An oxidizing flame can be used for
preheating at the start of the cut, and for cutting very thick sections.
According to the equation:
2C
2
H
2
+ 5O
2
4CO
2
+ 2H
2
O
an oxygen-to-acetylene ratio of 2.5 to 1 is required for a complete reaction. For complete combustion, however, as much
as 1.5 parts of oxygen is taken from ambient air. In oxyacetylene cutting, part of this oxygen may be supplied from the
cutting oxygen, but total oxygen consumption is relatively low, an advantage of acetylene over all other fuel gases.
Operation of oxyacetylene equipment in confined spaces, such as the inside of a closed tank or vessel, requires forced
ventilation to supply the additional air needed for breathing and for flame combustion.
Acetylene must be used at pressures below 105 kPa (15 psi), which is a stable operating range. Safety codes specify
equipment and handling practices for acetylene. When supplied in special cylinders, acetylene is dissolved in acetone,
which is contained in a porous mass that fills the cylinder. This technique eliminates the sensitivity of acetylene at
pressures over 105 kPa (15 psi). Such cylinders can be filled to pressures exceeding 105 kPa (15 psi), but not greater than
1725 kPa (250 psi). Acetylene may also be supplied from generators. With either means of supply, safety regulations
must be observed to avoid sudden decomposition and explosion.
Despite some disadvantages, acetylene has been used for cutting for a longer time than any other gas. Its performance is
well understood, equipment for it is perfected and widely marketed, and it is readily available. It has become the standard
against which other gases are compared.
Natural gas is a mixture of gases, but consists principally of methane, and therefore is usually given the chemical
symbol for methane (CH
4
). One source defines the most widely used mixture as 85% methane (CH
4
), 4% ethane (C
2
H
6
),
and 11% (N
2
, H
2
, O
2
, H
2
O). Some wells produce natural gas with large proportions of ethane and propane.
The chemical equation for complete combustion:
CH
4
+ 2O
2
CO
2
+ 2H
2
O
indicates an oxygen-to-methane ratio of 2 to 1; this ratio is used for the preheat flame. Maximum flame temperature at the
tip of the inner cones is about 2760 °C (5000 °F). Both higher and lower temperatures have been reported; also, the
optimum oxygen-to-gas ratio is about 2 to 1. The flame is more diffuse than with acetylene; heat intensity is lower; and
adjustment for carburizing, neutral, and oxidizing flame is less clearly defined. Initial cutting speeds are slower, and
oxygen consumption is greater. Also, more time is required for preheating with natural gas than with acetylene. An excess
of oxygen shortens preheat time, but increases consumption of oxygen. Furthermore, natural gas cannot be used for
welding of steel, so extra installations are needed if this operation is to be performed.
Despite these disadvantages, the use of natural gas for cutting has increased. It is the lowest-cost commercial fuel gas and,
with careful torch adjustment, produces excellent cuts in light-to-heavy-gage material.