The Gibbs phenomenon 311
Josiah Willard Gibbs (1 839—1903), American physicist, was pro-
fessor of mathematical physic s at Yale University. Gibbs revo-
lutionized the study of thermodynamics in 1873 by a geometric
approach and then, in 1876, by an article concerning the equilib-
rium properties of mixtures. He had the idea of using diagrams
with temperature–entropy coordinates, where the work duri ng a
cyclic transformation is given by the area of the cycle. It took
a long t ime for chemists to understand the true breadth of this
paper of 1876, which was written in a mathematical spirit. G ibbs
also worked in pure mathematics, in particular i n vector analy-
sis. Finally, his works in statistical mechanics helped provide its
mathematical basis.
11.3
The Gibbs phenomenon
Although the Gibb s phenomenon may be explained purely with the tools
of Fourier series,
5
it is easier to take advantage of t he Fourier transform of
distributions to clar ify things.
Let f be a function, with Fourier transform
e
f (ν) and denote
f
ξ
(x) =
Z
ξ
−ξ
e
f (ν) e
2πiν x
dν
for any ξ > 0. To obtain f
ξ
, the process is therefore:
• decompose f in its spectral components
e
f (ν);
• remove the higher frequencies (those with |ν| > ξ );
• reconstruct a function by summing the low-frequencies part of the spec-
trum, “forgetting” about the higher frequencies (which characterize the
finer details of the f unction).
So we see that the function f
ξ
is a “fuzzy” version of the original func-
tion f . It can be expressed as a convolution, since
f
ξ
= F
−1
Π(ν/2ξ ) ·
e
f (ν)
= f (x) ∗
sin 2πξ x
πx
.
Now recall tha t, in the sense of distributions, we have
lim
ξ→+∞
sin 2πξ x
πx
= δ(x),
5
Using, for instance, the Dirichlet kernel, as in [8].