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ɨɬɜɟɪɫɬɢɹ ɜ ɩɥɟɧɤɟ. Ɍɚɤɢɦ ɦɟɬɨɞɨɦ ɩɨɥɭɱɚɸɬ ɷɥɟɤɬɪɢɱɟɫɤɢɟ ɩɟɪɟɯɨɞɵ
ɩɪɢ ɮɨɪɦɢɪɨɜɚɧɢɢ ɦɧɨɝɨɫɥɨɣɧɵɯ ɤɨɦɦɭɬɚɰɢɨɧɧɵɯ ɩɥɚɬ ɧɚ ɩɨɥɢɢɦɢɞ-
ɧɨɣ ɩɥɟɧɤɟ. ɑɬɨɛɵ ɢɫɩɨɥɶɡɨɜɚɬɶ ɟɟ ɤɚɤ ɩɨɞɥɨɠɤɭ ɞɥɹ ɜɚɤɭɭɦɧɨɝɨ ɧɚɩɵ-
ɥɟɧɢɹ ɬɨɧɤɨɩɥɟɧɨɱɧɵɯ ɩɪɨɜɨɞɧɢɤɨɜɵɯ ɫɥɨɟɜ (ɨɛɵɱɧɨ Cr–ɋɢ), ɧɟɨɛɯɨ-
ɞɢɦɚ ɩɪɟɞɜɚɪɢɬɟɥɶɧɚɹ ɨɛɪɚɛɨɬɤɚ – ɚɤɬɢɜɚɰɢɹ ɩɨɜɟɪɯɧɨɫɬɢ ɫ ɰɟɥɶɸ ɩɪɟ-
ɨɞɨɥɟɧɢɹ ɟɟ ɚɞɝɟɡɢɨɧɧɨɣ ɢɧɟɪɬɧɨɫɬɢ. Ⱥɤɬɢɜɚɰɢɹ ɩɪɟɞɫɬɚɜɥɹɟɬ, ɩɨ ɫɭ-
ɳɟɫɬɜɭ, ɱɚɫɬɢɱɧɭɸ ɞɟɫɬɪɭɤɰɢɸ
ɢɥɢ ɦɨɞɢɮɢɤɚɰɢɸ ɜɧɟɲɧɢɯ ɫɥɨɟɜ ɫ ɨɛ-
ɪɚɡɨɜɚɧɢɟɦ ɧɟɧɚɫɵɳɟɧɧɵɯ ɚɞɫɨɪɛɰɢɨɧɧɨ-ɫɩɨɫɨɛɧɵɯ ɫɜɹɡɟɣ. Ⱦɨɫɬɢɝɚ-
ɟɬɫɹ ɷɬɨ ɜ ɪɟɡɭɥɶɬɚɬɟ ɜɨɡɞɟɣɫɬɜɢɹ ɤɨɧɰɟɧɬɪɢɪɨɜɚɧɧɨɝɨ (ɨɤɨɥɨ 250 ɝ/ɥ)
ɪɚɫɬɜɨɪɚ NaOH ɫ ɞɨɛɚɜɤɨɣ ɠɢɞɤɨɝɨ ɫɬɟɤɥɚ ɩɪɢ 353 Ʉ (80 °ɋ). ȼɨɡɦɨɠɧɚ
ɢ ɚɤɬɢɜɚɰɢɹ ɩɨɜɟɪɯɧɨɫɬɢ ɩɨɥɢɢɦɢɞɚ ɜ ɩɥɚɡɦɟ ɬɥɟɸɳɟɝɨ ɪɚɡɪɹɞɚ ɜ ɚɬɦɨ-
ɫɮɟɪɟ ɤɢɫɥɨɪɨɞɚ, ɨɞɧɚɤɨ ɬɚɤɨɣ ɨɛɪɚɛɨɬɤɢ ɧɟɞɨɫɬɚɬɨɱɧɨ ɞɥɹ ɧɚɞɟɠɧɨɣ
ɦɟɬɚɥɥɢɡɚɰɢɢ, ɨɫɨɛɟɧɧɨ
ɟɫɥɢ ɩɥɚɬɵ ɜ ɩɪɨɰɟɫɫɟ ɞɚɥɶɧɟɣɲɟɣ ɨɛɪɚɛɨɬɤɢ ɢ
ɷɤɫɩɥɭɚɬɚɰɢɢ ɩɨɞɜɟɪɝɚɸɬɫɹ ɢɡɝɢɛɚɦ. ɉɨɥɢɢɦɢɞ ɜɩɨɥɧɟ ɫɬɚɛɢɥɟɧ ɩɪɢ
ɧɚɝɪɟɜɟ ɜ ɜɚɤɭɭɦɟ, ɩɨɷɬɨɦɭ ɟɝɨ ɢɫɩɨɥɶɡɭɸɬ ɤɚɤ ɩɨɞɥɨɠɤɢ ɝɢɛɤɢɯ ɬɨɧ-
ɤɨɩɥɟɧɨɱɧɵɯ ɤɨɦɦɭɬɚɰɢɨɧɧɵɯ ɩɥɚɬ (ɪɟɡɢɫɬɢɜɧɵɟ ɷɥɟɦɟɧɬɵ ɧɚ ɬɚɤɢɯ
ɩɨɞɥɨɠɤɚɯ ɧɟ ɢɡɝɨɬɚɜɥɢɜɚɸɬ). ȼ ɨɬɥɢɱɢɟ ɨɬ ɮɬɨɪɨɩɥɚɫɬɚ ɩɨɥɢɢɦɢɞ
ɩɪɢɝɨɞɟɧ ɢ ɞɥɹ ɦɧɨɝɨɫɥɨɣɧɵɯ ɩɥɚɬ ɛɥɚɝɨɞɚɪɹ ɬɨɦɭ, ɱɬɨ ɩɨɡɜɨɥɹɟɬ ɢɡɝɨ-
ɬɨɜɥɹɬɶ ɩɟɪɟɯɨɞɧɵɟ
ɨɬɜɟɪɫɬɢɹ ɞɢɚɦɟɬɪɨɦ 70–100 ɦɤɦ.
ɉɨɥɢɢɦɢɞ ɹɜɥɹɟɬɫɹ ɫɥɚɛɨɩɨɥɹɪɧɵɦ ɫɪɟɞɧɟɱɚɫɬɨɬɧɵɦ ɦɚɬɟɪɢɚɥɨɦ,
ɩɨɫɤɨɥɶɤɭ ɟɝɨ tg = 0,003. ɉɨɥɢɢɦɢɞ ɨɛɥɚɞɚɟɬ ɩɨɜɵɲɟɧɧɵɦ ɜɥɚɝɨɩɨɝɥɨ-
ɳɟɧɢɟɦ, ɢ, ɜɟɪɨɹɬɧɨ, ɩɨɷɬɨɦɭ ɞɢɷɥɟɤɬɪɢɱɟɫɤɢɟ ɩɨɬɟɪɢ ɭɦɟɧɶɲɚɸɬɫɹ ɫ
ɩɨɜɵɲɟɧɢɟɦ ɬɟɦɩɟɪɚɬɭɪɵ: ɬɚɤ, ɩɪɢ 493 Ʉ ɟɝɨ tg = 0,0006. ɉɨɥɢɢɦɢɞ
ɜɵɩɭɫɤɚɟɬɫɹ ɜ ɪɚɡɥɢɱɧɵɯ ɜɢɞɚɯ:
– ɉɥɟɧɤɚ ɬɨɥɳɢɧɨɣ 8–100 ɦɤɦ, ɜ ɬɨɦ ɱɢɫɥɟ ɮɨɥɶɝɢɪɨɜɚɧɧɚɹ, ɩɪɟɞ-
ɧɚɡɧɚɱɟɧɧɚɹ ɞɥɹ ɝɢɛɤɢɯ ɩɟɱɚɬɧɵɯ ɩɥɚɬ, ɲɥɟɣɮɨɜ ɢ ɩɨɞɥɨɠɟɤ ɬɨɧɤɨɩɥɟ
-
ɧɨɱɧɵɯ Ƚɂɋ.
– Ʌɚɤ ɉȺɄ, ɫɬɨɣɤɢɣ ɩɨɫɥɟ ɜɵɫɵɯɚɧɢɹ ɩɪɢ 470–520 Ʉ, ɨɝɪɚɧɢɱɟɧɧɨ
ɩɪɢ 573 Ʉ, ɤɪɚɬɤɨɜɪɟɦɟɧɧɨ ɩɪɢ 670 Ʉ.
– ɉɪɟɫɫ-ɦɚɬɟɪɢɚɥ ɞɥɹ ɩɨɥɭɱɟɧɢɹ ɢɡɞɟɥɢɣ ɝɨɪɹɱɢɦ ɩɪɟɫɫɨɜɚɧɢɟɦ
ɩɪɢ 590 Ʉ ɢ ɞɚɜɥɟɧɢɢ 100 Ɇɉɚ.
– ɉɟɧɨɩɥɚɫɬ (ɩɟɧɨɩɨɥɢɢɦɢɞ) ɫ ɩɥɨɬɧɨɫɬɶɸ 0,8–2,5 ɝ/ɫɦ
3
, ɩɪɢɦɟ-
ɧɹɸɳɢɣɫɹ ɜ ɤɚɱɟɫɬɜɟ ɬɟɩɥɨ- ɢ ɷɥɟɤɬɪɨɢɡɨɥɹɰɢɨɧɧɨɝɨ ɦɚɬɟɪɢɚɥɚ ɞɥɹ
ɬɟɦɩɟɪɚɬɭɪ 90–520 Ʉ.
– ɋɬɟɤɥɨɩɥɚɫɬɢɤ ɧɚ ɨɫɧɨɜɟ ɩɨɥɢɢɦɢɞɚ, ɫɬɨɣɤɢɣ ɞɨ 670 Ʉ, ɢ ɭɝɥɟ-
ɩɥɚɫɬɢɤ, ɧɟ ɬɟɪɹɸɳɢɣ ɦɟɯɚɧɢɱɟɫɤɨɣ ɩɪɨɱɧɨɫɬɢ ɩɪɢ 550 Ʉ.
– ɂɡɨɥɹɰɢɨɧɧɚɹ ɥɟɧɬɚ, ɫɬɨɣɤɚɹ ɩɪɢ ɬɟɦɩɟɪɚɬɭɪɟ ɞɨ 500 Ʉ.
ɇɟɞɨɫɬɚɬɨɤ ɩɨɥɢɢɦɢɞɚ – ɩɨɜɵɲɟɧɧɨɟ ɜɥɚɝɨɩɨɝɥɨɳɟɧɢɟ (1–3 % ɡɚ
30 ɫɭɬ.), ɩɨɷɬɨɦɭ ɨɧ ɧɭɠɞɚɟɬɫɹ ɜ ɬɟɯɧɨɥɨɝɢɱɟɫɤɨɣ ɫɭɲɤɟ (ɨɫɨɛɟɧɧɨ ɩɪɢ
ɢɡɝɨɬɨɜɥɟɧɢɢ
ɢɡɞɟɥɢɣ ɢɡ ɩɪɟɫɫ-ɩɨɪɨɲɤɨɜ) ɢ ɡɚɳɢɬɟ.