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which becomes conducting at a pressure of
about 50 GPa. Shunting by epoxy biases low
the apparent resistivity. This report prompted a
re-examination of the theoretical arguments
(Stacey and Loper, 2007).
The scattering of electrons by thermal vibra-
tions can be regarded as a response to instanta-
neous deformation or irregularity of a crystal
lattice. This increases with temperature but
decreases with pressure, which reduces the
amplitude of atomic vibration. Thermal disorder
is essentially the same as that causing melting,
and so we expect the effect of scattering on resis-
tivity to be almost constant on the melting curve.
Stacey and Anderson (2001) gave this argument a
mathematical basis, concluding that it implies
constant resistivity on the melting curve.
However, this conclusion can apply only to elec-
tronically simple metals, such as copper, and not
to iron, which has overlapping bands with differ-
ent properties. In a simple metal with a single
conduction band, the number of electrons avail-
able for electrical conduction, those within
about kT of the Fermi level, is proportional to
the density of states at that level. But the proba-
bility of scattering, being proportional to the
number of available states into which an elec-
tron can be scattered, depends on the same num-
ber. Thus, to first order, conductivity does not
depend on the density of states, provided it is
high enough to give metallic conduction, and so
is not materially affected by the increasing
spread of the band by compression. In iron the
4s states, which dominate conduction, are spread
much more than the 3d states and the effective
number of conduction electrons decreases faster
with pressure than the number of states into
which they can be scattered. For this reason, pres-
sure reduces the conductivity of iron more than
it does for metals such as copper, in which all
electrons at the Fermi level are of the same kind.
A calculation by Bukowinsky and Knopoff (1977)
indicated that at four-fold compression the entire
4s band would be above the Fermi level, in which
case the conductivity would be very low, being
due to 3d electrons only, but this is well beyond
the terrestrial pressure range and is relevant only
because it indicates a trend. Stacey and Loper
(2007) made the simple assumption that the 4s
states follow a relationship with the form of
Eq. (19.17), but that the density of 3d states is
much less affected by compression. On this basis
they applied this equation as a multiplying factor
to the resistivity of pure iron, as calculated by
assuming that it is constant on the melting
curve, and obtained 2.72 mO matthetopofthe
outer core and 3.75 mO matthebottom.
The addition of impurity atoms to a solid
metal introduces static irregularities to its lat-
tice, causing an increment in resistivity that
is independent of temperature and, for small
concentrations, proportional to the impurity
concentration. Thus, at atmospheric pressure a
constant impurity contribution to resistivity
becomes a decreasing proportion of the total
as the resistivity increases with temperature. It
is often supposed that the impurity effect can
be neglected at high temperatures. However,
although pressure reduces the thermal effect, it
does not reduce the effect of impurity disorder,
but, as experiments by Bridgman (1957) showed,
increases it. With a sufficient impurity concen-
tration the normal decrease in resistivity with
pressure may be masked, and pressure and
temperature both cause increased resistivity.
Systematic measurements by Bridgman on a
variety of iron alloys at pressures up to 10 GPa
appear still to be the most relevant data that
we have. They show that, for a variety of alloy-
ing elements, the break-even concentration, at
which pressure has no effec t on the resistivity
of iron alloys at constant temperature, is about
14 atomic %. This is comparable to the concen-
tration of light elements required to explain
the core density (Section 2.8), so the effect of
pressure on impurity resistivity in the core is
probably slight, and we adopt the Stacey and
Anderson (2001) v alue, 0.90 mO m.
Adding the impurity effect to the pure iron
resistivity estimated above, we have a t otal
resistivity of 3.62 mO m at the top of the core
and 4.65 mO m at the bottom of the outer core.
Corresponding conductivities are 2.76 10
5
Sm
1
and 2.15 10
5
Sm
1
. For the inner core,
with less impurity resistivity, the estimated con-
ductivity is about 2.7 10
5
Sm
1
. As we note
in Section 19.6, application of Eq. (19.63), with a
small lattice contribution, gives thermal
404 THE GEOMAGNETIC FIELD