448 Radiation Dosimetry: Instrumentation and Methods
markedly for the Mg,Cu,P-doped ones; moreover, they reveal
irreversible radiation damage which invalidates their new uti-
lization after such exposures. In contrast,
6
LiF chips, doped
with Mg,Ti or Mg,Cu, P, do not show such radiation damage
in the fluence-investigated interval.
The different LET dependences of the low- and high-
temperature glow peaks of CaF
2
:Tm thermoluminescent
material (TLD-300) allow the determination of neutron and
gamma dose simultaneously.
To calibrate TLD-300 dosimeters, the individual sen-
sitivities of the two glow peaks to neutrons and photons
are experimentally determined. A calibration method was
proposed by Kriens et al. [26] The response of the
glow peak i to the mixed n-
field relative to its sensitivity
to the
-rays used for calibration is given by:
(10.31)
where of the glow peak
i to neutrons,
relative to its sensitivity to the
-rays used for calibration,
and of the glow peak i to photons in the
mixed n-
field, relative to its sensitivity to the
-rays
used for calibration.
With the assumption that the sensitivities of the TLD-
300 glow peaks to the photons in the mixed n-
field are
equal to their sensitivities to the
-rays used for calibration
, the relative neutron sensitivities of the two
peaks are given by: [26]
(10.32)
Dividing Equation (10.31) by the total dose D
N
D
T
D
yields:
(10.33)
The linear regression of multiple values or
and determines or and or , if and
the ratios are known for multiple measuring con-
ditions. The variation of is performed by three
procedures: different phantom depths, different field sizes,
and additional exposure to
60
Co
rays.
For all calibration methods used, the mean value of the
relative sensitivities of the two TLD-300 glow peaks were
found to be k
i
(0.078 0.029) and k
2
(0.215 0.047)
for fast neutrons, as well as h
1
(1.02 0.36) and h
2
(1.02 0.26) for photons of the mixed n-
beam, comparable
to recent measurement.
The relative neutron responses of both peaks in TLD-
300 chips were found by Hoffmann et al. [27] to be 0.10
and 0.32. Using this method, various dose distributions of
neutron and gamma dose in a water phantom were mea-
sured and compared with the results of GM counter mea-
surements and Monte Carlo dose calculations.
The normalized TLD readings for corresponding gam-
mas and neutrons of the low-and high-temperature glow
peaks should be different according to [27]
(10.34)
(10.35)
where
K kerma ratio CaF
2
/H
2
O 0.27 at 14 MeV.
From these equations, the neutron, gamma, and total dose
distribution are:
(10.36)
(10.37)
(10.38)
where is the sensitivity of the low-temperature peak
and is the sensitivity of the high-temperature peak.
The larger the difference and the higher the
kerma ratio
K, the higher the accuracy of the dose
determination.
The CaF
2
:Tm (TLD-300) material was used as chips
of size 3 mm 3 mm 0.9 mm. Before irradiation, the
chips were annealed at 400C for 1 h. Each dosimeter
was calibrated individually by
60
Co
irradiation at an
exposure level equivalent to 130 mGy (13 rad) in muscle
tissue. [27]
After neutron irradiation, the glow curves show a very
different shape as compared to those induced by
irradiation (see Figures 10.35 and 10.36). Due to the high
LET component, the response of the low-temperature peak
1 is largely reduced, whereas the response of peak 2
remains relatively high. The peak height ratio therefore
reduces from about 3:1 for gammas to 1.1:1 for free-air
neutron irradiations.
The resulting neutron responses can then be derived
from Equations 10.34 and 10.35 to be
R
i
R
i
k
i
D
N
h
i
D
k
i
sensitivity
k
12,
R
12,
D
()
D
N
-------------------------------
R
12,
D
T
-----------
k
12,
h
12,
k
12,
()
D
D
T
------
R
1
D
T
R
2
D
T
D
D
T
k
1
k
2
h
1
h
2
D
T
D
D
D
D
T
P
1N
P
1
P
1
()
Co
60
------------------
D
1
K()D
n
P
2
N
P
2
P
2
()
Co
60
------------------
D
2
K()D
n
D
n
P
2N
P
1N
2
K()
1
K()
-------------------------------------
D
2
K
1
K
----------
P
1N
P
2N
2
K
1
K
----------
1
----------------------------------
D
total
D
n
D
1
2
2
1
()
2
K 0.32
1
K, 0.10
Ch-10.fm Page 448 Friday, November 10, 2000 12:04 PM