
332 CLAUCONY AND VERDINE
Fe2O3 can be incorporated as potassium begins to enter the
smectite structure of glaucony.
Glauconitization typically occurs in submarine, low-energy
conditions, under slow sedimentation rates, within confined
microenvironments at the interface between oxidizing sea-
water and slightly reducing interstitial water. Typical depths
for glauconitization are comprised between
50
m and 500 m,
with temperatures below 15°C. In modern environments,
authigenic glaucony typically develops on the outer margins
of continental shelves and adjacent slope areas. Rapid burial
limits sediment residence time in the appropriate sub-oxic
redox regime, preventing glaucony evolution. The maturity of
glaucony thus reflects mostly the duration of nondeposition
before burial. Present-day forming glaucony is a poorly evolved
(nascent to slightly evolved) glauconitic smectite. Glaucony
can undergo more or less pronounced modifications due to
changes in local subsidence, terrigenous supply, and other
factors, such as availability and abundance of iron, pH/Eh,
and size and composition of substrates.
Despite its importance, the origin of glaucony is not fully
understood and considerable debate exists about both the
nature of the chemical reactions involved and the parameters
that control its development. The major models of glauconi-
tization include the layer lattice theory of Burst (1958) and
Hower (1961), the verdissement theory of Odin and Matter
(1981) and the two-stage evolutionary model of Clauer etal.
(1992).
All these models involve derivation of the constituents
ions from both parent sediment and seawater.
In common usage glaucony is depicted as an autochthonous
constituent of marine sediments. Since the first half of this
century, glaucony has been regarded as one of the most
reliable indicators of low sedimentation rate in marine settings,
and glaucony-bearing horizons have been considered as
diagnostic of transgressions, because of their presence in lower
parts of transgressive/regressive cycles. Glaucony has been
commonly reported from condensed sections (Loutit et ai,
1988),
in association with phosphate grains and abundant
fossils. Glaucony may also occur as a coating and incrusting
film
facies,
associated with hardgrounds or burrowed omission
surfaces.
Despite the widely held concept that the accumulation of
glaucony generally takes place in open-marine environments
and far from zones of active sedimentation, preferably during
long periods of sediment starvation due to relative sea-level
rise (Odin and FuUagar, 1988), glaucony is commonly
encountered within a variety of deposits in the rock record.
Penecontemporaneous remobilization of the green grains by
storms, tidal currents and waves, or reworking caused by
subaerial shelf exposure during relative sea-level fall are likely
to lead to important concentrations of allochthonous glaucony
in a variety of environments poorly suited to glauconitization,
such as nearshore, lagoonal, estuarine, incised-valley and
turbidite systems, and even alluvial plains.
A reliable interpretation of glaucony-bearing deposits thus
requires that spatial distribution, maturity, and genetic
attributes of glaucony be determined. This implies the
evaluation of autochthonous versus allochthonous glaucony,
with a further division of allochthonous glaucony to para-
utochthonous (intrasequential) versus detrital (extrasequen-
tial).
The integration of sedimentological, petrographic and
mineralogical studies provides a comprehensive framework to
differentiate autochthonous from allochthonous glaucony
(Amorosi, 1997). Criteria that might be useful in recognizing
an allochthonous origin of glaucony include: (i) association
with nonmarine deposits; (ii) selective spatial distribution of
grains; (iii) high degree of sorting and roundness; (iv) absence
of fractures in the most evolved samples, since such features
represent zones of weakness that are likely to facilitate
mechanical breakdown of grains in the case of prolonged
transport or reworking.
The distinction between parautochthonous and detrital
glaucony can be sometimes performed by radiometric dating.
More commonly, it requires that compositional attributes of
glaucony be matched against those of putative sources. The
combination of factors that primarily control glaucony
development is unique during each transgressive-regressive
cycle, and glauconies from distinct parent rocks generally have
different maturity and carry unique geochemical and miner-
alogical fingerprints.
Glaucony is a valid tool for the understanding of deposi-
tional cyclicity in the sedimentary record (Amorosi, 1995).
Stratigraphically condensed intervals, interpreted to have
formed during prolonged breaks in sediment accumulation at
sequence scale, may include up to 90 percent autochthonous
glaucony. Within these condensed sections, glaucony abun-
dance may show rhythmic fluctuations, with maximum
concentration near the base of each cycle and a systematic
upward decrease. In these instances, the burrowed, glaucony-
rich cycle boundaries correspond to marine flooding surfaces,
and the vertically stacked cycles reflect short term sea-level
fluctuations, at the scale of parasequences or parasequence sets
(Amorosi and Centineo, 2000). Although autochthonous
glaucony is most commonly associated with condensed
sections and marks the major marine flooding surfaces within
the transgressive systems tract, the green grains may be present
at any site of the third-order depositional sequence. Para-
utochthonous glaucony can be widespread throughout the
sequence, generally showing lower concentration and maturity
than its autochthonous counterpart. Detrital glaucony is
present mainly within falling-stage and lowstand deposits, its
concentration and composition depending on the character-
istics of the source horizon.
Radiometric dates of K-rich glauconies have been widely
used to determine the depositional age of sedimentary rocks,
and have provided numerous age constraints for the calibra-
tion of the relative time scale in strata lacking reliable high-
temperature chronometers (Odin, 1982). Although glaucony
supplies 40 percent of the absolute-age database for the
geological time scale of the last 250 million years, radiometric
dating of glaucony often presents large practical limitations,
because glaucony can be affected by tectonics, alteration and
diagenetic effects, and K-poor glauconies and (to some extent)
evolved glaucony are likely to provide apparent ages that are
significantly different from the actual age of glaucony.
Verdine
Verdine is a 1 : 1 layered, trioctahedral, 7A iron-rich silicate,
known for long under the name berthierine, but also referred
to as phyllite V or odinite. In terms of color and morphology,
the verdine facies is similar to and often visually indistinguish-
able from the glaucony facies. Verdine minerals, however,
differ from glauconitic minerals in their mineralogical struc-
ture (major peaks at 7.2A and 14A) and chemical composition
(contain significantly less K2O than glaucony).