9.1 The seasonal cycle of the stratospheric circulation 305
Figure 9.3 shows the daily mean flux of solar radiation incident on the top
of the atmosphere as a function of latitude and time of year. The maximum
insolation occurs at the summer pole, close to the time of the summer solstice.
Around the winter solstice, high polar latitudes receive no sunlight at all.
The most important absorber of ultraviolet radiation in the stratosphere is
ozone, the triatomic form of oxygen. Ozone has a maximum partial pressure
at around
25
km and a maximum mixing ratio at around
50
km.
It is an
extremely effective absorber of ultraviolet radiation with wavelengths of less
than
300
nm.
Thus the maximum heating rates, of up to
12
K day"
1
, occur
near the top of the ozone layer, at around
50
km.
It is this pattern of heating
which effectively determines the gross features of the vertical temperature
profile of the atmosphere, with stable stratification from the tropopause
to the stratopause at about
60
km,
and rather less stable stratification in
the mesosphere. The atmosphere develops strong temperature gradients in
response to this heating, until long wave cooling is sufficient to balance the
heating. Cooling is principally due to carbon dioxide, although both water
vapour and ozone itself have important infrared emission bands which make
large contributions to the cooling. Fig. 9.4 shows heating rates due to
absorption of solar radiation by ozone, and the net heating rates due to all
radiative processes. At the solstices, the heating follows the pattern we might
expect from the distribution of the solar radiation, with heating throughout
the summer hemisphere and intense cooling at high winter latitudes. At the
equinox, the pattern of heating is roughly symmetric about the equator, with
heating in the tropics and cooling at high latitudes in both hemispheres.
Although ozone has such a profound effect on the temperature structure
of the stratosphere, its total concentration is extremely small, amounting to
no more than 1 molecule in 10
5
at its most concentrated. The total volume
of ozone in a column is sometimes stated in terms of the depth of a column
of gas if the total ozone were isolated and compressed into a thin layer
at
100
kPa and
273
K. Typical values range from 2.6 to
4.5
mm,
depending
upon latitude and season. In contrast, the rest of the atmosphere measured
in this way would have a depth of
8
km.
The situation is complicated by the
fact that ozone is a highly variable constituent. The factors influencing its
concentration will be discussed in more detail in Section 9.3.
In the winter, the heating rate is zero at high latitudes, since there is
no incident sunlight. The heating rate builds up as tropical latitudes are
approached. The result is an intense gradient of temperature near the
poleward limit of sunlight at 66° of latitude, with very low temperatures
near the pole. In thermal wind balance with this temperature gradient, the
zonal winds increase with height at high latitudes, and are quite intense