
the boundary of the liquid and the solid. Alfè et al. (2002b) used the
impurities O, S, and Si and assumed concentrations for the core. They
found:
a. A large concentration of oxygen impurities ( 8 mole percent) is in
the outer liquid core and a much smaller concentration ( 0 :3 mole
percent) is in the inner solid core (Alfè et al. , 2002b). These oxygen
concentrations in the inner and outer cores explain the density jump
at the ICB (a solid-liquid core interface) found from seismology.
Silicon and sulfur impurity concentrations, which are almost evenly
distributed between the inner and outer cores, cannot help explai n
the density jump.
b. DT
m
due to impurities ¼700 K (Alfè et al. , 2002a), which
satisfies the seismically determined density jump at the ICB.
Since T
m
of iron at the ICB pressure is 6200 K, the value of
T
m
ðICB Þ¼ 5500 K in the ab initio ap pr oa ch . T hu s, D T
m
=T
m
¼
0 :1129.
To find the temperature depression due to impurities from the thermal
physics approach, we adopt the results of the calculation for DT
m
= T
m
from the ab initio approa ch, e.g., D T
m
= T
m
¼0 : 1129. Since T
m
for
iron at the ICB pressure is 6050 K (Anderson et al. , 2003), we have
D T
m
¼683 K and T
m
ð ICBÞ¼ 5367 K .
We now make the calculation for the value of T
m
of the core at the
CMB pressure (135 GPa). The value of g
l
along the liquidus found
using ab initio methods goes from 1.488 at the CMB to 1.527 at the
ICB, a change of only 3% (Alfè, pers. comm. 2003) . These values
are sufficiently close such that the value of T
m
(CMB) may be calcu-
lated using g ¼ 1: 51 in equation 8, resulting in
T
m
ð CMBÞ¼ T
m
ðICB Þð9903 = 12 166Þ
g
(Eq. 12)
For g ¼ 1 :51 and T
m
ð ICBÞ¼ 5500 K , we find T
m
ð CMBÞ¼ 4112 K
from the ab initio method. For the thermal physics method, we use
equation 12 with g ¼ 1: 51, obtaining T
m
ð CMBÞ¼ 3940 100 K ,
using DT
m
= T
m
¼0 :1129 and T
m
ð ICBÞ¼ 5367 K . In the calcula-
tions, we have implici tly assumed that the values are for the liquidus,
even though the measured properties are for the solidus in the thermal
physics approach. We justify this because at the ICB the measured
g
s
¼ 1: 50, whereas from the ab initio approach the value is
g
l
¼ 1: 53. Thus, g
l
and g
s
have nearly converged. We assume conver-
gence and therefore can use the liquidus properties for the adiabatic
decompression calculation. We assign an error of 100 K to
T
m
(CMB) because of the lack of exact convergence.
The value of thermal conductivity must be found. Since T
m
(CMB)
is higher for the ab initio method and the thermal physics method than
for the K
0
EoS method, the value of k
e
is correspondingly higher.
Equation 10 shows that k
e
is proportional to T, and appropriate values
of k
e
and k are entered in Table C9. The resulting values of Q(CMB) in
Table C9 are found from equation 1. It is seen that the highest value of
Q(CMB), 7.7 TW, is from the ab initio method and the lowest value,
6.2 TW, is from the K
0
EoS method. Midway between the extremes is
the value of Q(CMB) from the thermal physics method, 7 :0 0: 2 TW.
How is one to choose between the three values of Q (CMB) shown
in Table C9 ? First, we note that the three values are fairly close, espe-
cially when one considers the differences in the three methodologies.
Second, all three methods have a history of success, so preferring a
value from one method is somewhat arbitrary. Third, perhaps the best
way to regard these results is that Q(CMB) should lie between a mini-
mum value, 6.2 TW, and a maximum value, 7.7 TW. It is to be noted
that the maximum value, 7.7 TW, is the closest to three recent results
arising from theories of core thermal history. The total power passing
from the core to D
00
was reported as 8.3 TW by Gubbins et al. (2003),
9 TW by Gubbins et al. (2004), and 7.31 TW by Nimmo et al. (2004).
Orson L. Anderson
Bibl iogra phy
Alfè, D., Price, G.D., and Gillan, M.J., 2001. Thermodynamics of hex-
agonal close-packed iron under Earth ’s core conditions. Physical
Review B, 64: 045,123 1 –16, doi:10.1103/PhysRevB.64.0 45,123.
Alfè, D., Gillan, M.J., and Price, G.D., 2002a. Composition and tem-
perature of the Earth ’s core constrained by combining ab initio cal-
culations and seismic data. Earth and Planetary Science Letters ,
195:91–98.
Alfè, D., Gillan, M.J., and Price, G.D., 2002b. Ab initio chemical
potentials of solid and liquid solutions and the chemistry of the
Earth ’ s core. Journal of Chemical Physics , 11 6 : 7127 – 7136.
Alfè, D., Price, G.D., and Gillan, M.J., 2002c. Iron under Earth ’ s core
conditions: Liquid-state thermodynamics and high-pressure melt-
ing curve from ab initio calculations. Physical Review B , 65,
165,118 1 – 11, doi:10.1103/PhysRevB.65.165,118.
Anderson, O.L., 1998. The Grüneisen parameter for iron at outer
core conditions and the resulting conductive heat and power
in the core. Physics of the Earth and Planetary Interiors, 109:
179– 197.
Anderson, O.L., 2002a. The power balance at the core-mantle bound-
ary. Physics of the Earth and Planetary Interiors , 131:1– 17.
Anderson, O.L., 2002b. The three-dimensional phase diagram of iron.
In Dehant, V., Creager, K.C., Karato, S.I., and Zatman, S., (eds.),
Earth ’s Core: Dynamics, Structure, Rotation. vol. 31 of Geody-
namics Series , Washington, DC: American Geophysical Union,
doi: 10.1029/031GD07.
Anderson, O.L., Dubrovinsky, L., Saxena, S.K., and Le Bihan, T., 2001.
Experimental vibrational Grüneisen ratio values for e-iron up to 330
GPa at 300 K. Geophysical Research Letters , 28 : 399– 402.
Anderson, O.L., Isaak, D.G., and Nelson, V.E., 2003. The high-pressure
melting temperature of hexagonal close-packed iron determined
from thermal physics. Journal of Physics and Chemis try of Solids ,
64 : 2125– 2131.
Bi, Y., Tan, H., and Jing, F., 2002. Electrical conductivity of iron under
shock compression up to 200 GPa. Journal of Physics:Condensed
Matter, 14
: 10849– 10854.
Braginsky, S.I., and Robert s, P.H., 1995. Equations governing convec-
tion in Earth ’ s core and the geodynamo. Geophysical and Astro-
physical Fluid Dynamics , 79 :1– 97.
Bridgman, P.W., 1957. Effects of pressure on binary alloys, V and VI.
Proceedings of the American Academy of Arts and Sciences , 84:
131– 216.
Dziewonski , A.M., and Anderson, D.L., 1981. Preliminary reference
Earth model. Physics of the Earth and Planetary Interiors , 25:
297– 356.
Gubbins, D., Alfè, D., Masters, G., Price, G.D., and Gillan, M.J.,
2003. Can the Earth ’s dynamo run on heat alone? Geophysical
Journal International , 155: 609–622.
Gubbins, D., Alfè, D., Masters, G., Price, G.D., and Gillan, M., 2004.
Gross thermodynamics of two-component core convection. Geo-
physical Journal International , 157: 1407 – 1414.
Isaak, D.G., and Anderson, O.L., 2003. Thermal expansivity of
hcp iron at very high pressure and temperature. Physica B, 328:
345– 354.
Joos, G., 1958. Theoretical Physics , 3rd ed. London: Blackie. With the
collaboration of I.M. Freeman, 885 pp.
Labrosse, S., Poirier, J., and Mouël, J.L., 1997. On cooling of the
Earth ’ s core. Physics of the Earth and Planetary Interiors , 99:
1 – 17.
Landau , L.D., and Lifshitz, E.M., 1958. Statistical Physics. London,
UK: Pergamon Press Ltd. Translated from the Russian by E.
Peierls and R. F. Peierls.
Matassov, G., 1977. Electrical conductivity of iron-silicon alloys at high
pressures and the Earth’s core. Technical Report UCRL–52322,
Lawrence Livermore National Laboratory. http://www.llnl.gov/tid/
lof/documents/pdf/176480.pdf.
110 CORE, ADIABATIC GRADIENT