102 Conservation Laws
from which the pressure is found to be
p =−
1
3
τ
ii
+
2
3
µ + λ
∇ · u. (4.38)
Now the diagonal terms of e
ij
in a flow may be unequal. In such a case the stress
tensor τ
ij
can have unequal diagonal terms because of the presence of the term
proportional to µ in equation (4.37). We can therefore take the average of the
diagonal terms of τ and define a mean pressure (as opposed to thermodynamic
pressure p)as
¯p ≡−
1
3
τ
ii
. (4.39)
Substitution into equation (4.38) gives
p −¯p =
2
3
µ + λ
∇ · u. (4.40)
For a completely incompressible fluid we can only define a mechanical or mean
pressure, because there is no equation of state to determine a thermodynamic pressure.
(In fact, the absolute pressure in an incompressible fluid is indeterminate, and only
its gradients can be determined from the equations of motion.) The λ-term in the
constitutive equation (4.37) drops out because e
mm
= ∇ ·u = 0, and no consideration
of equation (4.40) is necessary. For incompressible fluids, the constitutive equation
(4.37) takes the simple form
τ
ij
=−pδ
ij
+ 2µe
ij
(incompressible), (4.41)
where p can only be interpreted as the mean pressure. For a compressible fluid, on
the other hand, a thermodynamic pressure can be defined, and it seems that p and ¯p
can be different. In fact, equation (4.40) relates this difference to the rate of expansion
through the proportionality constant κ = λ + 2µ/3, which is called the coefficient
of bulk viscosity. In principle, κ is a measurable quantity; however, extremely large
values of Dρ/Dt are necessary in order to make any measurement, such as within
shock waves. Moreover, measurements are inconclusive about the nature of κ.For
many applications the Stokes assumption
λ +
2
3
µ = 0, (4.42)
is found to be sufficiently accurate, and can also be supported from the kinetic theory of
monatomic gases. Interesting historical aspects of the Stokes assumption 3λ+2µ = 0
can be found in Truesdell (1952).
To gain additional insight into the distinction between thermodynamic pressure
and the mean of the normal stresses, consider a system inside a cylinder in which a
piston may be moved in or out to do work. The first law of thermodynamics may be
written in general terms as de = dw +dQ =−¯pdv + dQ =−pdv + TdS, where