360 Physical applications of the Fourier transform
of the particle at point r in space and at time t is |ψ( r, t)|
2
. T he function
ψ(·, t) is normalized (in the sense of the L
2
norm) to have norm 1:
for any t ∈ R,
ψ(·, t)
2
2
=
ZZZ
R
3
ψ( r, t)
2
d
3
r = 1.
DEFINITION 13.8 The wave function in position representation is the
square-integrable function thus defined. The vector space H of the wave
functions, with the usual scalar product, is a Hilbert space.
3
DEFINITION 13.9 The position operator along the O x-axis is denoted X ,
and similarly Y and Z are the position operators along the O y- and O z-
axes, where R
def
= (X , Y , Z). The operator X is defined by its action on wave
functions given by
X ψ = ϕ with ϕ(·, t) : r 7−→ x ψ( r, t),
where we write generically r = (x, y, z).
Be careful not to make the (class ical!) mistake of stating tha t ψ and X ψ
are proportional, with proportionality constant equal to x!
It is customary to denote
ψ(t)
the function ψ(·, t), considered as a vector
in the vector space of wave functions.
4
The scalar product of two vectors is
then given by
ψ(t)
ϕ(t)
def
=
ZZZ
ψ( r, t) ϕ( r, t) d
3
r,
(recall the chosen convention for the hermitian product in quantum mechan-
ics: it is linear on the right and semilinear on the left), and the position operator
acts as follows:
X
ψ(t)
=
ϕ(t)
with ϕ( r, t) = x ψ( r, t).
With each vector |ψ〉 is associated a linear form on the space H by means
of the scalar product, which is denoted 〈ψ| ∈ H
∗
. Thus, the notation 〈ϕ|ψ〉
can be interpreted in two (equivalent) ways: as the scalar product of ϕ with ψ
(in the sense of the product in L
2
), or as the action of the linear form 〈ψ| on
the vector |ϕ〉 (see Chapter 14 for a thorough discussion of this notation).
3
Only “physical” wave functions belong to this space. Some useful fu nct ions, such as
monochromatic waves r 7→ e
i k·r
do not; they are the so-called “generalized kets,” whi ch are
discussed in Chapter 14, in particular, in Section 14.2.d.
4
In fact
ψ(t)
is a vector in an abstract Hilbert space H . However, there exists an isometry
between H and H = L
2
(R
3
), that is, the vector
ψ(t)
can be represented by the function
r 7→ ψ( r, t): this is the position representation. B u t, si nce the Fourier transform is itself
an isometry of L
2
(R
3
) into itself, the vector
ψ(t)
may also be represented by the f u nction
p 7→
e
ψ( p, t), which is the Fourier transform of the previous function. This is called the
momentum representation of the wave vector.