Theoretical Aspects of Radiation Dosimetry 41
The formula for the mass collision stopping power for
a heavy charged particle can be written in the form
(2.117)
where is the classical electron radius,
is the electron rest energy, u is the atomic mass unit,
is
the particle velocity in units of the velocity of light, Z
and A are the atomic number and relative atomic mass of
the target atom, and z is the charge number of the projec-
tile. With standard numerical values for the various con-
stants, one finds that has the value 0.307075
MeV cm
2
g
1
.
The quantity L is called the stopping number. The
factors preceding the stopping number take into account
the gross features of the energy-loss process, whereas
L
takes into account the fine details. It is convenient to
express the stopping number as the sum of three terms:
(2.118)
The first term is given by
(2.119)
where
I is the mean excitation energy of the medium, C/Z
is the shell correction, and
/2 is the density-effect cor-
rection. is the largest possible energy loss in a single
collision with a free electron, given by
(2.120)
where m/M is the ratio of the electron mass to the mass
of the incident particle and is the electron rest energy
(0.511 MeV). If the factor in square brackets in Equation
(2.120) is set equal to unity, the maximum energy transfer
for protons is overestimated by only 0.1% at 1 MeV and
0.23% at 1000 MeV. In the non-relativistic limit,
.
The mean excitation energy
I is a quantity independent
of the properties of the projectile and depends only on the
properties of the medium. For the Thomas-Fermi model
of the atom, it is proportional to the atomic number,
, with approximately equal to 10 eV.
For gases, the mean excitation energy can be obtained
from the expression
(2.121)
where
df/dE is the density of optical dipole oscillator
strength per unit excitation energy E above the ground
state. The oscillator strength is proportional to the photo-
absorption cross section, for which abundant experimental
data are available.
For materials in the condensed phase, the analogous
formula for the mean excitation energy is
(2.122)
where
(
) is the complex-valued dielectric response
function and
(2.123)
is the plasma energy (in eV).
e is the charge of the electron,
is the number of electrons per unit volume, and p is
the density.
The selection of stopping power ratios water/air for
clinical electron beams is normally based on the use of
the so-called method, where is the mean
energy of the incident electron beam at the phantom sur-
face and z is the depth of measurement. Stopping power
ratios are determined for monoenergetic electron beams,
usually by means of Monte Carlo calculations, and
provides the link between the clinical electron beam and
the energy of the electrons used for the calculation. In a
sense, provides an approximate indication of the elec-
tron beam quality.
The relationship between the mean electron energy at
the surface of a phantom, , and the depth of the 50%-
absorbed dose in water, , receives special attention.
All dosimetry protocols use the 2.33 approximation;
i.e., .
A detailed analysis of values in terms of relative
depth-dose distributions shows very good agreement at
high energies. However, at lower energies, in the range
most commonly used in radiotherapy with electron beams,
discrepancies in increase with decreasing energy, dif-
ferences being close to 2% at 5 MeV.
Figure 2.17 compares results obtained with the two
Monte Carlo codes, EGS4 and ITS3, showing that,
although depth-dose distributions in water are similar, dis-
crepancies in energy deposition close to the depth of the
maximum yield different estimates of for mono-
energetic beams. [23]
The depth of the effective point of measurement of
the ionization chamber is used to select the stopping power
ratio, at the same depth, of a monoenergetic beam with
energy equal to . In order to verify the validity of the
method, electron beams with energies close
to 10 MeV and with varying energy and angular spread,
which in most cases exceed the conditions existing for
clinical beams, were analyzed. [23]
--
S
col
1
()dEdx()
el
4
r
e
2
mc
2
2
----------------------
1
u
---
Z
A
---
z
2
L
(
r
e
e
2
mc
2
mc
2
4
r
e
2
mc
2
u
L
() L
0
() zL
1
() z
2
L
2
()
L
0
()
1
2
---
2mc
2
2
W
m
1
2
---------------------------
2
I
C
Z
----
2
---
lnln
W
m
2mc
2
2
1
2
------------------
12mM()1
2
()
12
mM()
2
[]
1
mc
2
W
m
2 mv
2
4 mM()T
II
0
I
0
Iln
df
dE
------
Eln E
/
df
dE
------
Ed
0
d
0
Iln
2
p
2
-----------
Im 1
()[]h
()ln
d
0
h
p
4
h
2
e
2
n
e
m()
12
28.816
ZA()
12
S
wair,
E
0
z,() E
0
E
0
E
0
R
5
E
0
2.33 R
50
R
50
R
50
R
100
() R
50
E
0
s
wair,
E
0
z,()
Ch-02.fm Page 41 Friday, November 10, 2000 11:19 AM