Маркин А.Н., Низамов Р.Э. СО2-коррозия нефтепромыслового оборудования

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pnoalrr{ecKyro

no4a.ry

y.qapHofi

KoHueHTpauHI'I

nnru6r'rropa

Koppo3nlt

r rpy6onponog

ocyulecrBJrtlor

c HHrepBaJIoM

'30

c1'r'

106

CO2 - xopposun ueSmenpo tbtcJto1ozo

o6opydoeauu.z

Koraa crpyrrypa ra3o)Kr,rAKosrHoro

noroKa

B Me)r(npoMbrcJroBbx

rpy6onpono4ax u rpy6onponogax, rpaHcnoprnp)rcxlrD(

o6aogHeuuyro

qacruqHo

noAroromeHryo He$rr

nyurroa

c6opa

roBapHbrx nap-

KoB, coorBercrByer

oAHoMy H3

pnc.

2.6, c z, r{ BoAa mleJUrerc, B or-

.qeJrbrryo

Qary,

nau6onee eQQerrumHo 6yryr

pa6omr

BoAopacrBoprr-

uue

l+ru6rmprr

Koppo3uh npn Henpepueuofi no4ave. Henpepunrry+o

noAaqy BoAopacTBoprrMoro

peanelma

Haqr.rHaroT c KoHqeHrpalll,Il.i, npe-

Bbluarcqeii Cup. s 2...2,5

pa:a.

Pacraop c nossruleHHofi rconqerrrpaquefi

BoaopacrBopHMoro rHru6rropa

Koppo3trH noAaror

B lpy6onpoBoA B Te-

rreHr{e

BpeMeHr.r,

KoTOpoe x}.raKosrb npoxo/qm cn Harrarra

Kor

rpy6onpoaoqa.

Ilocne 3Toro noAaqy

pearerrra

cuuxaror

B c,'ryqae

HeBo3MoxHocrH nenpepsreHoft

noAaqu

BoAopacrBopn-

voro uura6r.rropa Koppo3HH cneayer npHMeHflTb nepHoaHqecKyn

no-

4avy

"yaapno

KoHqeHTpaurH nHru6uropa Koppo3Hr..r.

3Aecs

urr

craJIKHBaeMct c cnryaqraefi, ror4a

asr6op

rHna

pearenTa

3aBHcHT

cnoco6a ero

rroAaqu

B Tpy6onpoBoA.

,{eilo

e rorra,

qro

BoAopacrBopl,I-

mrre uuru6uropu Koppo3HH npaKT[qecKH se o6laAalor nocJreAeficr-

BueM H:lr,l o6raaaror HM JrHrrb s va.nofi creneHn. flocreAeficrsHelr uH-

ru6nropa Koppo3[H

HaBbrBaror

ero cnoco6nocrr

npeAorBpaularb [rJrH

3HaqHTeJILHO CHH)t(aTb KOppO3t tO MeTarjtJla B TeqeHHe HeKOTOpOTO Bpe-

MeHn nocJre

roro,

KaK KoHqeHTparIH.fl unrn6uropa Koppo3lrn B Koppo-

:uanofi

cpe4e,

[epBoHaqanbHo

paBIHa'.

bJru npeBbruarcuar Cy.p.,

c'tv-

Her

paanoft

rrynrc.

BoaopacrBopuMrre uHru6nropu Koppo3nH, B ornH-

vre or ue<frepacrBopr.rM;rx r.r

BoAoArrcfleprapyeMbrx, nerKo,4ecop6tt-

pylorct

c rroBepxHocrH MeraflJra

KaK B BoAHyro, TaK H B

yrjreBoaopoa-

ryro

Qa:u,

He coAepxaulue 3TKx

peareHToB

s Heo6xoAlrrttux xoHIIeH-

TpauHJrx. Ilosrouy

aJrr

nepuoAnqecKofi noAaqr,r

"y.4apuofi"

rouqeu-

rpaqr.ru uarrl6rrropa

Koppo3aH B

yKa3aHHbre

rpy6onporoarr

ou4e-

JreHHe

BoAbr B

orAenbHylo

Qa:y)

creryer ficnoJrb3oBarb He BoAopac-

TBopnMbre, a nerfrepacrnopuurre

uurn6rropu Koppo3lrr{. Konn'{ecrso

Nurn6uropa Koppo3I.IH

ua ogny o6pa6orKy

pacct{HTr,IBalor

raK xe,

KaK

npuBeAeHo Bbrue, a fiepr.roAr{vuocrr

o6pa6orok

onpe,qenrrcT

sKcnepr-

MeHTaJTbHO nO

AaHHLIM

MOHr.rTOpt Hfa KOppO3HH.

.{rr

salluru or

sr5npeH}refi Koppo3nl,t

rpy6onpono4on CCH

ne-

pHoaur{ecKyro

nogavy'!,4ap}rofi" xouqeHlpnuhu uurr.r6r.nopoa

roppo-

3ItH npIlMeIUIIor rpafiue

pe4xo,

It JIHITIL B HcKflrcrruTerbHbtx clyqaurx

107

A.H. Mapxu4

P.3.

Husaarce

6oree

ancoKxfi 3arur{rHbtfi

g$SeKT

3Aecb

AocrldraErct

HelrpeprlBHofi

IloAaqefi

peafeHToB,

qro

orMeqeHo

H B

[55].

CCH 6onrnuHcrsa

MecropoxqeHHfi

PoccHH tBJltlorct

pa3BerB-

JreHHbrMu

(lana

"gepero")

AByMfl

Ir 6oree no4r.nrcvenu,s[,rH x fIC

(puc.

4,7)

(pea:rrnar

CCH

He+rego6HBaloqero

npegnprurul 3ana.4-

uofi Cu6upu).

,ft.r

nunolHexnr

rnApoAr.IHaMr4qecrrrx

pacqeroB

napa-

MerpoB

ABrdKeHr.rs

ra3oxr{AKocrHoro

norora no tpy6onpoBo,uaM TaKI,rx

cucreM, a raKxe

a,'rr

Hx aHaJrH3a

c roqKu 3peHut aaqaru rpy6onposo-

AoB

or BrryrpeHHefi noppo:r,ra

[54]

6uro BBeAeHo no]urrue

"nanpan-

renue neSreraroc6opa".

Couacno

[54],

nanpannenne

uerfrera:oc6opa

eto

"cucteua

ne$rera:onponogot runa

"gepeeo"...,

cocroxulal us

HecKoJIbKI{x KycroB,.,,

BbrKr,r,qH6rx JrHHuft or Hrx. . ,, ocHoBHoro

KoJrreK-

ropa..., rryHKra c6opa

(IIC)

H oAHoro

)

racrKa, nplrMllxarctuero

rryunry

c6opa...".

BneAenue

nou.nrr.rx

"Hanpannenue

uetfrera:oc6opa"

6ulo,

6esycloruo, oqeHr,

rrore3Ho

.qnt

npaKTLIKH, oAHaKo

ero onpeAe-

JreHHe,

AaHHoe

[54],

rlMeer

prg

HeAocrarKoB.

Tax, cncreua

ueSrera-

3orrpoBoAoB

(ro

ecm

rpy6onponogon)

ne Mo)Ker cocrotrr, u3

KycroB

(nuerorcx

B Br4ry Kycrlr

crcraxnn),

[ocKon;Ky

oHI.I He tBJrtlorct

rpy-

6onporo4aur,r.

Her onpegerenrul

"ocsonsoro

ro.nrenropa",

u cneaoBa-

TeJrbHo,

HercHo,

rcaxofi rpy6onposoa

cqurarb

"ocllogttttv

KoJUreKTo-

ponr".

,{a.ree

puc.

4.7 BIlAHo,

rITo

AaHHoe

olpeAeneHue

He coBceM

rroaxoAr{T

n cucrelre

rpy6onpoBoAoB

Hsxnefi

qacrn

pucyHKa, TaK KaK

x fIC npalt

rrcator

aBa

)

IacrKa. flosrolry

uu no3BoJrHM

ce6e

5,"rouHr'nn

norurue

"uanpar:renlae

Hetfrera:oc6opa"

u Ha-:oneu eto

"Hanpaueuue

cr4creMbr c6opa

HeQru

uecropor44euu.r"

. Hanpaeteuue

cucmeaw

c6o-

ueQmu ntecmopocrcdeuua

(aa.nee

nanpan:reur're)

3To

cucreMa

KycroB

cKBarIcTH

a rpy6onpono4oB

MecropoxneHrrt,

coeAlantlol{Kx

srr.r Kycrbr

c fIC,

nuerorqar

rpy6onponog

(anu

uecxo.nr,xo

rarr'lx rpy-

6onpono4on),

noarrrcqensufi

rc fIC,

or.nr.ruarouiu{ct

reM,

qro

ABH-

xeHne

ra3oxrrnKocruofi

clrecu no

rpy6onpoao4au

sroft

cucreurl

3aBHCLlr

ABttJKeHHt

railoxl'laKocrnofi

cuecn

no .nlo6rlrra

.qpyruu

rpy-

6onpono4au

MecropoxaeHHt.

flpu

rarou onpeAeJreHHI'I

HanpaBneHnt

craHoBllrct

oqeBH.4HbIM,

qro

CCH

puc.

4.7 uueer

nBa

HanpaB;reHfit

Kycrbr

cKBiDIs.IH

u rpy6onpotogu

repxnefi

vacrrl

pucyHlca,

Kycrbl

cxBarnxH

rpy6onpoaogu

ullxnefi

qacru

pucyHKa. Ecln 6u,

nanpu-

Mep,

Kycr

6un

coegunen

rpy6onponogou

KycroM 31,

aanHaq

CCH

cocror.na 6u

Il3

oAHoro

HarIpaBJIeHIit.

108

CO2 -

rcopposun

ueQmenpovbtctt060?0

o6opydoeouw

PAc.

4.7. CucmeMa

c6opa

Heemu

Heemedo6arcanuleeo

npednpunmun

SanadHoi

Cu^upu

t09

BruereHlle

o CCH

uecropoxreulafi

HanpameHnfi

no3Borter

cBe-

cru

cno)KHyro

3aAarry

3aurHTbI

rnyrpeuuefi

Koppo3HI'I

Tpy6onpoBo-

AoB

Bcefi

cucreMbl

c6opa

grylrl

uJIH

HecKoJIbKI'IM

6olee

npocruu

:a-

Aat{aM,

KoTopble

MoxHo

peurarb

nocJIeAoBaTeJIbHO

ltn[

oaHoBpeMeHHO'

Ho,

orlpeAeJleHuoi

creneuu,

He3aBHcHMo

Apyr

Apyra'

qacrso-

crl,

3aull'trbl

nuyrpeuHefi

Koppo3ut'I

rpy6olposoaos aByx

Ha-

nparreHufi

Mo)IGo

ncnoJlb3ogart

a6colrcrno

pa:Hue unrlt6nropst

Koppo3Hl,l,

I,I

AiD(e

raKHe,

KOTOpsIe

npu coBMecrHoM

npHMeHeHLn

oAHOM

HanpaBJreHHI,I

),XyA[aIO'r

3au]',ITHOe

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apyf

Apyfa'

Ha-

npaBJreHHe,

cBoeMy

cMblcry,

tBrsercs

uunun'ra.nrnoft

crpyKTypHofi

eaunuqefi

cloxuofi

CCH,

xoropyro,

c rot{KH

3peHllt

sauurrr

rpy6o-

nporo4on

CCH

snyrpeHuefi

Koppo3trH'

neo6xoat'tttlo

paccMarpnBarl'

KaK

eauHoe

qe.noe.

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ocHoBHbIX

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3aIl(HTbI

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noAarre

peafeHTa:

npd7tulo

nepeoe

(rnaznoe)

cxeMa

pa3MeI{eHHt

H KOJIHqecrBo

grx

HenpepstsHofi

nonaun

nurn6lnopa

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golxHu

6snl

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cogaars

no,[aepxl{Barb

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rpaqnro

nxru6r.rropa

Koppo3l'lu

HI.rXe

cnP.'

npexae

Bcero

yqacT-

rax

tpy6onponogon:

no4xtlrc.renHux

r rryurry

c6oPa;

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Koropblx

BpeMt

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x Heo6xo-

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4o6u'ry

He{rn

Ha Kycrax

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e) rpaHcnoprupyrourrx

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He$tt;

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repPt.lropH.flx,

HMerculrrx

oxpaHnr'Ifi

craryc;

nepexoaax

rpy6onposo,4ol

qepe:

peKH

BoAoeMLI;

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yqacrKax

rpy6onporogon,

HapyueHl{e

repMerl'IqHocrl'I

Korop6lx

Moxer

HaHecrl'l

3Ha'{tlTerbHblfi

yuep6

ToM

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x<nroHei

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yrpo:y 6e:onacHocrN

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(xenatenbHoe'

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cxeMy

p*""u1"*r*

, *ontu""tuo

,41{

HenpepbloHoi

nogaun

r'trrr.r6nropa

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xeJIareJI;Ho

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raxuu

o6pasou,

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cogAars

no,DnepxltBarb

KoHqeHrpaqnn

rauru6nropa

roppo3HH

Hl,Ixe

MaKCUManbHoM

qucre

yqacrKoB

Tpy6onpono.4on

*ranpaBileHl'lt'

\ecrRyer

mpembe

npaawb'

Koropoe'

roo6qe

roaopr,

npanx-

JIOM

tBrterct,

KOTOpOMy

HeyKocHnTeJIsHO

CJIeAyIOT

BCeX

I l0

C02

xopposun neQmenpoMucnosozo

o6opydoeama

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u o6clyxunarr

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ua-

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BHJIO

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B3DrrA Ka;Kercr,

qro

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npaBHna 3aulnrr,r

rpy6onporo,4on

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6la-

rae noxeraHr.rs

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or npaKrr.rKn.

floeromy

gaqacryo

rexHoJrorn

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ToMy,

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or rlqnpeHuefi

Koppo3ur.r uurn6uropa-

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no oAnofi H3 MeToAHK

[54,

55, 99 ll

ap.],

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flpaeluruoe

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rerro Haftru, ucnonl3yt cpe4crna

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118

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