324 J. A. Sánchez and N. Ortega
mechanical and thermo-physical properties of this material led to the rapid develop-
ment of new alternatives such as brass and coated wires. Mechanical behaviour is
critical during the WEDM process. Axial force is imposed on the wire by the machine
itself to minimise deformations which can affect accuracy; however excessive axial
force may produce wire breakage, and this is why the ultimate tensile strength is con-
sidered a critical property. Tensile strength is 245
N/mm
2
for copper, 900
N/mm
2
for
“hard” brass, and may reach as high as 1,930
N/mm
2
for molybdenum. Of course,
these values depend not only on the material itself, but also on the operations (succes-
sive drawing operations and intermediate heat treatments) which take place during
the manufacturing process. Wires of low ultimate tensile strength may exhibit high
elongation values of well over 20%. These are considered “soft” wires. However,
elongation is much more reduced (below 2%) in “harder” wires. This is especially
important in taper-cutting, particularly when the part angle exceeds 7º. In this case,
a “soft” wire fits the geometry of the guides better, resulting in a more accurate angle.
Better fitting also ensures a higher stiffness of the system, and therefore deformations
induced by the forces exerted by the process will also be smaller.
The explanation is only complete when one looks at the temperatures of melt-
ing and evaporation, properties that depend upon material composition and coat-
ing. A low melting point is associated with the generation of debris from the wire
that facilitates ignition during discharge. A low evaporation temperature ensures
most of the heat generated is transferred to the workpiece, which is associated to
higher process efficiency.
Brass wire was introduced into the market in 1977. Immediately, cutting speed
was accelerated up to values unknown so far: on a 50
mm thick part cutting speed
was dramatically increased from 12
mm
2
/min to 25
mm
2
/min, values still very far
away from current speeds (up to 500
mm
2
/min, as stated in Sect. 9.2.2). The reason
for this improvement is the presence of zinc in the gap. Current basic brass wires
contain 63% copper and 37% zinc. Melting temperature of the latter is 420ºC, well
below 1,080ºC of copper. Zinc evaporates during cutting, because its evaporation
temperature is 1,000ºC. After coming into contact with a cool dielectric, zinc re-
solidifies in the form of debris, favouring ignition in the next discharge. Following
this, higher zinc contents in the wire composition would be beneficial for the proc-
ess. However, the phase-diagram for brass shows that over 40% content of zinc the
α
structure of CuZn37 results in a fragile (
α
+
β
) structure which causes very im-
portant problems in the production process for small wire diameters.
Brass wire can be found in different tensile strengths, from 490
N/mm
2
to
900
N/mm
2
, depending upon the production process. An alternative used in Japan
is the CuZn33Al2. Addition of 2% of Al enables tensile strength increase in wire
of up to 1,200
N/mm
2
.
Due to the above-mentioned impossibility to manufacture high-zinc content
brass, coated wires were developed in the 1970s. The first trials were made using
a zinc coating and copper as a base material, although the low tensile strength and
large dimensional variations forced the industry to move into other alternatives.
The current industrial solution involves using CuZn20 or CuZn30 as a base mate-
rial, coated with 50% Cu and 50% Zn, or even CuZn37 coated with zinc, which