666 Other PDEs of Mathematical Physics
28.2 The Schr¨odinger Equation
Chapter 22 separated the time part of the Schr¨odinger equation from its space
part, and resulted in the following two equations:
∇
2
ψ +
2m
2
[E −V (r)]ψ =0 and
dT
dt
=
iE
T, (28.5)
where E, the energy of the quantum particle, is the constant of separation.
5
We have also used ψ instead of R, because the latter is usually reserved to
denote a function of the radial variable r (or ρ) when separating the variables
of the Laplacian in spherical (or cylindrical) coordinates.
The solution of the time part is easily obtained: It is simply
T (t)=Ae
iEt/
= Ae
iωt
where ω ≡
E
. (28.6)
It is the solution of the first equation in (28.5), the time-independent
time-independent
Schr¨odinger
equation
Schr¨odinger equation that will take up most of our time in this section.
Historical Notes
Erwin Schr¨odinger was a student at Vienna from 1906 and taught there for ten
years from 1910 to 1920 with a break for military service in World War I. While
at Vienna he worked on radioactivity, proving the statistical nature of radioactive
decay. He also made important contributions to the kinetic theory of solids, studying
the dynamics of crystal lattices.
After leaving Vienna in 1920 he was appointed to a professorship in Jena, where
he stayed for a short time. He then moved to Stuttgart, and later to Breslau before
accepting the chair of theoretical physics at Zurich in late 1921. During these years
of changing from one place to another, Schr¨odinger studied physiological optics, in
particular the theory of color vision.
Zurich was to be the place where Schr¨odinger made his most important contribu-
tions. From 1921 he studied atomic structure. In 1924 he began to study quantum
statistics soon after reading de Broglie’s thesis which was to have a major influence
on his thinking.
Schr¨odinger published very important work relating to wave mechanics and the
general theory of relativity in a series of papers in 1926. Wave mechanics, proposed
by Schr¨odinger in these papers, was the second formulation of quantum theory, the
first being matrix mechanics due to Heisenberg. For this work Schr¨odinger was
awarded the Nobel prize in 1933.
Erwin Schr¨odinger
1887–1961
Schr¨odinger went to Berlin in 1927 where he succeeded Planck as the chair of
theoretical physics and he became a colleague of Einstein’s.
Although he was a Catholic, Schr¨odinger decided in 1933 that he couldn’t live
in a country in which the persecution of Jews had become a national policy. He left,
spending time in Britain where he was at the University of Oxford from 1933 until
1936. In 1936 he went to Austria and spent the years 1936–1938 in Graz. However,
the advancing Nazi threat caught up with him again in Austria and he fled again,
this time settling in Dublin, Ireland, in 1939.
5
We used α in place of E in Chapter 22.