
bonding. The resultant density and hardness of the
films is a function of the hydrogen content of the
films and the relative proportion of sp
3
/sp
2
bonding.
Values in the literature are in the range 5–20 GPa.
This compares with the hardness of, for example,
tungsten carbide, WC, at 3 GPa.
Typical lubricants are the perfluoropolyethers, such
as Fomblin, with molecular weights of 2000 and
more. These lubricants have the necessary properties
of thermal and chemical stability, low vapor pressure,
and low surface tension (Bushan 1990). The coating is
at a monolayer thickness and binds to the carbon
overcoat by interactions between end groups in the
linear polymer and the carbon surface. The strong
binding ensures that lubricant remains between the
head slider and the disk where contact occurs and also
that it does not leave the disk when it spins at high
speed. However, some mobility is needed so that areas
from where lubricant is lost can be recovered.
5. Perpendicular Recording Media
The thin-film media discussed so far have in-plane
magnetization and record information in the longi-
tudinal mode. A second mode of recording has been
proposed (Iwasaki and Nakamura 1977) in which the
transitions separate regions magnetized perpendicu-
larly to the film surface. This situation requires a
magnetically uniaxial film in which a strong, perpen-
dicular anisotropy, K
p
, outweighs the demagnetizing
energy, i.e., K
p
4m
0
M
s
2
/2, and supports magnetization
normal to the film. Several types of material have
been investigated, including particulate barium ferrite
films and sputter-deposited crystalline films of cobalt
alloyed with transition metals (Grundy and Ali 1983).
The media investigated mostly so far are cobalt
alloyed with chromium at compositions round
Co
81
Cr
19
(Wright et al. 1985) A well oriented, co-
lumnar or equiaxed microstructure can be obtained
by growth on a variety of substrates; including rigid
substrates, such as glass, and glass coated with f.c.c.
crystalline underlayers and NiFe (the NiFe acts as a
magnetic closure layer) and amorphous underlayers
such as germanium, and flexible substrates such as
polyimide and melinex. The metallic underlayers are
preferentially oriented with a /111S fiber texture,
which encourages heteroepitaxy in the CoCr layer,
whereas the amorphous plastics and germanium pre-
sumably favor the nucleation of the high surface en-
ergy basal planes in the cobalt alloy. The main
advantage of the perpendicular scheme is that, in
principle, the recording transition width is narrower
than for the longitudinal mode and hence higher bit
densities are possible. At the same time, the magnetic
structure is resistant to demagnetization, even at high
packing densities.
There is as yet no perpendicular recording disk
drive on the market. There is no doubt of the potential
of the scheme for very high storage densities. Calcu-
lations (Bertram and Williams 2000) have sugges-
ted that, although acceptable limits for longitudinal
recording may be upgraded to B100 Gbits in
2
(15 Gbits cm
2
), perpendicular recording may support
B500 Gbits in
2
(75 Gbits cm
2
). There have been
problems in developing a fully integrated system,
and the very rapid improvements in longitudinal me-
dia and associated GMR heads are providing strong
competition. However, the great potential of the per-
pendicular mode in resisting demagnetization and
thermal instability is rekindling a great deal of activity
in the development of this technology. It may yet
provide the transitional mode of magnetic storage
between the longitudinal scheme and patterned media.
6. Fabrication
Commercial deposition equipment attempts to re-
produce the precision of laboratory systems and yet
operate with the cost effectiveness and reproducibility
of mass production methods. They usually take one
of two forms. The first is the in-line coater in which
disks are unloaded from a cassette in a load-lock
chamber and progress through a series of in-line
process chambers in which the various layers are
sequentially deposited onto the disk.
In this type of coater, such as the Leybold A400
system (Leybold AG, Hanau, Germany), the indi-
vidual deposition chambers for, say, chromium,
CoCrTa,Pt, and carbon depositions are separated
by individually pumped buffer chambers with nar-
row-aperture slit load locks that allow continuous
passage of the palates loaded with disks between
large rectangular magnetron cathodes. The second
system is the single-station system where most of the
layers are deposited onto the disk from a cluster set of
circular magnetrons. The Balzers CIRCULUS M12
or M14 (Balzers Process Systems, Balzers, Liechten-
stein), have 12 or 14 process stations in a circular
layout (Fig. 3). Each disk progresses round the circle
of magnetrons from the input station to a holding
cassette at the output. Each station is isolated and has
its own pumping and cold trap system, gas supply,
and measurement devices.
In both systems rapid processing demands sputter
deposition at rates greater than 10 nm s
1
, and sub-
strate heating and cooling for the various deposition
regimes. Layers are deposited with little interrup-
tion to avoid contamination and to achieve repro-
ducibility. Uniformity across the disk can in principle
be enhanced by using magnetrons with on-line ad-
justable magnet fields. The base vacuum standard
in both systems is that of conventional high vacuum,
i.e., p10
5
Pa, with partial pressures of o10
4
Pa,
of H
2
O and o5 10
5
Pa of N
2
and O
2
, respec-
tively. Disk production demands, of course, a clean
room environment up to semiconductor fabrication
662
Magnetic Reco rding: Rigid Media, Preparation