112
Chapter 3 The Equations of Change for Isothermal Systems
3C.4 Alternative methods of solving the Couette vis-
cometer problem by use of angular momentum concepts
(Fig. 3.6-1).
(a) By making a shell angular-momentum balance on a thin
shell of thickness Ar, show that
Next insert the appropriate expression for
T,,
in terms of
the gradient of the tangential component of the velocity.
Then solve the resulting differential equation with the
boundary conditions to get Eq. 3.6-29.
(b) Show how to obtain Eq. 3C.4-1 from the equation of
change for angular momentum given in Eq. 3.4-1.
3C.5
Two-phase interfacial boundary conditions. In 52.1,
boundary conditions for solving viscous flow problems were
given. At that point no mention was made of the role of inter-
facial tension. At the interface between two immiscible fluids,
I and 11, the following boundary condition should be used:
This is essentially a momentum balance written for an in-
terfacial element dS with no matter passing through it, and
with no interfacial mass or viscosity. Here n' is the unit
vector normal to dS and pointing into phase I. The quanti-
ties R, and R, are the principal radii of curvature at dS, and
each of these is positive if its center lies in phase I. The sum
(l/R,)
+
(1/R2) can also be expressed as
(V
-
n'). The quan-
tity
u
is the interfacial tension, assumed constant.
(a) Show that, for a spherical droplet of I at rest in a sec-
ond medium 11, Laplace's equation
relates the pressures inside and outside the droplet. Is the
pressure in phase
I
greater than that in phase 11, or the re-
verse? What is the relation between the pressures at a pla-
nar interface?
(b) Show that
Eq.
3C.5-1 leads to the following dimension-
less boundary condition
in which
hV
=
(k
-
ho)/lo is the dimensionless elevation of
dS, and are dimensionless rate-of-deformation ten-
sors, and
I?,
=
R,/lo and
R,
=
R2/lo are dimensionless radii
of curvature. Furthermore
In the above, the zero-subscripted quantities are the scale
factors, valid in both phases. Idenhfy the dimensionless
groups that appear in Eq. 3C.5-3.
(c)
Show how the result in (b) simplifies to Eq. 3.7-36
under the assumptions made in Example 3.7-2.
3D.1
Derivation
of
the equations of change by integral
theorems (Fig. 3D.1).
(a)
A
fluid is flowing through some region of 3-dimensional
space. Select an arbitrary "blob of this fluid-that is, a
region that is bounded by some surface S(t) enclosing a
volume V(t), whose elements move with the local fluid ve-
locity. Apply Newton's second law of motion to this sys-
tem to get
in which the terms on the right account for the surface and
volume forces acting on the system. Apply the Leibniz for-
mula for differentiating an integral (see §A.5), recognizing
that at all points on the surface of the blob, the surface ve-
locity is identical to the fluid velocity. Next apply the
Gauss theorem for a tensor (see 5A.5) so that each term
in
the equation is a volume integral. Since the choice of the
"blob" is arbitrary, all the integral signs may be removed,
and the equation of motion in Eq. 3.2-9 is obtained.
(b) Derive the equation of motion by writing a momen-
tum balance over an arbitrary region of volume
V
and sur-
face
S,
fixed in space, through which a fluid is flowing.
In
doing this, just parallel the derivation given in 53.2 for
a
L.
Landau and
E.
M.
Lifshitz,
Fluid
Mechanics,
Pergamon,
Oxford, 2nd edition (1987),
Eq.
61.13. More general formulas
including the excess density and viscosity have been developed
by
L.
E.
Scriven,
Chern. Eng. Sci.,
12,98-108 (1960).
Fig.
3D.1.
Moving "blob of fluid to which Newton's sec-
ond law of motion is applied. Every element of the fluid
surface dS(t) of the moving, deforming volume element
V(t) moves with the local, instantaneous fluid velocity
v(t).