Bergaya F. Handbook of Clay Science

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Bajt, S., Clark, S.B., Sutton, S.R., Rivers, M.L., Smith, J.V., 1993. Synchrotron X-ray mi-

croprobe determination of chromate content using X-ray absorption near edge structure.

Analytical Chemistry 65, 1800–1804.

Bajt, S., Sutton, S.R., Delaney, J., 1994. X-ray microprobe analysis of iron oxidation states in

silicates and oxides using X-ray absorption near edge structure (XANES). Geochimica et

Cosmochimica Acta 58, 5209–5214.

Bajt, S., Sutton, S.R., Delaney, J., 1995. Microanalysis of iron oxidation states in earth and

planetary materials. Physica B 208, 209, 243–244.

Bargar, J.R., Brown, G.E., Parks, G.A., 1997a. Surface complexation of Pb(II) at oxide/water

interfaces: 1. XAFS and bond-valence determination of mononuclear and polynuclear

Pb(II) sorption products on aluminium oxides. Geochimica et Cosmochimica Acta 61,

2617–2637.

Bargar, J.R., Brown, G.E., Parks, G.A., 1997b. Surface complexation of Pb(II) at oxide/water

interfaces: 2. XAFS and bond-valence determination of mononuclear Pb(II) sorption

products and surface functional groups on iron oxides. Geochimica et Cosmochimica Acta

61, 2639–2652.

Bargar, J.R., Brown, G.E., Parks, G.A., 1998. Surface complexation of Pb(II) at oxide/water

interfaces: 3. XAFS determination of Pb(II) and Pb(II)-chloro adsorption complexes on

goethite and alumina. Geochimica et Cosmochimica Acta 62, 193–207.

Bargar, J.R., Towle, S.N., Brown, G.E., Parks, G.A., 1996. Outer-sphere lead(II) adsorbed at

speciﬁc surface sites on single crystal a-alumina. Geochimica et Cosmochimica Acta 60,

3541–3547.

Bargar, J.R., Trainor, T.P., Fitts, J.P., Chambers, S.A., Brown, G.E., 2004. In-situ grazing

incidence EXAFS study of Pb(II) chemisorption on hematite (0001) and (1-102). Langmuir

20, 1667–1673.

Bedzyk, M.J., Cheng, L., 2002. X-ray standing wave studies of minerals and mineral surfaces:

principles and applications. In: Fenter, P.A., Rivers, M.L., Sturchio, N.C., Sutton, S.R.

(Eds.), Applications of Synchrotron Radiation in Low-Temperature Geochemistry and

Environmental Science. Reviews in Mineralogy and Geochemistry, vol. 49. Mineralogical

Society of America, Washington, DC, pp. 221–266.

Berry, A.J., O’Neill, H.St.C., 2004. A XANES determination of the oxidation state of chro-

mium in silicate glasses. American Mineralogist 89, 790–798.

Berry, A.J., O

Neill, H.St.C., Jayasuriya, K.D., Cambell, S.J., Foran, G.J., 2003. XANES

calibrations for the oxidation state of iron in a silicate glass. American Mineralogist 88,

867–977.

Bertsch, P.M., Hunter, D.B., 2001. Applications of synchrotron-based X-ray microprobes.

Chemical Reviews 101, 1809–1842.

Bianconi, A., 1988. XANES spectroscopy. In: Koningsberger, D.C., Prins, R. (Eds.), X-ray

Absorption: Principles, Applications, Techniques of EXAFS, SEXAFS and XANES.

Wiley, New York, pp. 573–662.

Bianconi, A., Fritsch, E., Calas, G., Petiau, J., 1985. X-ray absorption near-edge structure of

3d transition elements in tetrahedral coordination. The effect of bond length variation.

Physics Reviews B 32, 4292–4295.

Bidoglio, G., Gibson, P.N., O’Gorman, M., Robert, K.J., 1993. X-ray absorption spectros-

copy investigation of surface redox transformations of thallium and chromium on colloidal

mineral oxides. Geochimica et Cosmochimica Acta 57, 2389–2394.

Chapter 12.3: X-ray Absorption Spectroscopy846

Bochatay, L., Persson, P., Lo

vgren, L., Brown, G.E., 1997. XAFS study of Cu(II)

at the water–goethite (a-FeOOH) interface. Journal of Physique IV, France 7, C2,

819–820.

Bonnin, D., Bouat, J., Kaiser, P., Fre

tigny, C., Be

guin, F., 1986. Bond angle determination by

angular EXAFS study and Debye–Waller anisotropy in 2D graphite intercalation com-

pounds. In: Lagarde, P., Rouax, D., Petiau, J. (Eds.), EXAFS and Near Edge Structure IV.

Journal de Physique collogue, C8, 865–868.

Bonnin, D., Calas, G., Suquet, H., Pezerat, H., 1985. Sites occupancy of Fe

in Garﬁeld

nontronite: a spectroscopy study. Physics and Chemistry of Minerals 12, 55–64.

Bottero, J-.Y., Manceau, A., Villie

ras, F., Tchoubar, D., 1994. Structure and mechanism of

nucleation of FeOOH(Cl) polymers. Langmuir 10, 316–319.

Brigatti, M.F., Lugli, C., Cibin, G., Marcelli, A.G.G., Paris, E., Mottana, A., Wu, Z., 2000.

Reduction and sorption of chromium by Fe(II)-bearing phyllosilicates: chemical treatments

and X-ray absorption spectroscopy (XAS) studies. Clays and Clay Minerals 48, 272–281.

Brindley, G.W., Brown, G., 1980. Crystal Structures of Clay Minerals and their X-ray Iden-

tiﬁcation. Mineralogical Society, London.

Brovelli, D., Caseri, W.R., Ha

hner, G., 1999. Self-assembled monolayers of alkylammonium

ions on mica: direct determination of the orientation of the alkyl chains. Journal of Colloid

and Interface Science 216, 418–423.

Brown, G.E., Calas, C., Waychunas, G.A., Petiau, J., 1988. X-ray absorption spectroscopy

and its application in mineralogy and geochemistry. In: Hawthorne, F.C. (Ed.), Spec-

troscopic Methods in Mineralogy and Geology. Reviews in Mineralogy, vol. 18. Miner-

alogical Society of America, Washington, DC, pp. 431–512.

Brown, G.E., Sturchio, N.C., 2002. An overview of synchrotron radiation applications to

low temperature geochemistry and environmental science. In: Fenter, P.A., Rivers,

M.L., Sturchio, N.C., Sutton, S.R. (Eds.), Applications of Synchrotron Radiation in Low-

temperature Geochemistry and Environmental Science. Reviews in Mineralogy and Geo-

chemistry, vol. 49. Mineralogical Society of America, Washington, DC, pp. 1–115.

Bugaev, L.A., Ildefonse, P., Flank, A.-M., Sokolenko, A.P., Dmitrienko, H.V., 1998. Alumi-

num K-XANES spectra in minerals as a source of information on their local atomic

structure. Journal of Physics: Condensed Matter 10, 5463–5473.

Bugaev, L.A., Ildefonse, P., Flank, A.-M., Sokolenko, A.P., Dmitrienko, H.V., 2000. Deter-

mination of interatomic distances and coordination numbers by K-XANES in crystalline

minerals with distorted local structure. Journal of Physics: Condensed Matter 12,

1119–1131.

Bugaev, L.A., Sokolenko, A.P., Dmitrienko, H.V., Flank, A.-M., 2002. Fourier ﬁltration of

XANES as a source of quantitative information of interatomic distances and coordination

numbers in crystalline minerals and amorphous compounds. Physics Reviews B 65, 1–8.

Bujda

k, J., Janek, M., Madejova

, J., Komadel, P., 2001. Methylene blue interactions with

reduced-charge smectites. Clays and Clay Minerals 49, 244–254.

Bujda

k, J., Komadel, P., 1997. Interaction of methylene blue with reduced charge montmo-

rillonite. Journal of Physical Chemistry B 101, 9065–9068.

Bunker, D.J., Jones, M.J., Charnock, J.M., Livens, F.R., Pattrick, R.A.D., Collinson,

D., 2002. EXAFS studies of co-precipitation and adsorption reactions of T

. Proceedings

of the Euroconference and NEA Workshop on Speciation, Techniques, and Facilities for

Radioactive Materials at Synchrotron Light Sources, Grenoble, France, 2000. Nuclear

References 847

Energy Agency/Organisation for Economic Co-operation and Development, AEN/NEA,

Paris, pp. 207–213.

Cabaret, D., Sainctavit, P., Ildefonse, P., Flank, A.-M., 1996. Full multiple-scattering cal-

culations on silicates and oxides at the Al K edge. Journal of Physics: Condensed Matter 8,

3691–3704.

Calas, G., Manceau, A., Combes, J.M., Farges, F., 1990. Application of EXAFS in miner-

alogy. In: Mottana, A., Burragato, F. (Eds.), Absorption Spectroscopy in Mineralogy.

Elsevier, Amsterdam, pp. 171–204.

Calas, G., Petiau, J., 1983. Coordination of iron in oxide glasses through high resolu-

tion K-edge spectra: information from the pre-edge. Solid State Communications 48,

625–629.

Charlet, L., Manceau, A., 1992. X-ray absorption spectroscopy study of the sorption of

Cr(III) at the oxide/water interface. 2. Adsorption, coprecipitation, and surface precipi-

tation on ferric hydrous oxide. Journal of Colloid and Interface Science 148, 443–458.

Charlet, L., Manceau, A., 1993. Structure, formation, and reactivity of hydrous oxide

particles: Insight from X-ray absorption spectroscopy. In: Bufﬂe, J., van Leeuwen, H.P.

(Eds.), Environmental Particles. Environmental Analytical and Physical Chemistry Series,

vol. 2. Lewis Publishers, Boca Raton, FL, pp. 117–164.

Charlet, L., Manceau, A., 1994. Evidence for the neoformation of clays upon sorption of

Co(II) and Ni(II) on silicates. Geochimica et Cosmochimica Acta 58, 2577–2582.

Cheah, S.-F., Brown, G.E., Parks, G.A., 1998. XAFS spectroscopic study of Cu(II) sorption

on amorphous SiO

and g-Al

: effect of substrate and time on sorption complexes.

Journal of Colloid and Interface Science 208, 110–128.

Cheah, S.-F., Brown, G.E., Parks, G.A., 1999. Structure and composition of copper(II)-2,2

bipyridine sorption complexes on amorphous SiO

. Geochimica et Cosmochimica Acta 63,

3229–3246.

Cheah, S.-F., Brown, G.E., Parks, G.A., 2000. XAFS study of copper model compounds and

copper(II) sorption on amorphous SiO

, g-Al

, and anatase. American Mineralogist 85,

118–132.

Chen, C.-C., Hapelis, C., Hayes, K.F., 1998. Extended X-ray absorption ﬁne structure

(EXAFS) analysis of aqueous Sr(II) ion sorption at clay–water interfaces. In: Jenne, E.A.

(Ed.), Adsorption of Metals by Geomedia: Variables, Mechanisms, and Model Applica-

tions. Academic Press, New York, pp. 333–348.

Chen, C.-C., Hayes, K.F., 1999. X-ray absorption spectroscopy investigation of aqueous

Co(II) and Sr(II) sorption at clay–water interfaces. Geochimica et Cosmochimica Acta 63,

3205–3215.

Chisholm-Brause, C.J., Brown, G.E., Parks, G.A., 1989a. EXAFS investigation of aqueous

Co(II) sorbed on oxide surfaces in situ. Physica B 158, 646–648.

Chisholm-Brause, C.J., Brown, G.E., Parkes, G.A., 1991. In situ EXAFS study of changes in

Co(II) sorption complexes on a-Al

with increasing sorption densities. In: Hasnain, S.

(Ed.), XAFS VI, 6th International Conference on X-ray Absorption Fine Structure. Ellis

Horwood, Chichester, pp. 263–265.

Chisholm-Brause, C.J., Conradson, S.D., Buscher, C.T., Eller, P.G., Morris, D.E., 1994.

Speciation of uranyl sorbed at multiple sites on montmorillonite. Geochimica et Cos-

mochimica Acta 58, 3625–3631.

Chapter 12.3: X-ray Absorption Spectroscopy848

Chisholm-Brause, C.J., Hayes, K.F., Roe, A.L., Brown, G.E., Parks, G.A., Leckie, J.O.,

1990b. Spectroscopic investigation of Pb(II) complexes at the g-Al

/water interface.

Geochimica et Cosmochimica Acta 54, 1897–1909.

Chisholm-Brause, C.J., Morris, D.E., Richard, R.E., 1992. Speciation of uranium(VI)

sorption complexes on montmorillonite. In: Arehart, G.B., Hulston, J.R. (Eds.), Proceed-

ings of the 7th International Symposium on Water–Rock Interactions, vol. 1, pp. 137–140.

Chisholm-Brause, C.J., O’Day, P.A., Brown, G.E., Parks, G.A., 1990a. Evidence for mul-

tinuclear metal-ion complexes at solid/water interfaces from X-ray absorption spectros-

copy. Nature 348, 528–531.

Chisholm-Brause, C.J., Roe, A.I., Hayes, K.F., Brown, G.E., Parks, G.A., Leckie, J.O.,

1989b. XANES and EXAFS study of aqueous Pb(II) sorbed on oxide surfaces. Physica B

158, 674–676.

Collins, C.R., Sherman, D.M., Ragnarsdottir, K.V., 1998. The adsorption mechanism of Sr

on the surface of goethite. Radiochimica Acta 81, 201–206.

Collins, C.R., Sherman, D.M., Ragnarsdottir, K.V., 1999. Surface complexation of Hg

goethite: mechanism from EXAFS spectroscopy and density functional calculations. Jour-

nal of Colloid and Interface Science 219, 345–350.

Combes, J.M., Chisholm-Brause, C.J., Brown, G.E., Parks, G.A., Conradson, S.D., Eller,

P.G., Triay, I., Meier, A., 1992. EXAFS spectroscopic study of neptunium(V) sorbed at the

a-FeOOH/water interface. Environmental Science and Technology 26, 376–382.

Combes, J.M., Manceau, A., Calas, G., 1986. Study of the local structure in poorly ordered

precursors of iron oxyhydroxides. Journal de Physique C 8, 697–701.

Combes, J.M., Manceau, A., Calas, G., 1989a. XAFS study of the evolution of local order

around iron(III) in the solution to gel to iron oxide (a-Fe

) transformation. Physica B

158, 419–420.

Combes, J.M., Manceau, A., Calas, G., 1990. Formation of ferric oxides from aqueous so-

lutions: a polyhedral approach by X-ray absorption spectroscopy. 2. Hematite formation

from ferric gels. Geochimica et Cosmochimica Acta 54, 1083–1091.

Combes, J.M., Manceau, A., Calas, G., Bottero, J.Y., 1989b. Formation of ferric oxides from

aqueous solutions: a polyhedral approach by X-ray absorption spectroscopy. 1. Hydrolysis

and formation of ferric gels. Geochimica et Cosmochimica Acta 53, 583–594.

Cressey, G., Henderson, C.M.B., van der Laan, G., 1993. Use of L-edge X-ray absorption

spectroscopy to characterize multiple valence states of 3d transition metals; a new probe for

mineralogical and geochemical research. Physics and Chemistry of Minerals 20, 111–119.

Criscenti, L.J., Sverjensky, D.A., 2002. A single-site model for divalent transition and heavy

metal adsorption over a range of metal concentrations. Journal of Colloid and Interface

Science 253, 339–352.

hn, R., Scheidegger, A.M., Manceau, A., Curti, E., Baeyens, B., Bradbury, M.H., Chat-

eigner, D., 2002a. Th uptake on montmorillonite: a powder and polarized extended X-ray

absorption ﬁne structure (EXAFS) study. Journal of Colloid and Interface Science 249,

8–21.

hn, R., Scheidegger, A.M., Manceau, A., Schlegel, M.L., Baeyens, B., Bradbury, M.H.,

Chateigner, D., 2003. Structural evidence for the sorption of Ni(II) atoms on the edges of

montmorillonite clay minerals: a polarized X-ray absorption ﬁne structure study. Geochi-

mica et Cosmochimica Acta 67, 1–15.

References 849

hn, R., Scheidegger, A.M., Manceau, A., Schlegel, M.L., Baeyens, B., Bradbury, M.H.,

Morales, M., 2002b. Neoformation of Ni phyllosilicate upon Ni uptake on montmorillo-

nite: a kinetics study by powder and polarized extended X-ray absorption ﬁne structure

spectroscopy. Geochimica et Cosmochimica Acta 66, 2335–2347.

hn, R., Scheidegger, A.M., Manceau, A., Schlegel, M.L., Baeyens, B., Bradbury, M.H.,

2001. Ni clay neoformation on montmorillonite surface. Journal of Synchrotron Radiation

8, 533–535.

Davis, R.D., Gilman, J.W., Sutto, T.E., Callahan, J.H., Trulove, P.C., De Long, H.C., 2004.

Improved thermal stability of organically modiﬁed layered silicates. Clays and Clay Min-

erals 52, 171–179.

Decarreau, A., 1990. Mate

riaux Argileux—Structure, proprie

s et applications. Ouvrage

collectif sous la direction de A. Decarreau. Socie

Fanc- aise de Mine

ralogie et de Crys-

tallographie, Groupe Franc- ais des Argiles, Paris 586pp.

Decarreau, A., Colin, F., Herbillon, A., Manceau, A., Nahon, D., Paquet, H., Trauth-Bad-

aud, D., Trescases, J.J., 1987. Domains segregation in Ni–Fe–Mg-bearing smectites. Clays

and Clay Minerals 35, 1–10.

de Groot, F., 2001. High-resolution X-ray emission and X-ray absorption spectroscopy.

Chemical Reviews 101, 1779–1808.

Delaney, J.S., Bajt, S., Dyar, M.D., Sutton, S.R., McKay, G., Roeder, P., 1996a. Comparison

of quantitative microXANES (SmX) FeIII/(FeII+FeIII) results for amphibole and

silicate glass with independent measurements. Lunar and Planetary Sciences XXVII,

299–300.

Delaney, J.S., Bajt, S., Sutton, S.R., Dyar, M.D., 1996b. In situ microanalysis of Fe

/SFe

ratios in amphibole by X-ray absorption near edge structure (XANES) spectroscopy.

Mineral Spectroscopy (R. Burns memorial volume) 5, 165–171.

Delaney, J.S., Dyar, M.D., Sutton, S.R., Bajt, S., 1998. Redox ratios with relevant resolution:

solving an old problem by using the synchrotron microXANES probe. Geology 26,

139–142.

Dent, A.J., Ramsay, J.D.F., Swanton, S.W., 1992. An EXAFS study of uranyl ions in so-

lutions and sorbed onto silica and montmorillonite clay colloids. Journal of Colloid and

Interface Science 150, 45–60.

d’Espinosa de la Caillerie, J.-B., Bobbin, C., Rebours, B., Clause, O., 1995b. Alumina/water

interfacial phenomena during impregnation. In: Delmon, B., Grange, P., Jacbobs, P.A.

(Eds.), Preparation of Catalysts VI—Scientiﬁc Basis for the Preparation of Heterogeneous

Catalysts. Elsevier, New York, pp. 168–184.

d’Espinosa de la Caillerie, J.-B., Kermarec, M., Clause, O., 1995a. Impregnation of g-alumina

with Co(II) and Ni(II) ions at neutral pH: hydrotalcite-type coprecipitate formation and

characterisation. Journal of the American Chemical Society 117, 11471–11481.

Doelsch, E., Rose, J., Masion, A., Bottero, J.Y., Nahon, D., Bertsch, P.M., 2000. Speciation

and crystal chemistry of iron(III) chloride hydrolysed in the presence of SiO

ligands. 1. An

Fe K-edge EXAFS study. Langmuir 16, 4727–4731.

Doelsch, E., Rose, J., Masion, A., Bottero, J.Y., Nahon, D., Bertsch, P.M., 2002. Hydrolysis

of iron(II) chloride under anoxic conditions and inﬂuence of SiO

ligands. Langmuir 18,

4292–4299.

Drits, V.A., Lanson, B., Gorshkov, A.I., Manceau, A., 1998a. Substructure and superstruc-

ture of four-layer Ca-exchanged birnessite. American Mineralogist 83, 97–118.

Chapter 12.3: X-ray Absorption Spectroscopy850

Drits, V.A., Lindgreen, H., Salyn, A.L., Ylagan, R., McCarty, D.K., 1998b. Semiquantitative

determination of trans-vacant and cis-vacant 2:1 layers in illites and illite–smectites by

thermal analysis and X-ray diffraction. American Mineralogist 83, 1188–1198.

Drits, V.A., Sakharov, B.A., Salyn, A.L., Manceau, A., 1993. New structural model for

ferrihydrite. Clay Minerals 28, 185–208.

Drits, V.A., Silvester, E., Gorshkov, A.I., Manceau, A., 1997. Structure of synthetic mono-

clinic Na-rich birnessite and hexagonal birnessite. 1. Results from X-ray diffraction and

selected-area electron diffraction. American Mineralogist 82, 946–961.

Duff, M.C., Coughlin, J.U., Hunter, D.B., 2002. Uranium co-precipitation with iron oxide

minerals. Geochimica et Cosmochimica Acta 66, 3533–3547.

Duff, M.C., Hunter, D.B., Bertsch, P.M., Amrhein, C., 1999. Factors inﬂuencing uranium

reduction and solubility in evaporation pond sediments. Biogeochemistry 45, 95–114.

Dyar, M.D., Delaney, J.S., Sutton, S.R., 2001. Fe XANES spectra of iron-rich micas.

European Journal of Mineralogy 13, 1079–1098.

Dyar, M.D., Gunter, M., Delaney, J.S., Lanzarotti, A., Sutton, S.R., 2002. Systematics in the

structure and XANES spectra of pyroxenes, amphiboles, and micas as derived from ori-

ented single crystals. Canadian Mineralogist 40, 1375–1393.

Eick, M.J., Fendorf, S.E., 1998. Reaction sequence of nickel(II) with kaolinite: mineral dis-

solution and surface complexation and precipitation. Soil Science Society of America

Journal 62, 1257–1267.

Eggleton, R.A., Fitzpatrick, R.W., 1988. New data and revised structural model for ferrihyd-

rite. Clays and Clay Minerals 36, 111–124.

Elzinga, E., Sparks, D.L., 1999. Nickel sorption mechanism in pyrophyllite–montmoirllonite

mixture. Journal of Colloid and Interface Science 213, 506–512.

Eng, P.J., Trainor, T.P., Brown, G.E., Waychunas, G.A., Newville, M., Sutton, S.R., Rivers,

M.L., 2000. Structure of the hydrated a-Al

(0001) surface. Science 28, 1029–1033.

England, K.E.R., Charnock, J.N., Pattrick, R.A.D., Vaughan, D.J., 1999. Surface oxidation

studies of chalcopyrite and pryrite by glancing-angle X-ray absorption spectroscopy (RE-

FLEXAFS). Mineralogical Magazine 63, 559–566.

Farmer, V.C., 1974. The Infrared Spectra of Minerals. Mineralogical Society, London.

Farquhar, M.L., Charnock, J.N., England, K.E.R., Vaughan, D.J., 1996. Adsorption of Cu

on the (0001) plane of mica. A REFLEXAFS and XPS study. Journal of Colloid and

Interface Science 177, 561–567.

Farquhar, M.L., Vaughan, D.J., Hughes, C.R., Charnock, J.N., England, K.E.R., 1997. Ex-

perimental studies of the interaction of aqueous metal cations with mineral substrates: lead,

cadmium, copper with perthitic feldspar, muscovite and biotite. Geochimica et Cosmoc-

hima Acta 61, 3051–3064.

Fendorf, S.E., 1995. Surface reactions of chromium in soils and waters. Geoderma 67, 55–71.

Fendorf, S., 1999. Fundamental aspects and applications of X-ray absorption spectroscopy in

clay and soil science. In: Schulze, D.G., Stucki, J.W., Bertsch, P.M. (Eds.), Synchrotron X-

ray Methods in Clay Science. CMS Workshop Lectures, vol. 9. The Clay Minerals Society,

Boulder, CO, pp. 19–67.

Fenter, P.A., 2002. X-ray reﬂectivity as a probe of mineral-ﬂuid interfaces: a user guide. In: Fenter,

P.A., Rivers, M.L., Sturchio, N.C., Sutton, S.R. (Eds.), Applications of Synchrotron Radi-

ation in Low-temperature Geochemistry and Environmental Science. Reviews in Mineralogy

and Geochemistry, vol. 49. Mineralogical Society of America, Washington, DC, pp. 149–220.

References 851

Fenter, P.A., Rivers, M.L., Sturchio, N.C., Sutton, S.R. (Eds.), 2002. Applications of Syn-

chrotron Radiation in Low-temperature Geochemistry and Environmental Science. Re-

views in Mineralogy and Geochemistry, vol. 49. Mineralogical Society of America,

Washington, DC.

Fenter, P.A., Sturchio, N.C., 1999. Structure and growth of sterate monolayers on calcite: ﬁrst

results of an in situ X-ray reﬂectivity study. Geochimica et Cosmochimica Acta 63,

3145–3152.

Fialips, C.-I., Huo, D., Yan, L., Wu, J., Stucki, J.W., 2002a. Infared study of reduced and

reduced–reoxidized ferruginous smectite. Clays and Clay Minerals 50, 455–469.

Fialips, C.-I., Huo, D., Yan, L., Wu, J., Stucki, J.W., 2002b. Effect of iron oxidation state on

the IR spectra of Garﬁeld nontronite. American Mineralogist 87, 630–641.

Fischer, D., Caseri, W.R., Ha

hner, G., 1998. Orientation and electronic structure of ion

exchanged dye molecules on mica: an X-ray absorption study. Journal of Colloid and

Interface Science 198, 337–346.

Fitts, J.P., Brown, G.E., Parks, G.A., 2000. Structural evolution of Cr(III) polymeric species

g-Al

/water interface. Environmental Science and Technology 34, 5122–5128.

Ford, R.G., Bertsch, P.M., 1999. Distinguishing between surface and bulk dehydration–

dehydroxylation reactions in synthetic goethites by high resolution theromogravimetric

analysis. Clays and Clay Minerals 47, 329–337.

Ford, R.G., Sparks, D.L., 2000. The nature of Zn precipitates formed in the presence of

pyrophyllite. Environmental Science and Technology 34, 2479–2483.

Ford, R.G., Bertsch, P.M., Farley, K.J., 1997a. Changes in transition and heavy metal par-

titioning during hydrous iron oxide aging. Environmental Science and Technology 31,

2028–2033.

Ford, R.G., Bertsch, P.M., Seaman, J.C., 1997b. Goethite morphologies investigated via

X-ray diffraction of oriented samples. Clays and Clay Minerals 45, 769–772.

Ford, R.G., Kemner, K.M., Bertsch, P.M., 1999a. Inﬂuence of sorbate–sorbent interaction on

the crystallization kinetics of nickel- and lead-ferrihydrite coprecipitates. Geochimica et

Cosmochimica Acta 63, 39–48.

Ford, R.G., Scheinost, A.C., Sheckel, K.G., Sparks, D.L., 1999b. The link between clay

mineral weathering and the stabilisation of nickel surface precipitates. Environmental Sci-

ence and Technology 33, 3140–3144.

Foster, A.L., Brown, G.E., Parks, G.A., 1998a. XAFS study of photocatalyzed, heteroge-

neous As(III) oxidation on kaolin and anatase. Environmental Science and Technology 32,

1444–1452.

Foster, A.L., Brown, G.E., Tingle, T.N., Parks, G.A., 1998b. Quantitative arsenic speciation in

mine tailings using X-ray absorption spectroscopy. American Mineralogist 83, 553–568.

Foster, A.L., Brown, G.E., Parks, G.A., 2002. EXAFS study of As(V) and Se(IV) sorption

complexes on hydrous Mn oxides. Geochimica et Cosmochimica Acta 67, 1937–1953.

Frederickson, J.K., Zachara, J.M., Kennedy, D.W., Duff, M.C., Gorby, Y.A., Li, S.-M.W.,

Krupka, K.M., 2000. Reduction of U(VI) in goethite ( a-FeOOH) suspensions by a dis-

similatory metal-reducing bacterium. Geochimica et Cosmochimica Acta 64, 3085–3098.

Frederickson, J.K., Zachara, J.M., Kennedy, D.W., Liu, C., Duff, M.C., Hunter, D.B.,

Dohnalkova, A., 2002. Inﬂuence of Mn oxides on the reduction of uranium(VI) by the

metal-reducing bacterium Shewanella putrifaciens. Geochimica et Cosmochimica Acta 66,

3247–3262.

Chapter 12.3: X-ray Absorption Spectroscopy852

Fukushima, Y., 1988. Extended X-ray absorption ﬁne structure study of cobalt-exchanged

sepiolite: reply. Clays and Clay Minerals 36, 384.

Fukushima, Y., Okomoto, T., 1987. Extended X-ray absorption ﬁne structure study of cobalt-

exchanged sepiolite. In: Schultz, L.G., van Olphen, H., Mumpton, F.A. (Eds.), Proceedings

of the International Clay Conference, Denver, 1985. The Clay Minerals Society, Bloom-

ington, IN, pp. 9–16.

Fuhrmann, M., Bajt, S., Schoonen, M.A.A., 1998. Sorption of iodine on minerals investi-

gation by X-ray absorption near edge structure (XANES) and

125

I tracer sorption exper-

iments. Applications in Geochemistry 13, 127–141.

Galoisy, L., Calas, G., Arrio, M.A., 2001a. High-resolution XANES spectra of iron in min-

erals and glasses: structural information from the pre-edge region. Chemical Geology 174,

307–319.

Galoisy, L., Cormier, L., Calas, G., Briois, V., 2001b. Environment of Ni, Co and Zn in low

alkali borate glasses: information from EXAFS and XANES spectra. Journal of Non-

Crystalline Solids 293–295, 105–111.

Gates, W.P., 2005. Infrared spectroscopy and the chemistry of dioctahedral smectites. In:

Kloprogge, J.T. (Ed.), The Application of Vibrational Spectroscopy to Clay Minerals and

Layered Double Hydroxides. CMS Workshop Series, vol. 13. The Clay Minerals Society,

Aurora, CO, pp. 125–168.

Gates, W.P., Hunter, D.B., Nuessel, P.R., Bertsch, P.M., 1997. A time resolved XANES study

of an organo-clay redox system. Journal of Physique, IV France 7, C2, 785–787.

Gates, W.P., Slade, P.G., Manceau, A., Lanson, B., 2002. Site occupancy by Fe in nontronite.

Clays and Clay Minerals 50, 223–239.

Gates, W.P., Stucki, J.W., Kirkpatrick, R.J., 1996. Structural properties of reduced Upton

montmorillonite. Physics and Chemistry of Minerals 23, 535–541.

Gehlen, M., Beck, L., Calas, G., Flank, A.-M., van Bennekom, A.J., van Beusekom, J.E.E.,

2002. Unravelling the atomic structure of biogenic silica: evidence of the structural

association of Al and Si in diatom frustules. Geochimica et Cosmochimica Acta 66,

1601–1609.

rard, P., Herbillon, A., 1983. Infrared studies of Ni-bearing clay minerals of the kero-

lite–pimelite series. Clays and Clay Minerals 31, 143–151.

Giaquinta, D.M., Soderholm, L., Yuchs, S.E., Wasserman, S.R., 1997a. The speciation of

uranium in a smectite clay. Evidence for catalysed uranyl reaction. Radiochemica Acta 76,

113–121.

Giaquinta, D.M., Soderholm, L., Yuchs, S.E., Wasserman, S.R., 1997b. Hydrolysis of ura-

nium and thorium in surface-modiﬁed bentonite under hydrothermal conditions. Journal

of Alloys and Coumpounds 249, 142–145.

ven, N., 1988. Smectites. In: Bailey, S.W. (Ed.), Hydrous Phyllosilicates. Exclusive of

Micas. Reviews in Mineralogy, vol. 19. Mineralogical Society of America, Washington,

DC, pp. 497–559.

hner, G., Marti, A., Spencer, N.D., Brunner, S., Caseri, W.R., Suter, U.W., 1996a. Self-

assembled layers of substituted poly(p-phenylene)s on gold and copper investigated by soft

X-ray spectroscopy. Langmuir 12, 719–725.

hner, G., Marti, A., Spencer, N.D., Caseri, W.R., 1996b. Orientation and electronic struc-

ture of methylene blue on mica: a near edge X-ray absorpiton ﬁne structure spectroscopy

study. Journal of Chemical Physics 104, 7749–7757.

References 853

Hayes, K.F., Roe, A.L., Brown, G.E., Hodgson, K.O., Leckie, J.O., Parks, G.A., 1987. In situ

X-ray absorption study of surface complexes at oxide/water interfaces: selenium oxyanions

on a-FeOOH. Science 238, 783–786.

Hayes, K.O., Katz, L.E., 1996. Application of X-ray absorption spectroscopy for surface

complexation modelling of metal ion sorption. In: Brady, P.V. (Ed.), Physics and Chem-

istry of Mineral Surfaces. CRC Press, Boca Raton, FL, pp. 147–223.

Hawthorne, F.C. (Ed.), 1988. Spectroscopic Methods in Mineralogy and Geology. Reviews in

Mineralogy, vol. 18. Mineralogical Society of America, Washington, DC.

Hazemann, J.-L., Manceau, A., Sainctavit, P., Malgrange, C., 1992. Structure of

the a-Fe

1x

OOH solid solution. 1 Evidence by polarized EXAFS for epitaxial growth

of hematite-like clusters in Fe-diaspore. Physics and Chemistry of Minerals 19,

25–38.

Heald, S.M., Stern, E.A., 1977. Anisotropic X-ray absorption in layered compounds. Physics

Review B 16, 5549–5559.

Hesterberg, D., Zhau, W., Hutchinson, K.J., Beauchemin, S., Sayer, D.E., 1999. XAFS study

of adsorbed and mineral forms of phosphate. Journal of Synchrotron Radiation 6,

636–638.

Hirshchmugl, C.J., 2002. Applications of storage ring infrared spectromicroscopy and reﬂec-

tion–absorption spectroscopy to geochemistry and environmental science. In: Fenter, P.A.,

Rivers, M.L., Sturchio, N.C., Sutton, S.R. (Eds.), Applications of Synchrotron Radiation

in Low-Temperature Geochemistry and Environmental Science. Reviews in Mineralogy

and Geochemistry, vol. 49. Mineralogical Society of America, Washington, DC,

pp. 317–339.

Hochella, M.F., 1988. Auger electron and X-ray photoelectron spectroscopy. In: Hawthorne,

F.C. (Ed.), Spectroscopic Methods in Mineralogy and Geology. Reviews in Mineralogy,

vol. 18. Mineralogical Society of America, Washington, DC, pp. 573–637.

Hodgson, K.O., Hedman, B., Penner-Hahn, J.E., 1984. EXAFS and near edge structure III.

Springer Proceedings in Physics. Springer, Berlin.

Hudson, E.A., Terminello, L.J., Viann, B.E., Denecke, M., Reich, T., Allen, P.G., Bucher,

J.J., Shuh, D.K., Edelstein, N.M., 1999. The structure of uranium(VI) sorption complexes

on vermiculite and hydrobiotite. Clays and Clay Minerals 47, 439–457.

Hunter, D.B., Bertsch, P.M., 1994. In situ measurements of tetraphenylboron degradation

kinetics on clay mineral surfaces by IR. Environmental Science and Technology 28,

686–691.

Hunter, D.B., Bertsch, P.M., 1998. In situ examination of uranium contaminated soil particles

by micro-X-ray absorption and micro-ﬂuorescence spectroscopies. Journal of Radioana-

lytical and Nuclear Chemistry 234, 237–242.

Hunter, D.B., Bertsch, P.M., Kemner, K.M., Clark, S.B., 1997. Distribution and chemical

speciation of metals and metaloids in biota collected from contaminated environments by

spatially resolved XRF, XANES, and EXAFS. Journal of Physique IV, France 7, C2,

767–771.

Hunter, D.B., Gates, W.P., Bertsch, P.M., Kemner, K.M., 1999. Degradation of tetraphenyl

boron at hydrated smectite surfaces by time-resolved IR and X-ray absorption spectros-

copies. In: Sparks, D.L., Grundl, T.J. (Eds.), Mineral–Water Interfacial Reactions:

Kinetics and Mechanisms. ACS Symposium Series, vol. 715. American Chemical Society,

Washington, DC, pp. 282–330.

Chapter 12.3: X-ray Absorption Spectroscopy854

Ildefonse, P., Kirkpatrick, R.J., Montez, B., Calas, G., Flank, A.-M., Lagarde, P., 1994.

MAS NMR and aluminum X-ray absorption near edge structure study of imogolite and

allophanes. Clays and Clay Minerals 42, 276–287.

Ildefonse, P., Cabaret, D., Sainctavit, P., Calas, G., Flank, A.M., Lagarde, P., 1998. Alu-

minium X-ray absorption near edge structure in model compounds and Earth’s surface

minerals. Physics and Chemistry of Minerals 25, 112–121.

Jambor, J.L., Dutrizac, J.E., 1998. Occurrence and constitution of natural and synthetic

ferrihydrite, a widespread iron oxyhydroxide. Chemical Reviews 98, 2549–2585.

Janek, M., Komadel, P., 1993. Autotransformation of H-smectites in aqueous solution. The

effect of octahedral iron content. Geologica Carpathica, Series Clays 44, 59–64.

Janek, M., Komadel, P., 1998. Acidity of proton saturated and autotransformed smectites

characterised with proton afﬁnity distribution. Geologica Carpathica, Series Clays 50,

373–378.

Kemner, K.M., Hunter, D.B., Bertsch, P.M., Kirkland, J.P., Elam, W.T., 1997. Determina-

tion of site speciﬁc binding environments of surface sorbed cesium on clay minerals by Cs-

EXAFS. Journal of Physique IV, France 7, C2, 811–812.

Kendelewicz, T., Liu, P., Doyle, C.S., Brown, G.E., 2000. Spectroscopic study of the reaction

of Cr(VI)

with Fe

(III) surfaces. Surface Science 469, 144–163.

Komadel, P., Madejova

, J., Stucki, J.W., 1995. Reduction and reoxidation of nontronite:

questions of reversibility. Clays and Clay Minerals 45, 105–110.

Koningsberger, D.C., Prins, R., 1988. X-ray Absorption: Principles, Applications, Techniques

of EXAFS, SEXAFS and XANES. Wiley, New York.

Lamble, G.M., Lee, J.F., Staudt, W.J., Reeder, R.J., 1995. Structural studies of selenate

incorporation into calcite crystals. Physica B 208, 209, 589–590.

Lamble, G.M., Reeder, R.J., Northoup, P.A., 1997. Characterization of heavy metal incor-

poration in calcite by XAFS spectroscopy. Journal of Physique IV, France 7, C2, 793–797.

Li, D., Bancroft, M., Fleet, M.E., Feng, X.H., Pan, Y., 1995. Al-K edge spectra of alumino-

silicate minerals. American Mineralogist 80, 432–440.

Lin, W., Lee, T.L., Lyman, P.F., Bedzyk, M.J., Marks, T.J., 1997. Atomic resolution X-ray

standing wave microstructural charcterisation of NLO-active self-assembled chromophoric

superlattices. Journal of the American Chemical Society 119, 2205–2211.

Lu, K., Stern, E.A., 1993. Size effect of powdered sample on EXAFS amplitude. Nuclear

Instruments and Methods 212, 475–478.

Madejova

, J., Komadel, P., C

el, B., 1994. Infrared study of octahedral site populations in

smectites. Clay Minerals 29, 319–326.

Manceau, A., 1990. Distribution of cations among the octahedra of phyllosilicates: insight

from EXAFS. Canadian Mineralogist 28, 321–328.

Manceau, A., 1995. The mechanism of anion adsorption on Fe oxides: evidence for the

bonding of arsenate tetrahedral on free Fe(O,OH)

edges. Geochimica et Cosmochimica

Acta 59, 3647–3653.

Manceau, A., Calas, G., 1985. Heterogeneous distribution of nickel in hydrous silicates from

New Caledonia ore deposits. American Mineralogist 70, 549–558.

Manceau, A., Calas, G., 1986. Nickel-bearing clay minerals: 2. Intracrystalline distribution of

nickel: a K-ray absorption study. Clay Minerals 21, 341–360.

Manceau, A., Calas, G., 1987. Absence of evidence for Ni/Si substitution in phyllosilicates.

Clay Minerals 22, 357–362.

References 855