398 9. Nuclear Cosmology
The job of primordial cosmology is to understand how this process pro-
ceeded from the earliest possible moments. While we cannot say what existed
at “the beginning” (if there was a beginning), we can extrapolate backward in
time to temperatures of order 1 GeV when the Universe was believed to con-
sist of a thermal plasma of relativistic quarks, antiquarks, gluons, neutrinos
and photons. When the temperature dropped below a transition temperature
estimated to be kT ∼ 200 MeV, the quarks and antiquarks combined to form
bound hadrons (mostly pions) which then, for the most part, annihilated
leaving nothing but photons and neutrinos. If there had been equal num-
bers of quarks and antiquarks this would have been pretty much the end of
the story. However, the small excess of order 10
−9
of quarks over antiquarks
meant that a small number nucleons remained at T ∼ 100 MeV, of order
10
−9
with respect to the photons and neutrinos. This was the initial condi-
tion for cosmological nucleosynthesis that came about when some nucleons
later combined (kT ∼ 40 keV) to form nuclei.
The process of cosmological nucleosynthesis differs from that of stellar
nucleosynthesis in several important respects. Among them are
• The presence of neutrons. Because of the lack of neutrons in stars, stellar
nucleosynthesis must start with the weak reaction 2
1
H →
2
He
+
ν
e
.Cosmo-
logical nucleosynthesis starts with an abundant supply of neutrons which
need only combine with protons to form nuclei, starting with the reaction
np→
2
Hγ.
• A low baryon–photon ratio. Whereas the baryon to photon ratio in stars
is greater than unity (∼ 10
3
for the sun, Fig. 8.2), it is of order 5 ×10
−9
in
the primordial Universe. This has the important consequence of delaying
nucleosynthesis since the abundant photons quickly dissociate any nuclei
that are produced until the temperature drops to ∼ 100 keV at which
point the probability of a thermal photon having sufficient energy to break
a nucleus becomes small enough.
• A low baryon–neutrino ratio, nearly equal to the baryon–photon ratio.
This was important during the time when most nucleons were free since
weak reactions like ν
e
n ↔ e
−
p can change neutrons into protons and vice
versa. In fact, for kT > 800 keV it turns out that these reactions are suf-
ficiently rapid that they can maintain a “chemical” equilibrium between
the neutrons and protons so that the neutron to proton ration takes the
thermal value of exp(−(m
n
−m
p
)c
2
/kT ). The weak interaction rate drops
to negligible values at a temperature of around 800 keV when the neutron
to proton ratio is about 0.2. Free neutron decay then lowers the ratio to
about 0.1 when nucleosynthesis starts at kT ∼ 100 keV. The proton excess
results in a large quantity of post-nucleosynthesis
1
H.
• A limited amount of time. The elapsed time from the quark–gluon phase
transition to the end of cosmological nucleosynthesis is about three min-
utes. Below temperatures of ∼ 60 keV, the Coulomb barrier prevents fur-