8.3 Stellar nucleosynthesis 375
a particular line is highly dependent on the photosphere temperature and
density which determines the populations of atomic levels. In this regard, it
should be noted that one of the most prominent lines in the solar spectrum is
due to calcium, a rather rare element. This caused a great deal of confusion
before the development of quantum mechanics allowed one to understand the
physics behind the creation of absorption lines. A more fundamental prob-
lem with the use of photosphere abundances is that they give only elemental
abundances since isotopic splittings of lines are generally narrower than the
thermally determined line widths. Exceptions are the isotopic abundances
of carbon and oxygen where the vibrational and rotational lines of the CO
molecule are directly determined by the atomic weights of the constituent
atoms.
The most accurate elemental abundances for most elements come from the
analysis of “carbonaceous chondritic meteorites” that are thought to have a
representative sample of elements with the important exceptions of hydro-
gen, carbon, nitrogen, oxygen and the noble gases. While the formation of
meteorites was a complicated process involving chemical separation, this type
contains three representative phases (silicate, sulfide, and metallic) that give
consistent results. With a few exceptions, agreement with photospheric abun-
dances is to within ±10%.
The most important elemental abundance that is accurately determined
neither by photosphere nor meteor abundances is that of
4
He. This nuclide
was not retained in the formation of small bodies. In fact, the majority of
terrestrial
4
He is believed to be due to α decay of heavy elements after the
formation of the Earth. In the Sun, helium lines are seen only in the chromo-
sphere where its abundance may not be entirely representative. In fact, the
most reliable estimation of the helium abundance appears to be that derived
from solar models where the initial helium abundance is a free parameter that
is adjusted so as to predict that correct solar radius and luminosity [73, 74].
The derived helium abundance is confirmed by measurements of the helio-
seismological oscillation frequencies [73]. These frequencies depend directly
on the sound speed v
s
∼ kT/µ where µ is the mean atomic weight. The
temperature profile is well determined in solar models so the sound speed
determines µ. Since the Sun is essentially made of hydrogen and helium, this
then determines the abundance of helium.
Once the elemental abundances are determined, the nuclear abundances
are generally found by multiplying elemental abundances by the terrestrial
isotopic abundance. Once again, this does not work for the noble gases. An
extreme example is argon where the atomic weight listed in the periodic table
is 39.948 reflecting the fact that
40
Ar is the dominant terrestrial isotope. In
reality, most terrestrial argon comes from
40
K decay (Fig. 5.1) while the α
nucleus
36
Ar dominates in the Sun. The isotopic abundance of this element
is therefore best determined from the solar wind.