Corrosion and Scaling
1335
2.
This results in high concentrations of zincate ions that are effective
scavengers. However, high concentrations of zincate can lead to problems
related to mud performance.
The second type of zinc-base scavenger, utilizes highly water-soluble,
organic, zinc-chelate compounds. The metal ions are bonded with organic
compounds, forming "metal chelates" that are highly soluble in water. This
high solubility enables their use in clear drilling fluids; whereas, a less-
soluble scavenger can settle out and become ineffective. Another advan-
tage of using zinc chelates is that they are effective over a wide range
of
pH.
IfOmB8Se
SC8VengerS.
There is only one iron compound that is commercially
available as a sulfide scavenger for drilling fluids. The product is a synthetic,
high-surface-area magnetite, Fe,O,. Fe,O, is often used in low-pH muds, where
sulfides in the mud exist largely as acidic molecular
H,S.
This is because reac-
tions
of
Fe,O, in normal alkaline-mud pH ranges proceed at
a
slow rate.
Consequently, a soluble sulfide may coexist with unreacted Fe,O, for undesirably
long periods of time. The scavenging reaction of
H,S
by Fe,O, proceeds accord-
ing to the following equation by type
A
reaction:
Fe90,
+
6H,S
+
3FeS,
5
+
4H,O
+
2H,
t
The reaction efficiency and products formed depend on downhole variables.
The most important variables are pH, temperature, reaction time, post-reaction
aging time, and mud-shear conditions, An advantage of using Fe,O, over other
chemicals is that large quantities of insoluble material can be added without
affecting the drilling fluid properties. Under optimum conditions with adequate
Fe,O, surface area exposed, the product may remove up
to
2,000
mg/L sulfides
for
1
lbm/bbl
(2.85
kg/m3) Fe,O, treatment. Fe,O, is often used as a pretreat-
ment to reduce the threat to drilling tools
and
health of the drilling crew, which
may result from a kick of gas containing high H,S content. Although the
chemical composition is the same as magnetite, Fe,O,, it is not very magnetic
and, therefore, does not cling to drillpipe or casing.
Microbiocides.
There are several microbiocides available commercially that
can perform an effective function in controlling microbial activity. Some
of
these chemicals
are
inorganic, such as chlorine, sodium hypochlorite, calcium
hypochlorite, hydrogen peroxide, chromates and compounds of mercury and
silver. However, the organic chemicals find
the
highest use as microbiocides.
Some examples
of
these organic compounds are peracetic acid, paraformalde-
hyde, polychlorophenols and quaternary ammonium derivatives,
to
name a
few
[208].
Microbiocides may be toxic to humans; therefore, care must be taken when
used. When selecting the microbiocide, the field engineer can obtain pertinent
information on chemicals from the service company providing the chemicals.
The microbiocide selected must be compatible with the system in which it is
being used. Some chemicals such as quaternary amines have dual functions; one
as microbiocides and the other as film-forming corrosion inhibitors. Insufficient
concentrations
of
this
type
of chemical may not be enough
to
coat the whole
surface of metal and can cause pitting corrosion. The selection must also depend
on chemicals that can produce the desired control in minimum time limits
and