Part
I:
Reservoir Engineering Primer
21
condition
in a
rock/fluid
system depends
on
IFT.
Changing
the
type
of
rock
or
fluid
can
change
IFT
and, hence,
wettability
of the
system. Adding
a
chemical
such
as
surfactant, polymer, corrosion inhibitor,
or
scale inhibitor
can
alter
wettability.
Contact Angle
Wettability
is
measured
by
contact angle. Contact angle
is
always
measured
through
the
more dense phase. Contact angle
is
related
to
interfacial
energies
by
(3.3)
os
ws
a
ow
cos0
where
o
os
interfacial energy between
oil and
solid [dyne/cm]
o
m
interfacial energy between water
and
solid [dyne/cm]
o
ow
interfacial energy,
or
IFT, between
oil and
water [dyne/cm]
0
contact angle
at
oil-water-solid interface measured through
the
water
phase
[degrees]
Examples
of
contact angle
are
presented
in
Table
3-2 for
different
wetting
conditions.
Table
3-2
Examples
of
Contact Angle
Wetting
Condition
Strongly
Water-
wet
Moderately Water-wet
Neutrally
Wet
Moderately Oil-wet
Strongly
Oil-wet
Contact
Angle,
degrees
0-30
30-75
75-105
105-150
150-180
Wettability
is
usually measured
in the
laboratory. Several factors
can
affect
laboratory measurements
of
wettability. Wettability
can be
changed
by
contact
of the
core
during coring with drilling fluids
or
fluids
on the rig floor,
and
contact
of the
core during core handling with oxygen
and/or
water
from
the
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