
5.3 Atmospheric energetics 131
But this is simply the statement made in Chapter 3 on thermodynamic
grounds; kinetic energy is generated if there is a net correlation between
ascent and positive temperature anomalies, and vice versa. That is, there
must be a preponderance of thermally direct circulations. This generation of
kinetic energy may be offset by the frictional dissipation of kinetic energy.
In order to generate this kinetic energy, we must have depleted some
potential energy. But the potential energy of the atmosphere is not a very
useful concept. It would be minimized by compressing all the air into an
infinitely thin layer near the ground. But such a compression is physically
unrealistic. It would require enormous amounts of work to be done against
pressure forces, and this work would go to increase the internal energy, that
is,
the temperature, of the air. Only if this internal energy could be radiated
steadily away to space would the potential energy be reduced, and it would
have gone, not into kinetic energy, but into thermal radiation. In other
words, most of the potential energy associated with the mass distribution
in the atmosphere is unavailable for conversion into kinetic energy. That
part of the energy which is available for conversion, the 'available potential
energy', is a small fraction of the total. The available potential energy is
defined as that part of the potential energy which can be released without
any change of the internal energy of the atmosphere. From the first law of
thermodynamics, and remembering that the total mass of the atmosphere
does not change, it must be released by adiabatic mixing of air parcels.
Formally, the available potential energy is defined as the maximum amount
of potential energy which could be destroyed by adiabatic mixing of the
atmosphere. Figure 5.11 illustrates the concept. Whether such mixing is in
fact possible depends upon the dynamic constraints to which the system is
subject. In Fig. 5.11
(a),
the isentropes are not parallel to the geopotentials.
We may imagine adiabatic processes which could exchange the wedge of
potentially warmer air marked A for the wedge of potentially colder air
marked B. The result would be to replace the mass of air B with somewhat
less dense air from A, while the air mass A would be replaced by denser air
from
B.
The mean mass distribution would have been lowered slightly and so
a certain amount of potential energy would have been destroyed. Once the
isentropes are parallel to the geopotentials, no further adiabatic exchanges
of air masses with different potential temperatures are possible. Accordingly,
the potential energy released in going from the state shown in Fig. 5.11 (a)
to the state in Fig. 5.11(b) is indeed the 'available potential energy'.
These arguments are restricted to the usual situation of a statically stable
atmosphere, in which the static stability is not supposed to vary on pressure
surfaces. This is a consistency requirement for a quasi-geostrophic descrip-