Geckeler K.E., Nishide H. (Eds.) Advanced Nanomaterials
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Index 899
– microgel 664
– nanogel 664
– precipitation 661
– reversible addition–fragmentation chain
transfer (RAFT) 12
– ring opening (ROP) 432ff.
– ring-opening metathesis (ROMP) 13, 743
– stable free radical 11
polymersome 836
poly(methacrylic acid) (PMA) 105
poly((3-methacryloxy) propyl
pentadimethyldisiloxane) 33
poly((3-methacryloxy) propyl
pentadimethyldisiloxane-block-tert-butyl
acrylate) 56
poly{Ν
ε
-2[2-(2-methoxyethoxy)ethoxy]acetyl
L-lysine-block-sodium L-aspartate}
– PELLys
100
-b-PNaLAsp
30
843
poly(γ-methyl L-glutamate) (PMLG,
PMLGlu) 175, 837
– aggregate with phosphate
(PMLGlu
10
-P) 841
poly(γ-methyl L-glutamate-block-butadiene-
block-γ-methyl D,L-glutamate)
(PMLGlu-b-PB-b-PMGlu) 855
poly(γ-methyl L-glutamate-block-butadiene-
block-γ-methyl L-glutamate)
(PMLGlu-b-PB-b-PMLGlu) 855
poly(γ-methyl L-glutamate-block-
tetrahydrofuran-γ-methyl L-glutamate)
(PMLGlu-b-PTHF-b-PMLGlu) 862
poly(methyl methacrylate) (PMMA) 22ff.,
385, 462
– chain scission 24
– miscible system PMMA/PEO 409
– syndiotactic and isotactic 792
poly(α-methylstyrene-block-hydroxystyrene)
(Pα-MS-b-HOST) 27, 56ff.
polynorbornene
– TEMPO-substituted 325
poly(norbornene-block-vinylalcohol) 14
polyolefi n (PO)
– matrix 414
– PO-g-MAH compatibilizer 425
– PO/OLS nanocomposite 414ff., 428
– preparation method of PO/layered silicates
nanocomposite 412ff.
poly(oxyalkylene)-amidoacid 469
poly(oxyalkylene)-amine 462ff.
– amphiphilic 459ff.
– salt 463
poly(oxyalkylene)-diamine (POA-diamine)
462ff.
– salt 464
poly(oxyalkylene)-polyamine salt 462
– intercalating agent 462
poly(oxybutylene)-diamine
(POB-diamine) 465
– POB2000 465
poly(oxyethylene)-amine (POE-amine) 462
poly(oxyethylene)-diamine
(POE-diamine) 462
– POE2000 462
poly(oxymethyl) dendron 745
poly(oxymethylphenylene) dendron
(PPD) 746
– thiol-terminated 746
poly(oxypropylene)-amine
(POP-amine) 462
– POP2000 464f.
– POP4000 465
– POP/MMT hybrid 472
poly(oxypropylene)-bis-amindocarboxylic acid
salt (POP-acid) 461
polypeptide 836
– core-forming 839
– corona-forming 837
– hybrid block copolymer 837
polypeptide-based block copolymer 835ff.
– aggregation 837
– linear 835
– self-assembly 835ff.
– solid-state structure 844
– solution self-assembly 837
polypeptide-based hydrogel 842
polyplex 98
polypropylene (PP) 383, 466
– functionalized with maleic anhydride
(PP-g-MAH) 410, 425f.
– immiscible system PP/PS 409
– PP/OLS nanocomposite 421ff.
– PP/PA blend 410
– PP-POP2000 copolymer 472
poly(propylene glycol) (PPG) 861
poly(propylene sulfi de) 100
polysaccharide 719, 836
polysarcosine (PSar) 853ff.
poly(sarcosine-block-styrene-block-sarcosine)
(PSar-b-PS-b-PSar) 856
polysilane 160ff.
– 1-D architecture on surfaces 162
– binary helical fi lm 185
– fl uoroalkyl-containing 162
– helical 161f.
– optically active 167
polysiloxane-based triblock copolymer 857
poly(sodium
L-glutamate) 842
poly(sodium 4-styrene sulfonate) (PSS) 282
900 Index
polystyrene (PS)
– atactic 792
– clay nanocomposite 462
– core 658
– dinitroxide functionalized 329
polystyrene-based diblock copolymer 845
polystyrene-based triblock copolymer 856
poly(styrene-block-γ-benzyl L-glutamate)
(PS-b-PBLGlu) 846ff.
– PS
10
-b-PBLGlu
10
848
– PS
10
-b-PBLGlu
20
849
– PS
10
-b-PBLGlu
40
849
– PS
52
-b-PBLGlu
104
848
poly(styrene-block-Ν
ε
-benzyloxycarbonyl
L-lysine) (PS-b-PZLLys) 839ff.
– PS
10
-b-PZLLys
20
848
– PS
10
-b-PZLLys
40
848
– PS
10
-b-PZLLys
60
848
– PS
10
-b-PZLLys
80
849
– PS
52
-b-PZLLys
111
847
– PS
258
-b-PZLLys
57
840
– PS
258
-b-PZLLys
109
840
poly(styrene-block-butadiene) (PS-b-PB) 20,
55, 123
poly(styrene-block-butadiene-block-styrene)
(PS-b-PB-b-PS) 116
poly(styrene-block-1,2-butadiene)
– modifi ed 58
poly(styrene-block-2-cinnamoyloxyethyl
methacrylate) (PS-b-PCEMA) 69ff.
– nanofi bre 69ff.
poly(styrene-block-2-cinnamoyloxyethyl
methacrylate-block-acrylamide)
(PS-b-PCEMA-b-PAA) 73
– γ-Fe
2
O
3
hybrid nanofi ber 87
– nanotube 82ff.
– PS
690
-b-PCEMA
170
-b-PtBA
200
73
poly(styrene-block-2-cinnamoyloxyethyl
methacrylate-block-tert-butyl acrylate)
(PS-b-PCEMA-b-PtBA) 43
poly(styrene-block-ethylene) (PS-b-PE) 147f.
poly(styrene-block-ethylene-co-butadiene-
block-styrene) (SEBS) 466, 802ff.
– SEBS-POA copolymer 467
poly(styrene-block-ethylene-co-
propylene) 390
poly(styrene-block-(ethylene-co-propylene)-
block-styrene) (SEPS) 806
poly(styrene-block-ethylene oxide) (PS-b-PEO)
14, 40, 116ff.
poly(styrene-block-ethylene oxide-block-
styrene) (PS-b-PEO-b-PS, SEOS) 815
poly(styrene-block-ethylene propylene)
(PS-b-PEP) 117
poly(styrene-block-ethylene propylene-block-
ethylene) (PS-b-PEP-b-PE) 141ff.
– anthracene 141ff.
– benzoic acid 141ff.
poly(styrene-block-ferrocenyldimethylsilane)
(PS-b-PFS) 27, 123, 136
poly(styrene-block-hydroxyethyl methacrylate-
block-methyl methacrylate)
(PS-b-PHEMA-b-PMMA) 120
poly(styrene-block-isoprene) (PS-b-PI) 7ff.,
50ff., 120, 148
– asymmetric 133
– nanofi bre 70ff.
– PS
130
-b-PI
370
80
poly(styrene-block-isoprene-block-styrene)
(PS-b-PI-b-PS, SIS) 798f.
poly(styrene-block-lactic acid) (PS-b-
PLA) 27, 40
poly(styrene-block-L-lactide) 56
poly(styrene-block-L-lysine)
(PS-b-PLLys) 846
– PS
8,10
-b-PLLys
9-72
838
poly(styrene-block-methyl methacrylate)
(PS-b-PMMA) 18ff., 55ff., 115ff.
– surfactant-assisted orientation 128
– symmetric diblock copolymer 132ff.
poly(styrene-block-methyl methacrylate-block-
ethylene oxide) (PS-b-PMMA-b-PEO) 116
poly(styrene-block-perfl uoro-octylethyl
methacrylate) (PS-b-PFOMA) 37
poly(styrene-block-dimethylacrylamide-block-
lactide) (PS-b-PDMA-b-PLA) 39
poly(styrene-block-2-vinylpyridine)
(PS-b-P2VP) 47
– diblock copolymer 136
poly(styrene-block-2-vinylpyridine-block-tert-
butyl acrylate) (PS-b-P2VP-b-PtBA) 115
poly(styrene-block-4-vinylpyridine) (PS-b-
P4VP) 37, 55, 123
poly(styrene-co-maleic anhydride)
(SMA) 466f.
– grafted with POA-amine 467
– SMA-POP copolymer 468
poly(styrene sulfonate) (PSS) 231
polytetrafl uoroethylene (PTFE) crystal 136
polytetrahydrofuran (PTHF) 862
polythiophene-based conjugated
polymer 323
poly(Ν
ε
-trifl uoroacetyl L-lysine)
(PTLLys) 853
poly(vinyl alcohol) (PVA) 286, 390f.
poly(vinyl methylether) (PVME)/polystyrene
(PS) 410
poly(vinylpyridine) (PVP) 45
Index 901
poly(vinyl pyrrolidone) (PVP) 199, 308, 390
poly(N-vinyl-2-pyrrolidone) 353
poly(vinylidene fl uoride) (PVDF)/nylon-6
(PA6) blend 410
porous anodic alumina (PAA) 265
porphyrin 671
post polymerization modifi cation 14
potassium hexaniobate nanotube 234
powder X-ray diffraction 485
precipitation polymerization 661
17-(1-prenyl)-13-oxo-hepta-decanethiol
(PHT) 277f.
preparation method
– biodegradable polyester 439
– PO/layered silicates
nanocomposite 412ff.
pressing 523
principle of independent surface action
49
pristine PO 424
pristine SWNT 622, 719
process zone size failure criterion 580
processability 444
propranolol 659ff.
protein 781f.
– interaction with CNT 723
protein kinase A (PKA) 101f.
proton sponge effect 96
pseudoextracellular fl uid (PECF) 856
pyrene 667
pyrene chromophore
– photolabile 105
pyrene fl uorophore 280
1-pyrenemethylamine 280
pyridinium 12-(cholesteryloxycarbonyloxy)
dodecanesulfate (TS) 658
pyridinium 12-(4-vinylbenzyloxycarbonyl)
dodecanesulfate (PS) 658
PZBAA 518
PZBAAr 518f.
q
quantum dot (QD) 531, 778
– CdSe–ZnS 286
– molecular imprinting 669
quartz crystal microbalance (QCM)
325ff.
r
radical group
– C-centered 324
– N-centered 324
– NO-centered 324
– O-centered 324
radical polymer
– mesoscale 319ff.
– organic radical polymer electrode 324
radiofrequency (RF)-sputtering 686
radiotherapy 549
– microbioceramics 549
random sequential addition (RSA) 775f.
re-sintering 557
– crack healing 558
reactive ion etching (RIE) 20, 136
reactive oxygen species (ROS) 605
redox capacity 329
redox polymer layer 321
redundancy 771
relative Kuhn’s dissymmetry ratio 179ff.
relative viscosity 78
relaxation 557
α-relaxation frequency 423
remodeling cycle 527
renewable thermoplastic matrix 403ff.
resist
– negative-tone 17
– positive-tone 17
reversible addition–fragmentation chain
transfer (RAFT) polymerization 12
Re-Writable (RW) mode 178
rhenium
– [Re
6
Se
6
]
2+
metal cluster 744
rhenium oxide (Re
2
O
7
) 513ff.
– Re/ALCOA 514f.
– Re/OMA 513ff.
– Re/OMA3.5 514f.
– Re/OMA6.5 514f.
– Re
2
O
7
/γ-Al
2
O
3
513
– Re
2
O
7
/meso-Al
2
O
3
513
ring opening metathesis polymerization
(ROMP) 13, 743
ring opening polymerization (ROP)
432ff.
RNA (ribonucleic acid) 781
– transfer 96
robocasting 534
rod structure 162ff.
rod–coil block copolymer 7
(S)-ropivacaine 662f.
rubidium
– [(Rb(18C6))
4
(MnCl
4
)][TlCl
4
]
2
∙ nH
2
O 371
ruboxyl
– pluronic micelle 107
rutile nanotube 220
s
S
A383
512
saponite 460
902 Index
Sb, see antimony
SBA-15 343ff.
scaffolding material 527
scandium oxide (Sc
2
O
3
) 570
scanning electron microscopy (SEM) 430,
529
scanning force microscopy (SFM) 120
scanning probe microscopy (SPM) 161
scanning tunnel microscopy (STM) 161
scattering angle 77
schizophyllan (SPG)
– single-stranded (s-SPG) 720
seed-mediated growth method 298ff.
– AuNP on ITO 298ff.
selenium nanostructure 205
selected area diffraction (SAD) 141
selected area electron diffraction
(SAED) 203
self-assembled fi brillar network
(SAFIN) 793, 817ff.
self-assembled micellar network
(SAMIN) 793ff., 827f.
self-assembled monolayer (SAM) 124, 220,
776ff.
self-assembled supramolecular
C
32
H
70
N
2
ZnO
4
nanotube 235
self-assembling nanocluster
– tetrahalometallate anion 365ff.
self-assembling synthetic material 2
self-assembly
– biomimetics 536
– concept 767ff.
– enantiopure 172
– gold nanoparticle 198
– information guided 869ff.
– layer-by-layer (LBL) 270, 281ff.
– linear polypeptide-based block
copolymer 835ff.
– manufacturing process 783
– molecular 791ff.
– nanostructured organogel 791ff.
– nucleated DNA 874
– passive 773
– programmable 773
– smectic 159
– solution 837
– Stranski–Krastanov 779
– structural DNA nanotechnology 869ff.
– surfactant 215
– templated 123
self-connecting 768
self-consistent mean fi eld 3
self-crack healing 559ff.
self-disorganizing system 771
self-healing 555ff.
– atmosphere 567
– ceramics 555ff., 588
– composition 562
– fatigue strength 575
– mechanism 559
– structure 562f.
– surface crack in structural
ceramics 555ff.
– temperature 568
self-joining 768f.
self-organization 772
– thermodynamics 770ff.
self-organized array 173f.
– 3-D bulk phase 175
– intermolecular weak van der Waals
interaction 175
– orientation 174
– visualization 173
semi circle structure 162ff.
semiconductor nanocrystal 531
sensor 737
– CNT 289
sequential minimization of entropy loss
(SMEL) 782
shape memory polymer (SMP) 386
shear-thinning effect 78
silicate
– copolymer hybrid 466ff.
– layered 460
– organophilic layered (OLS) 413ff.
– random platelet 472
silicon
– SiGe 689ff.
– visualization of Si–C bonding 682
silicon carbide (SiC) 557ff.
– bulk 684
– composite 569
– fi guration 563
– mullite composite 585f.
– multicomposite 585
– nanoparticle composite 587
– nanowire 240
– particle composite 571
– SiC/SiO
2
core–shell nanocable 240
– whisker 563ff., 585
silicon dioxide (silica)
– dielectric material 34
– double-walled nanotube 215
– hybrid nanotube 215
– liposome–silica nanoparticle hybrid
system 531
– molecular imprinting 653
– nanoparticle 665
Index 903
– nanotube 214f.
– Raman spectrum 687
– surface-modifi ed 809
silicon nitride (Si
3
N
4
) 557f.
– composite 569f.
– nanotube 238
silicone oil 819
silver
– Ag nanoparticle (AgNP) 309
– Ag nanowire 199, 211
– Ag
2
Se nanotube 211
– Ag
2
Te nanotube 211
– gold–silver alloy catalyst 342
– nanocatalyst 335
– nanoparticle 393
– nanorod 395
– PVA nanocomposite 394
silver catalyst 342ff., 351ff.
– epoxidation reaction 346f.
simulated body fl uid (SBF) 541ff.
single-walled carbon nanotube
(SWNT) 251ff., 598, 616ff., 716ff.
– AuNP 286
– CdSe–ZnS quantum dot 286
– DNA-met-SWNT 723
– emitter 289
– interaction with protein 723
– LSZ 725f.
– memory element 289
– metallic (met-SWNT) 717ff., 735
– nanotube aquator 289
– noncovalent functionalization 718
– semimetallic (sem-SWNT) 717, 735
– sensor 289
siRNA transfer 96
size-exclusion chromatography (SEC) 440
slip tube network (STN) 797
small angle neutron scattering
(SANS) 806, 837
small angle X-ray scattering (SAXS) 120,
409, 802
smectite 404, 460
sodium
– [(Na(15C5))
4
Br][TlBr
4
]
3
368
sodium dodecyl benzene sulfonate (SDBS)
279, 717
sodium dodecyl sulfate (SDS) 215, 234,
286, 301ff., 495
sodium montmorillonite (Na
+
-MMT) 461ff.
– exfoliating 473
sodium poly(acrylate) 390
sol–gel method 196, 216ff., 233ff., 536ff.
sol–gel nanohydroxyapatite 538
sol–gel processing 523
solid/liquid interface 774
solidifi cation
– directional 140
solution
– intercalation 412f.
– lyotropic 7
– self-assembly 837
solution–liquid–solid (SLS) method 234
solvated metal atom dispersion (SMAD)
265
solvent
– effect 826
– evaporation 122
sono-electrochemical method 210
sorbitol 820
spacer 820
spin-coating technique 186
spin–lattice relaxation time 856
spirobenzopyran (SBP) 107
stable free radical polymerization
(SFRP) 11
π–π-stacking interaction 277ff., 746ff.,
822ff.
standing wave effect 30
stannoxane 708ff.
stearyldimethylbenzylammonium
chloride 407
stem cell 529
stencil 18
stigmergy 780
stress 556, 571, 808
stress intensity factor 556, 573
stress shielding 533
strontium
– La
0.5
Sr
0.5
CoO
3
nanotube 235
– SrAl
2
O
4
nanotube 235
structural ceramics 555ff.
– self-healing of surface crack 555ff.
structural DNA nanotechnology 869ff.
– information guided self-assembly 869ff.
substrate-enhanced electroless deposition
(SEED) 260
sugar recognition 670
superconducting oxide 365
superconducting quantum interference
device (SQUID) 325
superhelical assembly
– homochiral intermolecular
interaction 169
– mesoscopic 2-D hierarchical 167
super-paramagnetism 43
supersaturation
– degree 46
superspheres 784
904 Index
supersurfactant 86
supramolecular assembly
– helical polymer 160
supramolecular chemistry 85, 779
supramolecular fi lm
– helical polymer-based 159ff.
supramolecular interaction
– AuNP and CNT 271
supermolecule 780
suprapolymer 75
surface
– low-energy 48
– fl uorinated block copolymer 48
– modifi cation 540
– nanopatterned 123
– relief grating 54
surface crack
– self-healing in structural ceramics 555ff.
surface energy 49
– photoswitchable 51
surface interaction 126
– homogeneous 126
– preferential wetting 126
surface plasmon resonance (SPR)
frequency 389
surface water contaminant 615ff.
– CNT as adsorbent 615ff.
surface-enhanced Raman scattering 680
surface-responsive material 2
surfactant 86, 222, 286, 395
– anionic surfactant templating 492ff.
– cationic surfactant templating 495ff.
– CNT dispersion 737
– intercalating agent 438
– ionic 717
– neutral surfactant templating 486ff.
– polymerizable 658
– self-assembly 215
switch
– helical polysilane fi lm 178
– helix–coil transition 182
– reversible 180
SWNT, see single-walled carbon nanotube
synthetic material
– self-assembling 1
t
taurodeoxycholic acid (TDOC) 720
tellurium nanostructure 205
temperature
– dependence of minimum fracture stress
582f.
– effect 801
– polymeric assembly 102ff.
temperature-programmed desorption (TPD)
508
temperature-programmed reduction (TPR)
511
template 17, 482
– effect 653
– nanolithographic 17
– nanoparticle 736
– nanoporous block copolymer 20
templating
– anionic surfactant 492ff.
– cationic surfactant 495ff.
– neutral surfactant 486ff.
– nonsurfactant 498ff.
tensile deformation 806ff.
teratogenicity 608
– engineered carbon nanoparticle 608
Tergitol
®
15-S-9 486
Tergitol
®
15-S-12 486
tetracalcium phosphate (TTCP) 534
2,3,7,8-tetrachlorodibenzo-p-dioxin
(TCDD) 639
tetraethoxysilane (TEOS) 199
tetraethylorthosilicate (TEOS) 35
2,2,6,6-tetramethylpiperidine-1-oxyl
(TEMPO) derivative 325
tetrakishydroxymethylphosphonium
chloride (THPC) 199
tetramethoxymethyl glycoluril
(TMMGU) 28
thallium
– [(Tl(18C6))
4
(MCl
4
)][TlCl
4
]
2
∙ nH
2
O 369
theophylline 659ff.
therapeutic agent 738
thermal annealing 114
thermal gradient 122
thermal shock 556
thermal stress 385ff., 556
thermoplastic elastomer (TPE) 795
– gel (TPEG) 795ff.
thermoseeds 550
thiobarbituric acid reactive substance
(TBARS) 605
thrombin aptamer 876
time-dependent indicator (TTI) 386
tin
– Sn(2-ethylhexanoate)
2
440ff.
tin oxide (SnO
2
) nanotube 232
tip-enhanced Raman scattering (TERS)
679ff.
tissue distribution
– carbon nanoparticle 600
tissue engineering 527ff.
tissue interaction 524
Index 905
titanium
– Ti6Al-4V 528ff.
– Ti(O-1-C
3
H
7
)
4
432
titanium dioxide (TiO
2
, titania)
– attachment of AuNP 307
– Brookite-type nanotube 221
– nanostructured bioceramic 547
– nanotube 216ff.
– sulfur-doped nanotubular array 220
tone chemistry
– negative 18
– positive 18
top-down process 334, 783
topology 161f.
– rod, semi-circle and circle structure
162
– switching 165
toroid-like architecture 166
toxicology
– ecological 595ff.
– engineered carbon nanoparticle 595ff.
transition state analogue (TSA) 664ff.
transition temperature 179f.
transmission electron microscopy
(TEM) 202, 409, 485
triblock copolymer (tri-BCP) 3, 39, 852
– organogel 803
– polydiene-based 852ff.
– polyether-based 858
– polysiloxane-based 857
– polystyrene-based 856
β-tricalcium phosphate (β-TCP)
534, 543f.
trihalomethane (THM) 642
– CNT 642f.
N,N,N-trimethyl octadecylammonium
bromide 432
trimethylolpropane trimethacrylate
(TRIM) 662
trinitrotoluene (TNT) 666
trioctylphosphine oxide (TOPO)
– CdSe nanoparticle 755
triphenylsulfonium trifl ate 28
tris(8-hydroxyquinoline) gallium organic
nanowire (GaQ
3
) 224
trypsin 726ff.
tumor 93
tungsten
– WS
2
206
tungsten oxide
– WO
3
nanotube 230
– WO
3
–H
2
O nanotube 234
turnover frequency (TOF) 748
turnover number (TON) 748
u
ultra-high molecular-weight polyethylene
(UHMWPE) 390
uncapping trigger 546
ureas 820
uric acid 300, 670
UV-diffuse refl ectance spectroscopy
(UV-DRS) 511
v
valproic acid (VPA) 548
vanadium 518
vanadium oxide
– VO
x
nanotube 225f.
– V
2
O
5
bulk-type 517
– V
2
O
5
∙ nH
2
O nanotube 225f.
vapor–liquid–solid (VLS) mechanism 230
Vickers indentation 560, 574
4-vinlpyridine 670
viscometry 75
viscosity 78, 444
– index 168
Volmer–Weber régime 779
w
W, see tungsten
water structure 786
Weibull function 574
Weibull modulus 574
wide-angle X-ray diffraction (WAXD) 172,
415
wide-angle X-ray scattering (WAXS) 434,
844
Write-once Read Many (WORM) mode
178ff.
x
X-ray diffraction (XRD) 461
– d-spacing 461
– pattern 237
– powder 485
– wide-angle (WAXD) 172, 415
X-ray lithography 17
X-ray photoelectron spectroscopy (XPS)
510, 854
y
Yamakawa–Fujii–Yoshizaki (YFY)
theory 78
yttrium
– YBa
2
Cu
3
O
7
365
yttrium oxide (Y
2
O
3
) 550, 570
– nanotube 232
– 17Y
2
O
3
–19Al
2
O
3
–64SiO
2
(YAS) 549
906 Index
z
zeolitic micropore 492
zigzag mechanism
– exfoliating Na
+
-MMT 473
zinc
– Pd-Zn alloy catalyst (PZBAAr) 518f.
– Zn(II) adsorption 630f.
– ZnAl
2
O
4
spinel nanotube 235
– ZnCl
2
//meso-Al
2
O
3
516f.
– ZnO nanorod array 240
– ZnO nanotube 221ff.
– ZnO–ZnS nanocable 240
– ZnS 206ff.
zirconium oxide
– ZrO
2
nanotube 232
zirconium titanate (ZrTiO
3
) nanotube 233