174 6 Applications of dressing to linear problems
6.3 Zero-range potentials, dressing,
and electron–molecule scattering
Following Andrianov et al. [25], the Darboux formulas can be applied in multi-
dimensional space in combination with those for the radial Schr¨odinger equa-
tion [324, 391]. This approach makes it po ssible to use the DT technique to
work with an improved version of a ZRP mo del.
Our aim here is to dress the ZRP by means of a special choice of the DT
in order to widen the possibilities of the ZRP model. The DT modi fies the
generalized ZRP boundary condition and creates a potential with arbitrarily
arranged discrete spectrum levels for any angular momentum l.
6.3.1 ZRPs and Darb oux transformations
Our statement consists in the fact that generalized ZRPs [38] appear as a
result of the DTs applied to zero potential. In order to demonstrate this we
consider a radial Schr¨odinger equation
−
1
2
d
2
dr
2
−
1
r
d
dr
+
l(l +1)
2r
2
+ u
l
− E
ψ
l
(r) = 0 (6.35)
for partial wave ψ
l
with orbital momentum l. The atomic units = m
e
=1
are used throughout the present section. Here u
l
, l =0, 1, 2,..., are potentials
for the partial waves with an asymptotic at infinity
ψ
l
(r) ∼
sin(kr −
lπ
2
+ δ
l
)
kr
,
where δ
l
are partial phase shifts. Equation (6.35) describes scattering of a
particle with energy E and momentum k =
√
2E by the rapidly decreasing
potential u
l
. In the absence of the potential, partial shifts δ
l
= 0 and partial
waves can be expressed via spherica l functions ψ
l
= j
l
(kr).
It is k nown that (6.30) with
a
1
= −
1
r
,a
0
=
l(l +1)
2r
2
+ u
l
(6.36)
is cova riant with respect to the DT (6.33) and (6.34). The prop function φ
plays an important role when applying the DT because it is used to calculate
s. The function φ is a solution of (6.35) at a particular value of energy E =
−κ
2
/2, where we assume κ is a real number. If κ is a complex number, then
the dressed potential will be a complex function in general.
Let us demonstrate how a generalized ZRP can be produced by the DT.
It is convenient to use a sequence of DTs (Crum formulas [94] with the wave
and prop functions multiplied by r), which for our equation look like
ψ
l
→ ψ
(1)
l
=const·
W (rψ
l
,rφ
1
,...,rφ
2l+1
)
rW(rφ
1
,...,rφ
2l+1
)
, (6.37)
u
l
→ u
(1)
l
= u
l
− [ln W (rφ
1
,...,rφ
2l+1
)]
′′
. (6.38)