158 Overview of global climate forcings and feedbacks
rising has caused a great deal of concern about potential human impact on climate,
and resulted in major research activities in global climate change.
In the absence of so-called greenhouse gases, the average surface temperature
of the Earth would be over 30
C cooler than it is today. This is because the
greenhouse gases absorb upwelling terrestrial radiation and radiate the absorbed
gases, both upward and downward, causing a net gain in energy (reduced loss)
at the Earth’s surface. Without those greenhouse gases, a larger fraction of the
upwelling terrestrial radiation would escape through the atmospheric window to
space. The major greenhouse gas is water vapor which varies naturally in space
and time due the Earth’s hydrological cycle (e.g., see Randall and Tjemkes, 1991).
The second most important greenhouse gas is carbon dioxide. In contrast to water
vapor, carbon dioxide is rather uniformly distributed throughout the troposphere,
although the radiative forcing associated with it is more heterogeneous as a result
of spatial (e.g., latitudinal) and temporal variations in tropospheric temperature
and water vapor concentrations, and in surface emissions and absorption.
We discuss the greenhouse effect further in Subsection 8.2.4. Other strong
absorbers of terrestrial radiation are methane, nitrous oxide, and chlorofluoro-
carbons (CFCs). Currently the concentrations of these gases are so small that
their contributions to infrared absorption cannot be easily detected by satellite.
The concentrations of CFCs, for example, are six orders of magnitude (a million
times) smaller than carbon dioxide. The concern about CFCs is that per molecule
they are 20 000 times more effective at absorbing infrared radiation than carbon
dioxide.
8.2.2 Absorption and scattering by aerosols
The radiative properties of aerosol particles is a complicated function of their
chemistry, shape, and size spectra. Moreover, if the aerosol particles are hygro-
scopic, their radiative properties change with the relative humidity of the air.
At relative humidities greater than 70%, the hygroscopic particles (called haze)
take on water vapor molecules and swell in size, thus changing their radiative
properties not only because of size effects but also because of changes in their
complex indices of refraction as the water-solution–particle mixture changes in
relative amounts.
Dry aerosol particles in high concentrations such as over major polluted urban
areas and over deserts can cause substantial absorption and scattering of solar
radiation. In some polluted boundary layers, aerosol absorption has been estimated
to result in heating rates on the order of a few tenths to several degrees per
hour (Braslau and Dave, 1975; Welch and Zdunkowski, 1976). In the Saharan
dust layer, aerosol absorption has been calculated to produce a heating of 1–2
C