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A discussion of these functions and their behavior at
z
=0 and as may be found, for example, in
[1]. In this application then
xℓm
is also the
ℓ
th positive root of the spherical Bessel function of the first
kind of order
m.
For each eigenvalue
uℓmn
with fixed
ℓ
and
m
we have the eigenfunctions
We verify by direct integration over the sphere that the eigenfunctions corresponding to the same
eigenvalue are all mutually orthogonal. The general theory assures that eigenfunctions with distinct
eigenvalues likewise are orthogonal.
Example 9.9 The eigenvalue problem for Schrödinger’s equation with a spherically
symmetric potential well.
The last example of this book is a classic textbook problem in quantum mechanics (see, e.g., [20]). It is
chosen to remind the reader that eigenfunction expansions are commonplace in quantum mechanics,
that the eigenfunctions of the Laplacian are essential building blocks for the eigenfunctions of the
Schrödinger equation, and that other eigenvalue problems occur naturally which no longer have the
concise structure of Sturm-Liouville problems but which can still be attacked with the algorithms
employed throughout these pages.
The arguments of Example 9.8 need only minor modifications when we consider the eigenvalue problem
for the Schrödinger equation
(9.3)
where
ħ
and
m
are constants and
V(r)
is a nonpositive function given as
Since
V
is discontinuous, the above Schrödinger equation cannot have a classical solution everywhere.
The postulates of quantum mechanics ask for a function
u
which is a classical solution where
V
is
continuous, which is continuous and has continuous gradients at all points, and which decays as
such that
Let us now solve equation (9.3). An eigenfunction expansion solution would be of the form
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