tartaric acid esters of fatty acids, polysorbate 60 and
sodium stearloyl 2-lactylate. Surfactants at low con-
centrations act to modify the surface behaviors of
liquids. They are believed to complex with the pro-
tein–starch structure, thereby strengthening the film,
and to delay dough setting during baking. The behav-
ior of surfactants is due to their amphoteric (possess-
ing both hydrophilic and hydrophobic molecular
regions) properties. Their behavior varies according
to the charges on the molecules, their solubility, the
hydrophilic–lipophilic balance, and the type of
functional groups involved. (See Emulsifiers: Uses in
Processed Foods.)
0017 Surfactants modify dough consistency and reduce
stickiness by reacting with the gluten. The greasiness
of biscuits with high fat content is also reduced by
surfactants. Crumb softeners also complex with the
starch molecules to delay retrogradation and texture
staling. The grain pattern and volume of the finished
product are often improved, as surfactants increase
dough gas-retaining properties.
0018 Antioxidants retard the development of oxidative
rancidity during product storage. All fats are subject
to oxidative or hydrolytic rancidity which causes ob-
jectionable odors and flavors, but antioxidants delay
these reactions from occurring within the biscuits’
shelf-life. They are usually added to bulk shortenings
and are important for preserving low-moisture prod-
ucts, which are expected to remain edible for several
months. (See Antioxidants: Natural Antioxidants;
Synthetic Antioxidants.)
Is Water an Ingredient?
0019 Water is often thought of as a processing aid or cata-
lyst, rather than as an ingredient. It is incorporated at
the dough stage but driven off during baking. Water
functions in several ways, including hydrating flour
proteins and starch, dissolving sugars, salts, and vari-
ous leavening chemicals, aiding in ingredient distribu-
tion and helping control dough temperature.
0020 A dough’s consistency is directly related to its water
content, or absorption. Many factors affect dough
absorption. Approximately 46% of flour’s total
absorption is associated with the starch, 31% with
protein, and 23% with the pentosans. Acceptable
consistency can be obtained only after sufficient
water is present to hydrate the flour. This is regarded
as bound water and controls the dough’s consistency.
As bound water layers are ‘stacked up,’ some of the
water is held less and less strongly, resulting in water
that can escape (evaporation) and/or migrate as
free water. Water activity (a
w
) is an important way
to measure and monitor water’s mobility in baked
products.
Making Biscuits Lighter
0021Leavening agents aerate the dough or batter to make
it light and porous. The leavening action is respon-
sible for good volume, improved eating quality, and a
uniform cell structure. Leavening can be achieved by
various methods, including yeast fermentation, the
mechanical incorporation of air by mixing and
creaming, formation of water vapor during baking,
and the creation of carbon dioxide and/or ammonia
by chemical leaveners. However, creation of the
initial air bubbles during the mixing phase is critical
before any of the other leavening agents can take
effect. (See Leavening Agents.)
0022Small products like biscuits that bake quickly need
a fast-acting leavener that will release the gas before
the structure sets. The most widely used source of
carbon dioxide in chemically leavened systems is the
reaction of sodium bicarbonate or baking soda
(NaHCO
3
) with an acid, usually the acidic salt of
a weak mineral acid. The leavening acid promotes a
controlled and nearly complete evolution of carbon
dioxide from sodium bicarbonate in an aqueous solu-
tion. Some examples include monocalcium phosphate
monohydrate (CaH
4
PO
4
)
2
.H
2
O), sodium acid pyro-
phosphate (Na
2
H
2
P
2
O
7
) and potassium acid tartrate
(KHC
4
H
4
O
6
). When these agents combine with
water, they react to form controlled amounts of
carbon dioxide. Sodium bicarbonate also raises
dough pH.
0023Ammonium bicarbonate (NH
4
HCO
3
) generates
carbon dioxide, ammonia, and steam when heated.
It increases spread and gives a larger, more desirable
surface ‘crack’ in some types of hard, high-sugar bis-
cuits. However, it can be used only with low-moisture
biscuits that are baked sufficiently to drive off all
residual ammonia.
Other Ingredients
0024Milk products, eggs, and salt are added for variety.
Milk and eggs are viewed as wholesome ingredients
by consumers; however, they are among the most
expensive.
0025Milk and whey are good sources of protein and
lactose, which aid in shape retention and browning
reactions. They add flavor and nutrients, improve
texture, crust color, moisture retention, and control
spread. They are usually added in dried form. (See
Whey and Whey Powders: Production and Uses.)
0026Eggs contribute color, structure, nutritional value,
and some flavor. They affect texture as a result of
their emulsifying, tenderizing, leavening, and binding
actions. The form of eggs used can be fortified or
whole components (yolks and whites) in the liquid,
frozen or dried state, or combined with sugar.
536 BISCUITS, COOKIES, AND CRACKERS/Chemistry of Biscuit Making