
nitrogen, sulfur, and oxygen contribute to increasing
hysteresis losses, because they form precipitates that
act as pinning centers on moving domain walls. They
also have an indirect detrimental effect, because they
hinder grain growth and negatively affect the forma-
tion of favorable textures. Finally, the control of grain
size is important. The hysteresis loss is a decreasing
function of the average grain size s, and usually follows
a law of the type P
h
Da þb/s,wherea and b are ma-
terial-dependent constants. Conversely, the excess loss
is an increasing function of s,ofthetypeP
exc
Dks
b
,
with bB1/2. As a result, the total loss has a minimum
for a particular grain size. Material manufacturers try
to obtain materials with optimal loss performance by
appropriate grain-growth treatments. The optimal
grain size is of the order of 150 mm at 1.5 T and 50 Hz.
Contrary to nonoriented steels, grain-oriented steels
are characterized by strongly anisotropic properties.
These materials contain between 2.9 and 3.2 wt.% Si.
As the result of highly sophisticated metallurgical
processes of selective grain growth, a grain-oriented
lamination is characterized by a particular texture,
known as Goss texture, in which all the crystal grains
have one of their [001] axes close to the lamination
rolling direction. This fact, together with the large
grain size of these materials (in the millimeter–centi-
meter range) and the low impurity content yields hys-
teresis losses about one order of magnitude lower
than those typical of nonoriented steels, when the
lamination is magnetized along the rolling direction.
Grain-oriented steels are further subdivided into con-
ventional grain-oriented (CGO) and high-permea-
bility grain-oriented (HGO) materials.
The main difference is the more accurate texture
control realized in HGO materials which yields better
loss performance. In CGO steels, the lamination
thickness ranges from 0.35 to 0.23 mm and the loss
accordingly ranges from 1.4 to 1.15 Wkg
1
at 1.7 T
and 50 Hz. In HGO steels, the lamination thickness
ranges from 0.30 to 0.23 mm and the loss from 1.05 to
0.80 Wkg
1
at 1.7 T and 50 Hz. The more refined
texture control of HGO materials is reflected in the
magnetic domain structure. In fact, the nearly perfect
grain orientation yields very regular structures of
wide longitudinal bar-like domains, quite similar to
the ones assumed in the calculation of Eqn. (9). The
regularity of the domain structure and the material
perfection (very low impurity content and lack of
grain boundary effects because of the large grain size)
give a very low hysteresis loss. However, as shown by
Eqn. (9), the excess loss may attain substantial values
when wide domains are present (2L/db1).
For this reason, methods aimed at artificially re-
ducing the domain size without altering the hysteresis
loss have been developed. Two of them are of par-
ticular interest:
*
deposition of a coating on the lamination sur-
face that exerts a tensile stress of 2–10 MPa on
the material. The stress introduces a magnetoelastic
energy contribution that alters the energy balance in
the material and favors the formation of smaller
magnetic domains;
*
scribing of the lamination surface by one among
many possible techniques (mechanical scratching,
laser irradiation, plasma jet scribing, or etch pitting).
Scribing alters the magnetoelastic and magnetostatic
energy content of the lamination in a way that again
favors the formation of smaller domains.
The power loss at 1.7 T and 50 Hz is as low as
0.80 Wkg
1
in coated, scribed laminations of 0.23 mm
thickness.
2.3 Rapidly Solidified Materials
Soft magnetic materials can be prepared as very thin
ribbons by means of rapid solidification methods, in
particular by planar-flow-casting. The resulting rib-
bons have variable width (up to 20 cm and more) and
a thickness of 10–100 mm. The reduced thickness in-
hibits classical losses (see Fig. 3) and makes these
materials suited to high-frequency applications,
where classical losses play the most detrimental role.
On the other hand, rapid solidification permits the
preparation of materials in a variety of quenched
metastable states not present in the equilibrium phase
diagram, which display a broad range of interesting
magnetic and mechanical properties.
Amorphous ribbons, lacking long-range atomic
order, are prepared by rapid solidification of alloys
containing around 80 at.% transition metals and
20 at.% metalloids (B, Si, P, C). The lack of atomic
order yields electrical resistivities two to three times
larger than the corresponding crystalline alloy (typ-
ical values are in the range 120–140 10
8
Om), with
important benefits for losses. At the same time,
atomic disorder leads to a random distribution of
local magnetic anisotropy, which is averaged to zero
over the typical distances involved in magnetization
processes, a fact that yields magnetic softness and low
hysteresis loss. Magnetic softness is further enhanced
in materials with vanishing magnetostriction, because
the absence of magnetoelastic coupling eliminates the
pinning action of internal stresses. In Fe
78
B
13
Si
9
amorphous ribbons 25 mm thick, power losses attain
values around 0.25 Wkg
1
at 1.4 T and 50 Hz. Of this,
the main contribution comes from the hysteresis
component (compare Fig. 3). A similar behavior is
exhibited by nanocrystalline materials (grain dimen-
sion of the order of 10 nm) obtained by suitable an-
nealing of amorphous materials of appropriate
composition (Fe
73.5
Cu
1
Nb
3
Si
13.5
B
9
in so-called Fine-
met materials) (see also Amorphous and Nanocrystal-
line Materials).
Rapidly solidified Fe–6.5 wt.% Si materials exhibit a
favorable combination of high resistivity, low magne-
tocrystalline anisotropy, and vanishing magnetostrict-
ion, which contribute to lowering losses. Materials
468
Magnetic Los ses