Bergaya F. Handbook of Clay Science

Подождите немного. Документ загружается.

Kaneyoshi, M., Jones, W., 1998. Exchange of interlayer terephthalate anions from a Mg–Al

layered double hydroxide: formation of intermediate interstratiﬁed phases. Chemical

Physics Letters 296, 183–186.

Kanezaki, E., 1998a. A thermally induced metastable solid phase of Mg/Al-layered double

hydroxides by means of in situ high temperature powder X-ray diffraction. Journal of

Materials Science Letters 17, 371–374.

Kanezaki, E., 1998b. Effect of atomic ratio Mg/Al in layers of Mg and Al layered double

hydroxide on thermal stability of hydrotalcite-like layered structure by means of in situ

high temperature powder X-ray diffraction. Materials Research Bulletin 33, 773–778.

Kanezaki, E., 1998c. Thermal behavior of the hydrotalcite-like layered structure of Mg and

Al-layered double hydroxides with interlayer carbonate by means of in situ powder

HTXRD and DTA/TG. Solid State Ionics 106, 279–284.

Kannan, S., Narayanan, A., Swamy, C.S., 1996. Effect of composition on the physicoche-

mical properties of nickel aluminium hydrotalcites. Journal of Materials Science 31,

2353–2360.

Kannan, S., Swamy, C.S., 1992. Synthesis and physicochemical characterization of cobalt

aluminium hydrotalcite. Journal of Materials Science Letters 11, 1585–1587.

Kannan, S., Swamy, C.S., 1994. Catalytic decomposition of nitrous oxide on ‘‘in situ’’ gen-

erated thermally calcined hydrotalcites. Applied Catalysis B: Environmental 3, 109–116.

Kannan, S., Velu, S., Ramkumar, V., Swamy, C.S., 1995. Synthesis and physicochemical

properties of cobalt aluminium hydrotalcites. Journal of Materials Science 30, 1462–1468.

Kannan, S., Vir Jasra, R., 2000. Microwave assisted rapid crystallization of Mg–M(III) hy-

drotalcite where M(III)QAl, Fe or Cr. Journal of Materials Chemistry 10, 2311–2314.

Kapteijn, F., Rodriguez-Mirasol, J., Moulijn, J.A., 1996. Heterogeneous catalytic decompo-

sition of nitrous oxide. Applied Catalysis B: Environmental 9, 25–64.

Kelkar, C.P., Schutz, A.A., 1997a. Ni-, Mg- and Co-containing hydrotalcite-like materials

with a sheet-like morphology: synthesis and characterization. Microporous Materials 10,

163–172.

Kelkar, C.P., Schutz, A.A., Cullo, L.A., 1997b. Synthesis of hydrotalcite-like materials with a

sheet-like morphology. Chemical Industries (Dekker) 69(Synthesis of Porous Materials),

691–703.

Khaldi, M., Badreddine, M., Legrouri, A., Chaouch, M., Barroug, A., de Roy, A., Besse,

J.-P., 1998. Preparation of a well-ordered layered nanocomposite from zinc–alumi-

num–chloride layered double hydroxide and hydrogenophosphate by ion exchange. Ma-

terials Research Bulletin 33, 1835–1843.

Khaldi, M., de Roy, A., Chaouch, M., Besse, J.-P., 1997. New varieties of zinc–chro-

mium–sulfate lamellar double hydroxides. Journal of Solid State Chemistry 130, 66–73.

Khan, A.I., Lei, L., Norquist, A.J., O’Hare, D., 2001. Intercalation and controlled release of

pharmaceutically active compounds from a layered double hydroxide. Chemical Commu-

nications, 2342–2343.

Khan, A.I., O’Hare, D., 2002. Intercalation chemistry of layered double hydroxides: recent

developments and applications. Journal of Materials Chemistry 12, 3191–3198.

Kirkpatrick, R.J., Yu, P., Hou, X., Kim, Y., 1999. Interlayer structure, anion dynamics, and

phase transitions in mixed-metal layered hydroxides: variable temperature

Cl NMR

spectroscopy of hydrotalcite and Ca-aluminate hydrate (hydrocalumite). American Min-

eralogist 84, 1186–1190.

References 1081

Kloprogge, J.T., Frost, R.L., 1999. Fourier transform infrared and Raman spectroscopic

study of the local structure of Mg-, Ni-, and Co-hydrotalcites. Journal of Solid State

Chemistry 146, 506–515.

Kloprogge, J.T., Frost, R.L., 2001. Infrared and Raman spectroscopic studies of layered

double hydroxides (LDHs). In: Rives, V. (Ed.), Layered Double Hydroxides. Nova Science

Publishers, Huntington, pp. 139–192.

Kloprogge, J.T., Hickey, L., Frost, R.L., 2001. Heating stage Raman and infrared emission

spectroscopic study of the dehydroxylation of synthetic Mg-hydrotalcite. Applied Clay

Science 18, 37–49.

Kloprogge, J.T., Wharton, D., Hickey, L., Frost, R.L., 2002. Infrared and Raman study of

interlayer anions CO

2

,NO



,SO

2

and ClO



in Mg/Al-hydrotalcite. American Miner-

alogist 87, 623–629.

Komarneni, S., Kozai, N., Roy, R., 1998. Novel function for anionic clays: selective

transition metal cation uptake by diadochy. Journal of Materials Chemistry 8,

1329–1331.

Kooli, F., Chisem, I.C., Vucelic, M., Jones, W., 1996. Synthesis and properties of terephtha-

late and benzoate intercalates of Mg–Al layered double hydroxides possessing varying layer

charge. Chemistry of Materials 8, 1969–1977.

Kooli, F., Depe

ge, C., Ennaqadi, A., de Roy, A., Besse, J.-P., 1997a. Rehydration of Zn–Al

layered double hydroxides. Clays and Clay Minerals 45, 92–98.

Kooli, F., Jones, W., 1995. Direct synthesis of polyoxovanadate-pillared layered double hy-

droxides. Inorganic Chemistry 34, 6237–6238.

Kooli, F., Jones, W., Rives, V., Ulibarri, M.A., 1997b. An alternative route to polyoxom-

etalate-exchanged layered double hydroxides: the use of ultrasound. Journal of Materials

Science Letters 16, 27–29.

Kooli, F., Martin, C., Rives, V., 1997c. FT-IR spectroscopy study of surface acidity and iso-

propanol decomposition on mixed oxides obtained upon calcination of layered double

hydroxides. Langmuir 13, 2303–2306.

Kooli, F., Rives, V., Ulibarri, M.A., 1994. Vanadate-pillared hydrotalcite containing tran-

sition metal cations. Materials Science Forum, 152–153 (Soft Chemistry Routes to New

Materials), 375–378.

Kooli, F., Rives, V., Ulibarri, M.A., 1995. Preparation and study of decavanadate-pillared

hydrotalcite-like anionic clays containing transition metal cations in the layers. 1. Samples

containing nickel-aluminum prepared by anionic exchange and reconstruction. Inorganic

Chemistry 34, 5114–5121.

Kopka, H., Beneke, K., Lagaly, G., 1988. Anionic surfactants between double metal hy-

droxide layers. Journal of Colloid and Interface Science 123, 427–436.

Kuk, W.-K., Huh, Y.-D., 1998. Preferential intercalation of organic anions into layered dou-

ble hydroxide. Bulletin of the Korean Chemical Society 19, 1032–1036.

Kuzel, H.J., Baier, H., 1996. Hydration of calcium aluminate cements in the presence of

calcium carbonate. European Journal of Mineralogy 8, 129–141.

Kwon, T., Pinnavaia, T.J., 1992. Synthesis and properties of anionic clays pillared by

[XM

]

n

Keggin ions. Journal of Molecular Catalysis 74, 23–33.

Kwon, T., Tsigdinos, G.A., Pinnavaia, T.J., 1988. Pillaring of layered double hydroxides

(LDHs) by polyoxometalate anions. Journal of the American Chemical Society 110,

3653–3654.

Chapter 13.1: Layered Double Hydroxides1082

Labajos, F.M., Rives, V., 1996. Thermal evolution of chromium(III) ions in hydrotalcite-like

compounds. Inorganic Chemistry 35, 5313–5318.

Labajos, F.M., Rives, V., Malet, P., Centeno, M.A., Ulibarri, M.A., 1996. Synthesis and

characterization of hydrotalcite-like compounds containing V

in the layers and of their

calcination products. Inorganic Chemistry 35, 1154–1160.

Labajos, F.M., Rives, V., Ulibarri, M.A., 1992. Effect of hydrothermal and thermal treat-

ments on the physicochemical properties of Mg–Al hydrotalcite-like materials. Journal of

Materials Science 27, 1546–1552.

Lagaly, G., Mecking, O., Penner, D., 2001a. Colloidal magnesium aluminum hydroxide and

heterocoagulation with a clay mineral. I. Properties of colloidal magnesium aluminum

hydroxide. Colloid and Polymer Science 279, 1090–1096.

Lagaly, G., Mecking, O., Penner, D., 2001b. Colloidal magnesium aluminum hydroxide and

heterocoagulation with a clay mineral. II. Heterocoagulation with sodium montmorillo-

nite. Colloid and Polymer Science 279, 1097–1103.

Lakraimi, M., Legrouri, A., Barroug, A., de Roy, A., Besse, J.-P., 1999. Removal of pesticides

from water by anionic clays. Journal de Chimie Physique et de Physico-Chimie Biologique

96, 470–478.

Latterini, L., Elisei, F., Aloisi, G.G., Costantino, U., Nocchetti, M., 2002. Space-resolved

ﬂuorescence properties of phenolphthalein-hydrotalcite nanocomposites. Physical Chem-

istry Chemical Physics 4, 2792–2798.

Legrouri, A., Badreddine, M., Barroug, A., de Roy, A., Besse, J.-P., 1999. Inﬂuence of pH on

the synthesis of the Zn–Al–nitrate layered double hydroxide and the exchange of nitrate by

phosphate ions. Journal of Materials Science Letters 18, 1077–1079.

Lehmann, M., Zouboulis, A.I., Matis, K.A., 1999. Removal of metal ions from dilute aqu-

eous solutions: a comparative study of inorganic sorbent materials. Chemosphere 39,

881–892.

Leroux, F., Adachi-Pagano, M., Intissar, M., Chauvie

re, S., Forano, C., Besse, J.-P., 2001a.

Delamination and restacking of layered double hydroxides. Journal of Materials Chemistry

11, 105–112.

Leroux, F., Besse, J.-P., 2001. Polymer interleaved layered double hydroxide: a new emerging

class of nanocomposites. Chemistry of Materials 13, 3507–3515.

Leroux, F., Moujahid, M., Roussel, H., Flank, A.-M., Briois, V., Besse, J.-P., 2002. Local

order of the transition metals for the substitution (Co

1y

)

Al(OH)

Cl nH

O(0oyo1)

in a copper–aluminium layered double hydroxide-like phase. Clays and Clay Minerals 50,

260–270.

Leroux, F., Moujahid, M., Taviot-Gue

ho, C., Besse, J.-P., 2001b. Effect of layer charge

modiﬁcation for Co-Al layered double hydroxides: study by X-ray absorption spectros-

copy. Solid State Science 3, 81–92.

Li, Y., Chen, J., Qin, Y., Chang, L., 2000. Simultaneous production of hydrogen and nano-

carbon from decomposition of methane on a nickel-based catalyst. Energy and Fuels 14,

1188–1194.

Lopez, T., Bosh, P., Ramos, E., Gomez, R., Novaro, O., Acosta, D., Figueras, F., 1996.

Synthesis and characterization of sol-gel hydrotalcites. Structure and texture. Langmuir 12,

189–192.

Lopez, T., Ramos, E., Bosh, P., Asomoza, M., Gomez, R., 1997. DTA and TGA charac-

terization of sol-gel hydrotalcites. Materials Letters 30, 279–282.

References 1083

Lopez-Salinas, E., Abasolo, J.A., Acosta, D.R., 1998. Electron microscopy studies of a gal-

lium substituted synthetic hydrotalcite-like-compound. In: Benavides, C., Hector, A.,

Yacaman, J., M. (Eds.), Electron Microscopy 1998, Proceedings of the 14th International

Congress on Electron Microscopy, Cancun, Mexico, vol. 3. Institute of Physics Publishing,

Bristol, pp. 339–340.

Lopez-Salinas, E., Garcia-Sanchez, M., Llanos-Serrano, M., Navarrete-Bolanoz, J., 1997a.

Formation of base sites on calcined Mg–Ga hydrotalicte-like [Mg

1x

(OH)

]

(CO

)

x/2

H

O. Journal of Physical Chemistry, B 101, 5112–5117.

Lopez-Salinas, E., Garcia-Sanchez, M., Montoya, J.A., Acosta, D.R., Abasolo, J.A., Schifter,

I., 1997b. Structural characterization of synthetic hydrotalcite-like [Mg

1x

(OH)

]

(CO

)

x/2

H

O. Langmuir 13, 4748–4753.

Lopez-Salinas, E., Garcia-Sanchez, M., Ramon-Garcia, M.L., Schifter, I., 1996. New gallium-

substituted hydrotalcites: [Mg1-xGax(OH)2](CO3) x/2 mH2O. Journal of Porous Mate-

rials 3, 169–174.

Lopez-Salinas, E., Torres-Garcı

a, E., Garcı

a-Sa

nchez, M., 1997c. Thermal behavior of hy-

drotalcite-like [Mg

1x

(OH)

](CO

)

x/2

mH

O as a function of gallium content. Journal

of Physics and Chemistry of Solids 58, 919–925.

Lotsch, B., Millange, F., Walton, R.I., O’Hare, D., 2001. Separation of nucleoside mono-

phosphates using preferential anion exchange intercalation in layered double hydroxides.

Solid State Sciences 3, 883–886.

Lwin, Y., Yarmo, M.A., Yaakob, Z., Mohamad, A.B., Ramli Wan Daud, W., 2001. Synthesis

and characterization of Cu–Al layered double hydroxides. Materials Research Bulletin 36,

193–198.

MacKenzie, K.J.D., Meinhold, R.H., Sherriff, B.L., Xu, Z., 1993.

Al and

Mg solid-state

magic-angle spinning nuclear magnetic resonance study of hydrotalcite and its thermal

decomposition sequence. Journal of Materials Chemistry 3, 1263–1269.

Malherbe, F., Besse, J.-P., 2000. Investigating the effects of guest–host interactions on the prop-

erties of anion-exchanged Mg–Al hydrotalcites. Journal of Solid State Chemistry 155, 332–341.

Malherbe, F., Bigey, L., Forano, C., de Roy, A., Besse, J.-P., 1999. Structural aspects and

thermal properties of takovite-like layered double hydroxides pillared with chromium oxo-

anions. Journal of the Chemical Society, Dalton Transactions 21, 3831–3839.

Malherbe, F., Depe

ge, C., Forano, C., Besse, J.-P., Atkins, M.P., Sharma, B., Wade, S.R.,

1998. Alkoxylation reaction catalyzed by layered double hydroxides. Applied Clay Science

13, 451–466.

Malherbe, F., Forano, C., Besse, J.-P., 1997. Use of organic media to modify the surface and

porosity properties of hydrotalcite-like compounds. Microporous Materials 10, 67–84.

Marchi, A.J., Apesteguı

a, C.R., 1998. Impregnation-induced memory effect of thermally ac-

tivated layered double hydroxides. Applied Clay Science 13, 35–48.

Marquevich, M., Farriol, X., Medina, F., Montane

, D., 2001. Hydrogen production by steam

reforming of vegetable oils using nickel-based catalysts. Industrial and Engineering Chem-

istry Research 40, 4757–4766.

Martin, K.J., Pinnavaia, T.J., 1986. Layered double hydroxides as supported anionic reagents.

Halide-ion reactivity in zinc chromium hexahydroxide halide hydrates [Zn

Cr(OH)

X 

O] (X ¼ Cl, I). Journal of the American Chemical Society 108, 541–542.

Mascolo, G., 1995. Synthesis of anionic clays by hydrothermal crystallization of amorphous

precursors. Applied Clay Science 10, 21–30.

Chapter 13.1: Layered Double Hydroxides1084

Mendiboure, A., Scho

llhorn, R., 1987. Formation and anion exchange reactions of layered

transition metal hydroxides [Ni

1x

](OH)

(CO

)

x/2

(M ¼ iron, cobalt). Revue de

Chimie Minerale 23, 819–827.

trier, M., Han, K.S., Guerlou-Delourgues, L., Delmas, C., 1997. Vanadate-inserted lay-

ered double hydroxides: A (51)V NMR investigation of the grafting process. Inorganic

Chemistry 36, 2441–2445.

Messersmith, P.B., Stupp, S.I., 1995. High-temperature chemical and microstructural

transformations of a nanocomposite organoceramic. Chemistry of Materials 7, 454–460.

Meyn, M., Beneke, K., Lagaly, G., 1990. Anion-exchange reactions of layered double hy-

droxides. Inorganic Chemistry 29, 5201–5207.

Meyn, M., Beneke, K., Lagaly, G., 1993. Anion-exchange reactions of layered double salts.

Inorganic Chemistry 32, 1209–1215.

Millange, F., Walton, R.I., O’Hare, D., 2000. Time-resolved in situ X-ray diffraction study of

the liquid-phase reconstruction of Mg–Al–carbonate hydrotalcite-like compounds. Journal

of Materials Chemistry 10, 1713–1720.

Miyata, S., 1983. Anion-exchange properties of hydrotalcite-like compounds. Clays and Clay

Minerals 31, 305–311.

Miyata, S., 1991. Properties and applications of hydrotalcite-type minerals. Zeoraito 8, 7–16.

Miyata, S., 1980. Physico-chemical properties of synthetic hydrotalcites in relation to com-

position. Clays and Clay Minerals 28, 50–56.

Miyata, S., Hirose, T., 1978. Adsorption of N

,CO

, and H

on hydrotalcite-like system:

–Al

–(Fe(CN)

)

4

. Clays and Clay Minerals 26, 441–447.

Mohmel, S., Kurzawski, I., Uecker, D., Muller, D., Gessner, W., 2002. The inﬂuence of a

hydrothermal treatment using microwave heating on the crystallinity of layered double

hydroxides. Crystal Research and Technology 37, 359–369.

Moneyron, J.E., de Roy, A., Besse, J.-P., 1990. Realisation of hydrotalcite-type protonic

conductor thick ﬁlms by the screen-printing technique. Hybrid Circuits 22, 25–28.

Moneyron, J.E., de Roy, A., Besse, J.-P., 1991a. Protonic conductivity of hydrotalcite-

type compound thick ﬁlms: application to a humidity sensor. Solid State Ionics 46,

175–181.

Moneyron, J.E., de Roy, A., Besse, J.-P., 1991b. Realisation of a humidity sensor based on the

protonic conductor Zn

Al(OH)

Cl nH

O. Hybrid Circuits 24, 26–31.

Moneyron, J.E., De Roy, A., Besse, J.-P., 1991c. Realization of a humidity sensor. Sensors

and Actuators B 4, 189–194.

Montanari, B., Vaccari, A., Gazzano, M., Ka

Xner, P., Papp, H., Pasel, J., Dziembaj, R.,

Makowski, W., Lojewski, T., 1997. Characterization and activity of novel copper-con-

taining catalysts for selective catalytic reduction of NO with NH

. Applied Catalysis B:

Environmental 13, 205–217.

Morigi, M., Scavetta, E., Berrettoni, M., Giorgetti, M., Tonelli, D., 2001. Sulfate-selective

electrodes based on hydrotalcites. Analytica Chimica Acta 439, 265–272.

Mori, K., Nakamura, Y., Kikuchi, I., 1981. Modiﬁcation of poly(vinyl chloride): XLI. Effect

of hydrotalcite on the stabilization of poly(vinyl chloride) by 6-anilino-1,3,5-triazine-2,4-

dithiol and zinc stearate. Journal of Polymer Science: Polymer Letters Edition 19, 623–628.

Morioka, H., Tagaya, H., Karasu, M., Kadokawa, J., Chiba, K., 1995. Preparation of new

useful materials by surface modiﬁcation of inorganic layered compound. Journal of Solid

State Chemistry 117, 337–342.

References 1085

Morpurgo, S., Jacono, M.L., Porta, P., 1996. Copper–zinc–cobalt–aluminium–chromium

hydroxycarbonates and mixed oxides. Journal of Solid State Chemistry 122, 324–332.

Moujahid, M., Besse, J.-P., Leroux, F., 2002a. Synthesis and characterization of polystyrene

sulfonate layered double hydroxide nanocomposite. In-situ polymerization versus polymer

incorporation. Journal of Materials Chemistry 12, 3324–3330.

Moujahid, M., Besse, J.-P., Leroux, F., 2003. Polystyrene sulfonate layered double hydroxide

nanocomposites. Stability and subsequent structural transformation in temperature. Jour-

nal of Materials Chemistry 13, 258–264.

Moujahid, M.E., Dubois, M., Besse, J.-P., Leroux, F., 2002b. The role of atmospheric oxygen

for the polymerization of interleaved aniline sulfonic in LDH. Chemistry of Materials 14,

3799–3807.

Mousty, C., Therias, S., Forano, C., Besse, J.-P., 1994. Anion-exchanging clay-modiﬁed elec-

trodes: synthetic layered double hydroxides intercalated with electroactive organic anions.

Journal of Electroanalytical Chemistry 374, 63–69.

Narita, E., Kaviratna, P., Pinnavaia, T.J., 1991. Synthesis of heteropolyoxometalate pillared

layered double hydroxides via calcined zinc–aluminium oxide precursors. Chemistry Let-

ters 805–808.

Neuha

usler, U., Abend, S., Jacobsen, C., Lagaly, G., 1999. Soft X-ray spectromicroscopy on

solid-stabilized emulsions. Colloid and Polymer Science 277, 719–726.

Newman, A.C.D., 1987. Chemistry of Clays and Clay Minerals. Wiley-Interscience, New

York.

Newman, S.P., Greewell, H.C., Coveny, P.V., Jones, W., 2001. Computer modelling of layered

double hydroxides. In: Rives, V. (Ed.), Layered Double Hydroxides. Nova Science Pub-

lishers, Huntington, pp. 93–114.

Newman, S.P., Jones, W., 1998. Synthesis, characterization and applications of layered

double hydroxides containing organic guests. New Journal of Chemistry 22,

105–115.

Newman, S.P., Jones, W., 2002. Layered double hydroxides as templates for the formation

of supramolecular structures. In: Jones, W., Rao, C.N.R. (Eds.), Supramolec-

ular Organization and Materials Design. Cambridge University Press, Cambridge.

Newman, S.P., Jones, W., O’Connor, P., Stamires, D.N., 2002b. Synthesis of the 3R

polytype

of a hydrotalcite-like mineral. Journal of Materials Chemistry 12, 153–155.

Nijs, H., Clearﬁeld, A., Vansant, E.F., 1998. The intercalation of phenylphosphonic acid in

layered double hydroxides. Microporous and Mesoporous Materials 23, 97–108.

Nijs, H., De Bock, M., Vansant, E.F., 1999. Evaluation of the microporosity of pillared

[Fe(CN)6]-MgAl-LDHs. Microporous and Mesoporous Materials 30, 243–253.

Ogawa, M., Kaiho, H., 2002. Homogeneous precipitation of uniform hydrotalcite particles.

Langmuir 18, 4240–4242.

Hare, D., Evans, J.S.O., Fogg, A.M., O’Brien, S., 2000. Time-resolved, in situ X-ray

diffraction studies of intercalation in lamellar hosts. Polyhedron 19, 297–305.

Oh, J.-M., Hwang, S.-H., Choy, J.-H., 2002. The effect of synthetic conditions on tailoring the

size of hydrotalcite particles. Solid State Ionics 151, 285–291.

O’Leary, S., O’Hare, D., Seeley, G., 2002. Delamination of layered double hydroxides in polar

monomers: new LDH–acrylate nanocomposites. Chemical Communications, 1506–1507.

Olguı

n, M.T., Bosch, P., Acosta, D., Bulbulian, S., 1998.

131



sorption by thermally treated

hydrotalcites. Clays and Clay Minerals 46, 567–573.

Chapter 13.1: Layered Double Hydroxides1086

Olsbye, U., Akporiaye, D., Rytter, E., Rønnekleiv, M., Tangstad, E., 2002. On the stability of

mixed M

oxides. Applied Catalysis A: General 224, 39–49.

Ono, Y., Baba, T., 1997. Selective reactions over solid base catalysts. Catalysis Today 38,

321–337.

Oriakhi, C.O., Faar, I.V., Lerner, M.M., 1996. Incorporation of poly(acrylic acid), poly

(vinylsulfonate) and poly(styrenesulfonate) within layered double hydroxides. Journal of

Materials Chemistry 6, 103–107.

Oriakhi, C.O., Faar, I.V., Lerner, M.M., 1997. Thermal characterization of poly(styrene

sulfonate)/layered double hydroxide nanocomposites. Clays and Clay Minerals 45,

194–202.

Palomares, A.E., Lo

pez-Nieto, J.M., La

zaro, F.J., Lo

pez, A., Corma, A., 1999. Reactivity in

the removal of SO

and NO

on Co/Mg/Al mixed oxides derived from hydrotalcites.

Applied Catalysis B: Environmental 20, 257–266.

Parker, L.M., Milestone, N.B., Newman, R.H., 1995. The use of hydrotalcite as an anion

absorbent. Industrial and Engineering Chemistry Research 34, 1196–1202.

Passaglia, E., Sacerdoti, M., 1988. Hydrocalumite from Montalto di Castro, Viterbo, Italy.

Neues Jahrbuch fuer Mineralogie, Monatshefte (10), 454–461.

Paul, M., Glasser, F.P., 2000. Impact of prolonged warm (85 1C) moist cure on Portland

cement paste. Cement and Concrete Research 30, 1869–1877.

Pausch, I., Lohse, H.H., Schu

rmann, K., Allmann, R., 1986. Syntheses of disordered and A1-

rich hydrotalcite-like compounds. Clays and Clay Minerals 34, 507–510.

Pavan, P.C., Crepaldi, E.L., Gomes, G.deA., Valim, J.B., 1999. Adsorption of sodium do-

decylsulfate on a hydrotalcite-like compound: effect of temperature, pH and ionic strength.

Colloids and Surfaces A: Physicochemical and Engineering Aspects 154, 399–410.

Pavan, P.C., Crepaldi, E.L., Valim, J.B., 2000. Sorption of anionic surfactants on layered

double hydroxides. Journal of Colloid and Interface Science 229, 346–352.

Pavan, P.C., Gomes, G.deA., Valim, J.B., 1998. Adsorption of sodium dodecyl sulfate on

layered double hydroxides. Microporous and Mesoporous Materials 21, 659–665.

rez-Ramı

rez, J., Mul, G., Kapteijn, F., Moulijn, J.A., 2001a. On the stability of the ther-

mally decomposed Co–Al hydrotalcite against retrotopotactic transformation. Materials

Research Bulletin 36, 1767–1775.

rez-Ramı

rez, J., Mul, G., Kapteijn, F., Moulijn, J.A., 2001b. A spectroscopic study of the

effect of the trivalent cation on the thermal decomposition behaviour of Co-based hy-

drotalcites. Journal of Materials Chemistry 11, 2529–2536.

rez-Ramı

rez, J., Mul, G., Kapteijn, F., Moulijn, J.A., 2001c. In situ investigation of the

thermal decomposition of Co–Al hydrotalcite in different atmospheres. Journal of Ma-

terials Chemistry 11, 821–830.

rez-Ramı

rez, J., Mul, G., Moulijn, J.A., 2001d. In situ Fourier transform infrared and laser

Raman spectroscopic study of the thermal decomposition of Co–Al and Ni–Al hydrotal-

cites. Vibrational Spectroscopy 27, 75–88.

rez-Ramı

rez, J., Overeijnder, J., Kapteijn, F., Moulijn, J.A., 1999. Structural promotion

and stabilizing effect of Mg in the catalytic decomposition of nitrous oxide over calcined

hydrotalcite-like compounds. Applied Catalysis B: Environmental 23, 59–72.

Pesic, L., Salipurovic, S., Markovic, V., Vucelic, D., Kagunya, W., Jones, W., 1992. Thermal

characteristics of a synthetic hydrotalcite-like material. Journal of Materials Chemistry 2,

1069–1073.

References 1087

Pinnavaia, T.J., 1987. Swelling clays and related complex layered oxides. NATO ASI, Ser. B

172, 233–252.

Pinnavaia, T.J., 1995. Nanoporous layered materials. Materials Chemistry: Advances in

Chemistry Series 245, 283–300.

Pitsch, S., Eschenmoser, A., Gedulin, B., Hui, S., Arrhenius, G., 1995. Mineral induced

formation of sugar phosphates. Origin of Life and Evolution of the Biosphere 25, 297–334.

Pre

vot, V., Forano, C., Besse, J.-P., 2001. Hybrid derivatives of layered double hydroxides.

Applied Clay Science 18, 3–15.

Pre

vot, V., Forano, C., Besse, J.-P., Abraham, F., 1998. Syntheses and thermal and chemical

behaviors of tartrate and succinate intercalated Zn

Al and Zn

Cr layered double hydrox-

ides. Inorganic Chemistry 37, 4293–4301.

Prinetto, F., Ghiotti, G., Durand, R., Tichit, D., 2000a. Investigation of acid-base properties

of catalysts obtained from layered double hydroxides. Journal of Physical Chemistry B 104,

11117–11126.

Prinetto, F., Ghiotti, G., Grafﬁn, P., Tichit, D., 2000b. Synthesis and characterization of sol-

gel Mg/Al and Ni/Al layered double hydroxides and comparison with co-precipitated

samples. Microporous and Mesoporous Materials 39, 229–247.

Putyera, K., Bandosz, T.J., Jagieo, J., Schwarz, J.A., 1996. Effect of template constraints on

adsorption properties of synthetic carbons prepared within the gallery of layered double

hydroxides. Carbon 34, 1559–1567.

Qiu, J., Villemure, G., 1995. Anionic clay modiﬁed electrodes: electrochemical activity of

nickel(II) sites in layered double hydroxide ﬁlms. Journal of Electroanalytical Chemistry

395, 159–166.

Raja, T., Santhanalakshmi, J., 1996. Physico-chemical studies on synthetic disordered Ni–Fe

layered double hydroxides. Journal of Materials Science Letters 15, 718–720.

Rankin, B.J., Zhu, H., Webb, M., Roberts, N.B., 2001. The development and in-vitro eval-

uation of novel mixed metal hydroxy-carbonate compounds as phosphate binders. Journal

of Pharmacy and Pharmacology 53, 361–369.

Rebours, B., de la Caillerie, J.-B.D., Clause, O., 1994. Decoration of nickel and magnesium

oxide crystallites with spinel-type phases. Journal of the American Chemical Society 116,

1707–1717.

Refait, Ph., Ge

nin, J.-M.R., 1997. Mechanisms of oxidation of Ni(II)–Fe(II) hydroxides in

chloride-containing aqueous media: role of the pyroaurite-type Ni–Fe hydroxychlorides.

Clay Minerals 32, 597–613.

Renaudin, G., Franc- ois, M., 1999. The lamellar double-hydroxide (LDH) compound with

composition 3CaO Al2O3 Ca(NO3)2 10H2O. Acta Crystallographica Section C 55,

835–841.

Ren, L., He, J., Evans, D.G., Duan, X., Ma, R., 2001. Some factors affecting the immo-

bilization of penicillin G acylase on calcined layered double hydroxides. Journal of Mo-

lecular Catalysis B: Enzymatic 16, 65–71.

Ren, Q., Luo, Q., Wu, H., Chen, S., 2002. Preparation and thermal property of the acicular

Mg,Al-hydrotalcite. Key Engineering Materials, 224–226 (High-Performance Ceramics

2001), 237–242.

Rey, F., Forne

s, V., Rojo, J.M., 1992. Thermal decomposition of hydrotalcites: an infrared

and nuclear magnetic resonance spectroscopic study. Journal of the Chemical Society,

Faraday Transactions 88, 2233–2238.

Chapter 13.1: Layered Double Hydroxides1088

Rey, S., Me

rida-Robles, J., Han, K.-S., Guerlou-Demourgues, L., Delmas, C., Duguet, E.,

1999. Acrylate intercalation and in situ polymerization in iron substituted nickel hydrox-

ides. Polymer International 48, 277–282.

Rives, V. (Ed.), 2001. Layered Double Hydroxides. Nova Science Publishers, Huntington.

Rives, V., 2002. Characterisation of layered double hydroxides and their decomposition

products. Materials Chemistry and Physics 75, 19–25.

Rives, V., Ulibarri, M.A., 1999. Layered double hydroxides intercalated with metal coordi-

nation compounds and oxometalates. Coordination Chemistry Reviews 181, 61–120.

Robins, D.S., Dutta, P.K., 1996. Examination of fatty acid exchanged layered double hy-

droxides as supports for photochemical assemblies. Langmuir 12, 402–408.

Rocha, J., del Arco, M., Rives, V., Ulibarri, M.A., 1999. Reconstruction of layered double

hydroxides from calcined precursors: a powder XRD and

Al MAS NMR study. Journal

of Materials Chemistry 9, 2499–2503.

Roelofs, J.C.A.A., van Dillen, A.J., de Jong, K.P., 2001. Condensation of citral and ketones

using activated hydrotalcite catalysts. Catalysis Letters 74, 91–94.

Roussel, H., Briois, V., Elkaim, E., de Roy, A., Besse, J.-P., 2000. Cationic order and structure

of [Zn–Cr–Cl] and [Cu–Cr–Cl] layered double hydroxides: a XRD and EXAFS study.

Journal of Physical Chemistry, B 104, 5915–5923.

Roussel, H., Briois, V., Elkaim, E., de Roy, A., Besse, J.-P., Jolivet, J.-P., 2001. Study of the

formation of the layered double hydroxide [Zn–Cr–Cl]. Chemistry of Materials 13,

329–337.

Rousselot, I., Taviot-Gueho, C., Besse, J.-P., 1999. Synthesis and characterization of mixed

Ga/Al-containing layered double hydroxides: study of their basic properties through the

Knoevenagel condensation of benzaldehyde and ethyl cyanoacetate, and comparison to

other LDHs. International Journal of Inorganic Materials 1, 165–174.

Rousselot, I., Taviot-Gueho, C., Leroux, F., Leone, P., Palvadeau, P., Besse, J.-P., 2002.

Insights on the structural chemistry of hydrocalumite and hydrotalcite-like materials:

investigation of the series Ca2M3+(OH)6Cl 2H2O (M3+: Al3+, Ga3+, Fe3+

and Sc3+) by X-ray Powder Diffraction. Journal of Solid State Chemistry 167,

137–144.

Rouxhet, P.G., Taylor, H.F.W., 1969. Thermal decomposition of sjo

grenite and pyroaurite.

Chimia 23, 480–485.

Sanchez Martin, M.J., Villa, M.V., Sanchez-Camazano, M., 1999. Glyphosate-hydrotalcite

interaction as inﬂuenced by pH. Clays and Clay Minerals 47, 777–783.

Sanz, J., Serratosa, J.M., 1984. Silicon-29 and aluminum-27 high-resolution MAS–NMR

spectra of phyllosilicates. Journal of the American Chemical Society 106, 4790–4793.

Sato, T., Fujita, H., Endo, T., Shimada, M., Tsunashima, A., 1988. Synthesis of hydrotalcite-

like compounds and their physico-chemical properties. Reactivity of Solids 5, 219–228.

Sato, T., Kato, K., Endo, T., Shimada, M., 1986a. Preparation and chemical properties of

magnesium aluminium oxide solid solutions. Reactivity of Solids 2, 253–260.

Sato, T., Masaki, K., Yoshioka, T., Okuwaki, A., 1993. Photocatalytic properties of CdS and

CdS–ZnS mixtures incorporated into the interlayer of layered compounds. Journal of

Chemical Technology and Biotechnology 58, 315–319.

Scavetta, E., Berrettoni, M., Seeber, R., Tonelli, D., 2001. [Ni/Al–Cl]-based hydrotalcite

electrodes as amperometric sensors: preparation and electrochemical study. Electrochimica

Acta 46, 2681–2692.

References 1089

Scheckel, K.G., Scheinost, A.C., Ford, R.G., Sparks, D.L., 2000. Stability of layered Ni

hydroxide surface precipitates: a dissolution kinetics study. Geochimica et Cosmochimica

Acta 64, 2727–2735.

Scheidegger, A.M., Lamble, G.M., Sparks, D.L., 1997. Spectroscopic evidence for the for-

mation of mixed-cation hydroxide phases upon metal sorption on clays and aluminum

oxides. Journal of Colloid and Interface Science 186, 118–128.

Scheidegger, A.M., Wieland, E., Scheinost, A.C., Da

hn, R., Tits, J., Spieler, P., 2001. Ni

phases formed in cement and cement systems under highly alkaline conditions: an XAFS

study. Journal of Synchrotron Radiation 8, 916–918.

Scho

llhorn, R., 1996. Intercalation systems as nanostructured functional materials. Chemistry

of Materials 8, 1747–1752.

Schon, J.C., Alder, D., Dresselhaus, G., 1988. Theory of staging in intercalation compounds.

Journal of Physics C: Solid State Physics 21, 5595–5614.

Schu

tz, A., Biloe

n, P., 1987. Interlamellar chemistry of hydrotalcites. I. Polymerization of

silicate anions. Journal of Solid State Chemistry 68, 360–368.

Seida, Y., Nakano, Y., 2000. Removal of humic substances by layered double hydroxide

containing iron. Water Resources 34, 1487–1494.

Seida, Y., Nakano, Y., Nakamura, Y., 2001. Rapid removal of dilute lead from water by

pyroaurite-like compound. Water Resources 35, 2341–2346.

Seida, Y., Nakano, Y., Nakamura, Y., 2002. Crystallization of layered double hydroxides by

ultrasound and the effect of crystal quality on their surface properties. Clays and Clay

Minerals 50, 525–532.

Sels, B., de Vos, D., Buntinx, M., Pierard, F., Kirsch-de Mesmaeker, A., Jacobs, P., 1999.

Layered double hydroxides exchanged with tungstate as biomimetic catalysts for mild

oxidative bromination. Nature 400, 855–857.

Sels, B.F., De Vos, D.E., Jacobs, P.A., 2001. Hydrotalcite-like anionic clays in catalytic

organic reactions. Catalysis Reviews—Science and Engineering 43, 443–488.

Serna Carlos, J., Rendon, J.L., Iglesias, J.E., 1982. Crystal-chemical study of layered

[Al2Li(OH)6]+X- nH2O. Clays and Clay Minerals 30, 180–184.

Serwicka, E.M., 2001. Clays as catalysts for removal of nitrogen oxides. Polish Journal of

Chemistry 75, 307–328.

Scheidegger, A.M., Strawn, D.G., Geraldine, M., Lamble, G.M., Sparks, D.L., 1998.

The kinetics of mixed Ni–Al hydroxide formation on clay and aluminum oxide

minerals: a time-resolved XAFS study. Geochimica et Cosmochimica Acta 62,

2233–2245.

Shaw, B.R., Deng, Y., Strillacci, F.E., Carrado, K.A., Fessehaie, M.G., 1990. Electrochemical

surface analysis of nonconducting solids: ferricyanide and phenol as electrochemical probes

of the surfaces of layered double hydroxide anion-exchanging clays. Journal of the Elect-

rochemical Society 137, 3136–3143.

Shaw, W.H.R., Bordeaux, J.J., 1955. The decomposition of urea in aqueous media. Journal of

the American Chemical Society 77, 4729–4733.

Shen, J., Tu, M., Hu, C., 1998. Structural and surface acid/base properties of hydrotalcite-

derived MgAlO oxides calcined at varying temperatures. Journal of Solid State Chemistry

137, 295–301.

Shin, H.-S., Kim, M.-J., Nam, S.-Y., Moon, H.-C., 1996. Phosphorus removal by hydrotal-

cite-like compounds (HTLcs). Water Science and Technology 34, 161–168.

Chapter 13.1: Layered Double Hydroxides1090