
356 Tribology of Metal Cutting
the test specimens showed a great increase in the number of active slip planes. He con-
cluded that this resulted from the penetration (absorption) of the surface active acid into
microcracks which lowered the strength of the specimen.
Rebinder’s studies were directly concerned with the metal cutting process. Conducting a
great number of cutting tests under different cutting conditions and with different cutting
fluids, he observed microcracks formation and “healing.” The latter was particularly
pronounced in machining ductile materials, where great plastic deformation of the layer
being removed is observed. The results of Rebinder’s study showed that the absorbed
films prevent the closing of microcracks (healing due to plastic deformation of the work
material). Because each microcrack in the machining zone serves as a stress concentrator,
smaller energy was required for cutting. Pursuing this direction, Epifanov [53] found
that the penetration of the foreign atoms (from cutting fluid decomposition) produced an
embrittlement effect in a manner similar to hydrogen embrittlement. He concluded that
it thus facilitated by a resulting decrease in plasticity.
Our current understanding of the Rebinder effect is that the alternation of the mechanical
and physical properties of materials is due to the influence of various physiochemical
processes on the surface energy [52]. The energies of the process which lead to the
formation of a new fracture surface was considered by Griffith [54], who developed the
equation which defines the thermodynamic requirements for fracture
σ
f
=
"
2γ
sf
E
πc
cr
, (6.47)
where σ
f
is the fracture stress, γ
sf
is the surface energy, E is the Young’s modulus and
c
cr
is the length of some pre-existing crack.
Griffiths’ equation assumes that the only process that absorbs energy during fracture is
the energy required to form a new surface. As follows from this equation, the surface
energy reduces from a certain level γ
sf −1
to a new level γ
sf −2
due to the penetration of
the foreign atoms (from cutting fluid decomposition) then the energy required for fracture
reduces by
γ
sf −1
/γ
sf −2
1/2
. At this point one may wonder if pre-existing cracks exist
at the surface of ductile work materials. Multiple observations on the surface conditions
show that there are many cracks existing on the surface of even very ductile materials. For
example, Fig. 6.10 shows a micrograph of partially formed chip (ductile work material –
AISI steel 4330), where a number of very deep cracks exists on the surface of the layer
being removed.
The Rebinder effect takes place for practically all solids and structures. Its occurrence
depends on many physiochemical factors like the chemical composition of solid and
fluid, deformation and fracture conditions (strain, velocity, state of stress, material struc-
ture), etc. Depending upon a particular combination of the conditions, the Rebinder
effect manifests itself in different ways: from lowering the shear flow stress to a signif-
icant reduction of strength (both the stress and strain at fracture). The thermodynamic
condition for the Rebinder effect to lower the strength of a material is that the inten-
sity of surface interactions should be comparable with the energy of atomic, ion and/or