176 Diesel engine system design
© Woodhead Publishing Limited, 2011
is very low, condensate of highly corrosive compounds may form, especially
sulfuric acid. The SO
3
reacts with the water vapor to form sulfuric acid
(H
2
SO
4
). The presence of acid increases the corrosion at lower component
temperatures close to the acid dew points. The sulfuric acid in the exhaust
gas will condense at near 150∞C; and the dew point margin is believed to
be the most important variable that affects corrosion (Kass et al., 2005).
The corrosion rate is dependent on the condensation and formation of
sulfuric acid, which is a function of fuel sulfur level, EGR rate, dew point
temperature margin and ambient humidity. The diesel fuels with high sulfur
level (e.g., 350 ppm sulfur) combined with condensation at the EGR cooler
outlet produce high corrosion rates in the engine components, while the
ultra-low-sulfur diesel fuel (with less than 15 ppm sulfur) does not produce
signicant corrosion (Kass et al., 2005). Sulfuric corrosion can be minimized
by using the ultra-low-sulfur fuel and by limiting the condensation of water
to avoid acid condensation in the EGR circuit. Sulfuric acid condensation
in EGR cooler was discussed by McKinley (1997), Kreso et al. (1998) and
Mosburger et al. (2008). Acidic condensation for diesel and biodiesel fuels
was investigated by Moroz et al. (2009).
Water condensate
There are two types of condensate in the engine: acid and water. Condensate
may cause three durability problems: in-cylinder lubricant oil dilution by
water, acidic corrosion, and aggravation of cooler fouling. Water condensation
may occur at any cooler outlet (e.g., charge air cooler, EGR cooler, inter-
stage cooler) and eventually in the intake manifold. EGR cooler condensation
occurs when the EGR cooler outlet gas temperature is lower than the local
condensation temperature. The condensation temperature is affected by the
gas pressure and humidity. At higher ambient humidity (higher dew point
temperature of water), higher EGR gas pressure or colder EGR cooler outlet
gas temperature, it is easier for the water in the EGR gas ow to condense.
The condensate rate is equal to the difference between the mass ow rate of
the H
2
O in EGR and the mass ow rate of saturated water vapor. The H
2
O
ow rate in EGR can be calculated based on the EGR rate and the H
2
O ow
in the exhaust gas. The H
2
O in the exhaust comes from the water contained in
the intake ambient air and the water formed during the combustion process.
The saturated vapor ow rate is calculated based on the saturation pressure
of the water vapor, which in turn varies with the gas temperature.
For heavy-duty engines, high water condensate rate at the EGR cooler
outlet usually occurs in regions of low speed and high load in the engine
speed–torque domain (e.g., around peak torque) due to the combination of
a relatively high EGR gas ow rate, high EGR gas pressure, and cold EGR
cooler outlet gas temperature. At rated power or low load, the water condensate
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