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controlled by the modulus (Eq. (10.5)), and
shear wave speed, controlled by rigidity, , pro-
vides a direct observation of the ratio K/ ¼dP/d,
where is density and P is pressure.
A pure shear strain with no change in volume,
described by , involves no change in temper-
ature and is unambiguous. On the other hand,
a pure compression with no change in shape,
which is described by K, requires specification
of the conditions under which the compression
is applied. If temperature is maintained constant
we have the isothermal modulus, K
T
, but if the
material is thermally isolated or if the compres-
sion is too rapid to allow any transfer of heat, as
in a seismic P wave, then the temperature rises
and a higher, adiabatic modulus, K
S
, applies. This
allows for the fact that compression is partially
offset by thermal expansion. The two principal
bulk moduli, K
T
and K
S
, are related by an identity
K
S
¼ K
T
ð1 þ TÞ (10:1)
(T is temperature, is volume expansion co-
efficient and g is the dimensionless Gr ¨uneisen
parameter, which has numerical values between
1.0 and 1.5 in the Earth). In the deep Earth
the difference between K
S
and K
T
is between 4%
and 10%. The other moduli, considered in the
following section, all describe deformations
involving changes in both volume and shape,
so that relationships between isothermal and
adiabatic versions are inconveniently compli-
cated. Equation (10.1) is one of the thermody-
namic identities that link bulk modulus to
other properties, such as thermal expansion
(Appendix E). Rigidity (and therefore also the
other moduli that can be regarded as combina-
tions of K and , as in Appendix D) are not subject
to comparable controls. This means that, when
we consider effects such as the temperature
dependences of moduli (Section 17.5), rigidity
cannot be treated with the same thermodynamic
rigour as bulk modulus and further assumptions
are needed.
For many purposes isotropy is an adequate
approximation, but elastic anisotropy is well rec-
ognized in both the mantle and the solid inner
core. It can arise both from an alignment of
crystals, which are individually anisotropic, and
from the layering of materials with different
properties. The simplest crystals are those with
cubic structures, which have three independent
moduli, but more general anisotropies, requir-
ing a larger number of moduli, are normal in
minerals. The most general situation of a crystal
completely lacking structural symmetry is rep-
resented by 21 moduli (for a reason outlined in
Section 10.3). Although mineralogists face such
complications, in the Earth the form of aniso-
tropy most commonly considered in detail is
uniaxial, that is, having properties in one dir-
ection differing from those in the perpendicular
plane, within which there is no variation. In the
upper mantle the single axis is assumed to be
vertical (radial) and seismologists refer to such a
structure as transversely isotropic. It is repre-
sented by five moduli (Section 10.3). Although
azimuthal anisotropy occurs, both on continents
(e.g. Davis, 2003) and on the ocean floors, on a
global scale gravity selects the vertical axis as
unique. Transverse anisotropy is smeared out
statistically, so that transverse isotropy is to be
expected as a global average. In the inner core it
appears that the rotational axis is selected as a
unique direction. This is best explained by the
precipitation of added material predominantly
on its equator and deformation towards the equi-
librium ellipticity (Yoshida et al., 1996).
Our understanding of the Earth’s interior is
derived almost entirely from seismology and its
interpretation, based on elastic and inelastic
properties. These properties include anisotropy,
the behaviour of composites and polycrystalline
materials, effects of temperature and pressure
and the frequency variation of elasticity, all of
which need to be understood to make maximum
use of seismological data.
10.2 Elastic moduli of an
isotropic solid
The simplest derivation of the relationships
between moduli starts with Young’s modulus,
E, and Poisson’s ratio, , which are defined with
the other moduli in Table 10.1. Consider a rec-
tangular prism, as in Fig. 10.1, with axes x, y, z,
chosen to be parallel to the principal stresses,
x
,
136 ELASTIC AND INELASTIC PROPERTIES