“White rust”isthe destruction of the surface of galvanized steel or zinc by oxygen or other chemical
elements. The reaction is accelerated by the presence of moistureacting as acatalyst.
The zinc coating may be applied by hot dip galvanizing or electrodeposition and is primarily intended
to serve as aprotective layer for the main metal substrate.
However,this protective film has its own limitations when subjected to environments antagonistic to
its protection properties. The rate of attack is related to temperature,phand composition of moisture
and the concentration of dissolved gases within that moisture. The higher the oxygen and carbon dioxide
content, and the softer the water,the greater the rate of surface breakdown is. When the water is present,
the corrosion cycle starts with the formation of zinc oxide, which, in turn, is converted to zinc hydroxide
and then to basic zinc carbonate in the presence of carbon dioxide. The final product prevents the onset
of further corrosion at that particular area of attack providing no highly acidic or alkaline contaminant
becomesinvolved later.
Under enclosed conditions such as blind angles and boxsections, rapid attack by the available oxygen
gives rise to apitting condition as the exhausted gas is not replaced as fast as it is used. The corrosion
pattern, therefore, is nonuniform and typical of “white rust”conditions.
It is essential that roll formed sections and tubes be drained of as much coolant as possible. Weep holes
should be pierced or drilled in blind sections whenever feasible. Storage should be in selected areas where
freecirculation of air is not aproblem in ordertoavoid stagnation of anyresidual fluid.
Zinc is rapidly attackedinacidic and alkaline aqueous conditions. Storage and manufacturewithin the
vicinityoffumes fromplating or pickling shops will accelerate metal surface breakdown.
The accumulation of metal fines in acoolant reservoir is another sourceofpotential problems. Should
the particulate contaminants not be filtered out or removed, therewill be aconstant deposition on the
metal as it is formed. The particles of fines will create isolated areas of chemical and electrochemical
corrosion. Zinc is sacrificial to steel (iron).
The chemical and physical properties of the lubricant maycontribute to “white rust.”Some of these
properties are unstable water-soluble materials, activechemical agents such as chlorine or sulfur (which
are not properly inhibits). In general, stable emulsions of properly selected synthetic solubles are best for
galvanized surfaces. Evaporativecompounds can work well on these surfacesalso.
Another precaution that should be takeninlubricating galvanized material is to prevent excessive
amounts of water-based lubricant from being allowedtoremainonrollformed sections. This trapped
water can definitely contribute to a“white rust” condition, especially when parts are nested or stacked.
Some operators will blow offthe excessive water-soluble lubricant beforethe cutoffinorder to
minimize the amount of residual left on the part. As noted above, stacking parts so that the configuration
provides for air circulation is extremely helpful.
Conditions of highrelativehumidityabove 70 to 75% aggravate corrosion. When the metal surface
temperature dropsinthe presence of highhumidity, the condensed moistureonthe section is rich in
oxygen because the thin water film is exposed to alarge volume of air.Conditions are then ideal for
extensive uniform corrosion. Closely packed, tightly nested, products stored outside the plant cool down
during the night. During the day,the large amount of water condenses on the surface of the cold metal.
Because thereare so manydifferent precoated materials being rollformed, extra caremust be takento
check first with both your lubricant and material supplier beforeattempting to use anyforming lubricant
on coated stock. This is especially true not only on galvanized material but on spray coated, painted,
vinyl, paper clad, and electroplated material.
Further Reading
[137] Ivaska, J. 1991. The three keysegments of roll forming lubrication. SME Te chnical Report,
MFR91-14.
[401] Harmon,J.J.1990. Laws Involved in Governing the Use, Management and Disposal of Metal-
working Lubricants. Cors &Bassett, Environmental Group,Cincinnati, OH.
Roll Forming Handbook7 -22