Григорьев Н.А. Распределение химических элементов в верхней части континентальной коры
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ñÂËÈ. Ç ˛ÒÍÓÏ Î‡ÚËÚ ËÁ ᇷ‡È͇θfl (ÉÂÓıËÏËfl ÏÂÁÓÁÓÈÒÍËı…, 1984)
ÒÓ‰ÂʇÌË Ce 0.009%, χÍÒËÏË̇Î˚ Ì ӷ̇ÛÊÂÌ˚; ‚ ‰‚Ûı ÔÓ·‡ı ¯Ó-
¯ÓÌËÚÓ‚ Ò ÓÒÚÓ‚‡ ëÚÓÏ·ÓÎË, ÒÓ‰Âʇ˘Ëı 0.012 Ë 0.0102% ëÂ, Â„Ó Ï‡ÍÒË-
ÏË̇Î˚ Ì ӷ̇ÛÊÂÌ˚; ‚ Í‚‡ˆÂ‚Ó-‰ËÓÔÒˉӂÓÏ Ë ‰ËÓÔÒˉ-Ò͇ÔÓÎËÚÓ-
‚ÓÏ Ô·„ËÓÒ·̈‡ı ËÁ ÄΉ‡ÌÒÍÓÈ ÙÎÓ„ÓÔËÚÓÌÓÒÌÓÈ ÔÓ‚Ë̈ËË (èÂÚÓ‚‡,
ëÏËÌÓ‚‡, 1982) ÒÓ‰ÂʇÌË ë 0.0072 Ë 0.01%, χÍÒËÏË̇Î˚ Ì ÛÒÚ‡ÌÓ‚-
ÎÂÌ˚; ‚ Ï˄χÚËÚÂ Ë Ô·„ËÓ„ÌÂÈÒ ËÁ ë‚ÂÌÓ„Ó èË·‡È͇θfl (å‡Í˚„Ë̇,
ëÏËÌÓ‚‡, 1984) ÒÓ‰ÂʇÌË ë 0.018 Ë 0.011%; ‚ χÍÒËÏË̇·ı – ÓÚËÚÂ
(„·‚Ì˚È) Ë ‡Ô‡ÚËÚ (‚ÚÓÓÒÚÂÔÂÌÌ˚È) ÒÍÓ̈ÂÌÚËÓ‚‡ÌÓ ÒÓÓÚ‚ÂÚÒÚ‚ÂÌÌÓ
78 Ë 57% χÒÒ ëÂ.
è‡ÁÂÓ‰ËÏ. Ç.Ä. å‡Í˚„Ë̇ Ë Ç.Ç. ëÏËÌÓ‚‡ (1984) ËÁÛ˜ËÎË ‰‚ ÔÓ-
·˚ Ï˄χÚËÚÓ‚ ËÁ ë‚ÂÌÓ„Ó èË·‡È͇θfl Ò ÒÓ‰ÂʇÌËÂÏ Pr
241
臇Ò·̈˚ Ç ˆÂÎÓÏ
éÚÓÏÂÚ‡ÏÓÙ˘ÂÒÍË ÔÓÓ‰˚
Ç ˆÂÎÓÏ
åË̇Î˚
ɇÌËÚÓ-„ÌÂÈÒ˚åÂÚ‡ÔÂÒ˜‡ÌËÍË
ì‡ÌËÌËÚ ç ÓÔ. ç ÓÔ. ç ÓÔ. < 0.01 ç ÓÔ. < 0.01
(6⋅10
–7
)(5⋅10
–7
)
èËÓıÎÓ ç ÓÔ. ç ÓÔ. ç ÓÔ. < 0.01 ç ÓÔ. < 0.01
(2⋅10
–6
)(2⋅10
–6
)
éÚËÚ 2.4 7.79 7.4 7.51 13.77 6.91
(0.0012) (0.008) (0.0071) (0.0066) (0.008) (0.0056)
åÓ̇ˆËÚ 1.99 2.9 2.76 10.18 0.01 8.98
(3⋅10
–4
)(9⋅10
–4
)(8⋅10
–4
) (0.0027) (2⋅10
–6
) (0.0022)
ŇÒÚÌÂÁËÚ ç ÓÔ. ç ÓÔ. ç ÓÔ. 4.6 ç ÓÔ. 4.15
(0.0012) (0.001)
ÇÒÂ„Ó 4.39 10.69 10.16 22.29 13.78 20.04
(0.0015) (0.0089) (0.0079) (0.0098) (0.008) (0.0088)
퇷Îˈ‡ 11.17
ÑÓÎË Ï‡ÒÒ Ce (%), ÒÍÓ̈ÂÌÚËÓ‚‡ÌÌ˚ ‚ χÍÒËÏË̇·ı
ÏÂÚ‡ÏÓÙ˘ÂÒÍËı ÔÓÓ‰ „‡ÌËÚÌÓ-„ÌÂÈÒÓ‚Ó„Ó ÒÎÓfl
臇ÏÂÚ‡ÏÓÙ˘ÂÒÍË ÔÓÓ‰˚
åÂÚ‡ËÓÎËÚ˚
臇Ò·̈˚ Ç ˆÂÎÓÏ
éÚÓÏÂÚ‡ÏÓÙ˘ÂÒÍË ÔÓÓ‰˚
Ç ˆÂÎÓÏ
åË̇Î˚
ɇÌËÚÓ-„ÌÂÈÒ˚åÂÚ‡ÔÂÒ˜‡ÌËÍË
éÚËÚ 2.03 6.4 6.25 5.28 22.7 5.19
(0.0012) (0.008) (0.0071) (0.0066) (0.008) (0.0056)
ŇÒÚÌÂÁËÚ ç ÓÔ. ç ÓÔ. ç ÓÔ. 3.6 ç ÓÔ. 3.47
(0.0012) (0.001)
åÓ̇ˆËÚ 2.31 3.27 3.2 9.82 0.03 9.26
(3⋅10
–4
)(9⋅10
–4
)(8⋅10
–4
) (0.0027) (2⋅10
–6
) (0.0022)
ÇÒÂ„Ó 4.34 9.67 9.45 18.7 22.73 17.92
(0.0015) (0.0089) (0.0079) (0.0105) (0.008) (0.0088)
퇷Îˈ‡ 11.18
ÑÓÎË Ï‡ÒÒ Pr (%), ÒÍÓ̈ÂÌÚËÓ‚‡ÌÌ˚ ‚ χÍÒËÏË̇·ı
ÏÂÚ‡ÏÓÙ˘ÂÒÍËı ÔÓÓ‰ „‡ÌËÚÌÓ-„ÌÂÈÒÓ‚Ó„Ó ÒÎÓfl
臇ÏÂÚ‡ÏÓÙ˘ÂÒÍË ÔÓÓ‰˚
åÂÚ‡ËÓÎËÚ˚
0.003–0.0044%, ‚ Ó·ÂËı χÍÒËÏË̇ΠÓÚËÚ, ‚ ÍÓÚÓÓÏ ÒÍÓ̈ÂÌÚËÓ‚‡-
ÌÓ 71 Ë 40% χÒÒ˚ ëÂ.
í‡ÍËÏ Ó·‡ÁÓÏ, ˝ÔËÁӉ˘ÂÒÍË ÏË̇θÌ˚ ·‡Î‡ÌÒ˚ Óڇʇ˛Ú ‚ ÓÒ-
ÌÓ‚ÌÓÏ Ë̉˂ˉۇθÌ˚ ÓÒÓ·ÂÌÌÓÒÚË ËÁÛ˜ÂÌÌ˚ı „ÓÌ˚ı ÔÓÓ‰.
11.2.3. ÑÓÎË Ï‡ÒÒ Nd Ë Sm, ÒÍÓ̈ÂÌÚËÓ‚‡ÌÌ˚ ‚ χÍÒËÏË̇·ı
êÓθ χÍÒËÏË̇ÎÓ‚ Í‡Í ÌÓÒËÚÂÎÂÈ Nd Ë Sm ÒÛ˘ÂÒÚ‚ÂÌ̇ ‚ „‡ÌËÚÌÓ-
„ÌÂÈÒÓ‚ÓÏ ÒÎÓÂ Ë ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌڇθÌÓÈ ÍÓ˚ ‚ ˆÂÎÓÏ
(Ú‡·Î. 11.19, 11.20). Ç ÓÒ‡‰Ó˜ÌÓÏ ÒÎÓ ËÁÛ˜ÂÌ˚ ÚÓθÍÓ ÔÂÒÍË, ÍËÒÎ˚ Ë
Ò‰ÌË ‚ÛÎ͇ÌËÚ˚. êÓθ χÍÒËÏË̇ÎÓ‚ Á̇˜ËÚÂθ̇ ‚ ÍËÒÎ˚ı ‚ÛÎ-
͇ÌËÚ‡ı (Ú‡·Î. 11.21, 11.22), χÍÒËχθ̇ ‚ „‡ÌËÚ‡ı Ë ÒËÂÌËÚ‡ı
(Ú‡·Î. 11.23, 11.24). åÌÂÌ Á̇˜ËÚÂθ̇ Ó̇ ‚ „‡ÌËÚÓ-„ÌÂÈÒ‡ı Ë ÏÂÚ‡Ë-
ÓÎËÚ‡ı (Ú‡·Î. 11.25, 11.26). ÑÓÔÓÎÌËÚÂθÌÓ ÓÚÏÂÚËÏ, ˜ÚÓ ‚ ÏÂÚ‡·‡ÁËÚ‡ı
ÛÒÚ‡ÌÓ‚ÎÂÌ ÏÓ̇ˆËÚ (҉̠ÒÓ‰ÂʇÌË 4⋅10
–8
%), ÌÓ ÒÍÓ̈ÂÌÚËÓ‚‡Ì-
Ì˚ ‚ ÌÂÏ ‰ÓÎË Ï‡ÒÒ Nd Ë Sm < 0.01%.
ÇÓÁÏÓÊÌÓÒÚË ÒÓÔÓÒÚ‡‚ÎÂÌËfl ÔÓÎÛ˜ÂÌÌ˚ı ‰‡ÌÌ˚ı Ò ÂÁÛθڇڇÏË ËÁÛ˜Â-
ÌËfl ‡ÒÔ‰ÂÎÂÌËfl Nd Ë Sm ÔÓ ÏËÌÂ‡Î‡Ï „ÓÌ˚ı ÔÓÓ‰ ÏËÌËχθÌ˚Â. Ç
·Óθ¯ËÌÒÚ‚Â ÒÎÛ˜‡Â‚ ËÎË Ì‰ÓÒÚ‡ÚÓ˜ÌÓ ‰‡ÌÌ˚ı ‰Îfl ‡Ò˜ÂÚ‡ ÏË̇θÌ˚ı
·‡Î‡ÌÒÓ‚, ËÎË ‚ÂÎËÍË Ôӄ¯ÌÓÒÚË ÓÔ‰ÂÎÂÌËfl ÒÓ‰ÂʇÌËÈ Nd Ë Sm ‚ ÏË-
̇·ı. ëÛÏÏ˚ Û˜ÚÂÌÌ˚ı ‰ÓÎÂÈ Ï‡ÒÒ Nd Ë Sm ‚ ÏË̇·ı ÒÓÒÚ‡‚Îfl˛Ú
26–128% ÓÚ Ï‡ÒÒ, ÒÓÓÚ‚ÂÚÒÚ‚Û˛˘Ëı ÒÓ‰ÂʇÌËflÏ Nd Ë Sm ‚ ËÒÒΉӂ‡ÌÌ˚ı
ÔÓ·‡ı „ÓÌ˚ı ÔÓÓ‰ ÔÓ ÂÁÛÎ¸Ú‡Ú‡Ï Ëı ‡Ì‡ÎËÁ‡. Ä‚ÚÓÓÏ Û˜ÚÂÌÓ ‚Ò„Ó
9 ÏË̇θÌ˚ı ·‡Î‡ÌÒÓ‚ (Nd –7 Ë Sm – 2). ùÚÓ ‚ ÓÒÌÓ‚ÌÓÏ ·‡Î‡ÌÒ˚, „‰Â ÒÛÏ-
Ï˚ Û˜ÚÂÌÌ˚ı ‰ÓÎÂÈ Ï‡ÒÒ Nd Ë Sm Ì ‚˚ıÓ‰flÚ Á‡ Ô‰ÂÎ˚ 90–110% ÓÚ Ï‡ÒÒ
˝ÚËı ˝ÎÂÏÂÌÚÓ‚, ÛÒÚ‡ÌÓ‚ÎÂÌÌ˚ı ÔË ‡Ì‡ÎËÁ‡ı „ÓÌ˚ı ÔÓÓ‰. àÒÍβ˜ÂÌËÂ
҉·ÌÓ ‰Îfl ̉ÓÒÚ‡ÚÓ˜ÌÓ ÚÓ˜Ì˚ı, ÌÓ ÔÓ‰Ó·Ì˚ı ‰‡ÌÌ˚ı Ó ‡ÒÔ‰ÂÎÂÌËË
Nd Ë Sm ‚ ÒÓ‚ÓÍÛÔÌÓÒÚË ÏË̇ÎÓ‚ „‡ÌÓ‰ËÓËÚ‡ ËÁ ·‡ÚÓÎËÚ‡ ÇÓÒÚÓ˜Ì˚È
242
ÑÓÎË Ï‡ÒÒ
Nd, %
ÑÓÎË Ï‡ÒÒ
Nd, %
ëÓ‰ÂʇÌËÂ
ÏË̇ÎÓ‚, %
ÑÓÎË Ï‡ÒÒ
Nd, %
ëÓ‰ÂʇÌËÂ
ÏË̇ÎÓ‚, %
ÇÂıÌflfl ˜‡ÒÚ¸ ÍÓÌÚËÌÂÌ-
ڇθÌÓÈ ÍÓ˚
åË̇Î˚
ëÓ‰ÂʇÌËÂ
ÏË̇ÎÓ‚, %
ɇÌËÚÌÓ-„ÌÂÈÒÓ‚˚È ÒÎÓÈ
ù‚ÍÒÂÌËÚ 0.5 ç ÓÔ. ç ÓÔ. 8.6⋅10
–6
< 0.01 6.6⋅10
–6
< 0.01
ÅÎÓÏÒڇ̉ËÌ 0.8 ç ÓÔ. ç ÓÔ. 1.2⋅10
–6
< 0.01 9⋅10
–7
< 0.01
àÚÚˇÎËÚ 1.41 ç ÓÔ. ç ÓÔ. 2.1⋅10
–5
0.01 1.6⋅10
–5
0.01
éÚËÚ 2.1 6⋅10
–5
0.05 0.0063 4.27 0.0048 3.48
ŇÒÚÌÂÁËÚ 2.3 ç ÓÔ. ç ÓÔ. 4.2⋅10
–4
0.31 3.2⋅10
–4
0.25
êËÌÍÓÎËÚ 2.7 ç ÓÔ. ç ÓÔ. 6.9⋅10
–9
< 0.01 5.3⋅10
–9
< 0.01
î„ÛÒÓÌËÚ 3.2 ç ÓÔ. ç ÓÔ. 3.1⋅10
–6
< 0.01 2.4⋅10
–6
< 0.01
ó‚ÍËÌËÚ 7.4 ç ÓÔ. ç ÓÔ. 5.5⋅10
–7
< 0.01 4.2⋅10
–7
< 0.01
ɇ‰ÓÎËÌËÚ 8.5 ç ÓÔ. ç ÓÔ. 5.2⋅10
–6
0.01 4⋅10
–6
0.01
åÓ̇ˆËÚ 12 4.6⋅10
–5
0.23 0.0016 6.19 0.0013 5.38
ëÛÏχ 1.06⋅10
–4
0.28 0.0083 10.79 0.0064 9.13
퇷Îˈ‡ 11.19
êÓθ χÍÒËÏË̇ÎÓ‚ Í‡Í ÌÓÒËÚÂÎÂÈ Nd ‚ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌڇθÌÓÈ ÍÓ˚
ëÓ‰ÂʇÌËÂ
Nd ‚ ÏËÌÂ-
‡Î‡ı, %
éÒ‡‰Ó˜Ì˚È ÒÎÓÈ
èÂÌËÌÒÛÎfl êẨÊÂÒ (Gromet, Silver, 1983). á‰ÂÒ¸ ÒÛÏÏ˚ Û˜ÚÂÌÌ˚ı ‰ÓÎÂÈ
χÒÒ ÒÓÓÚ‚ÂÚÒÚ‚ÂÌÌÓ 128 Ë 111 ÓÚÌ.%.
çÂÓ‰ËÏ. Ç „ˇÎÓËÓÎËÚÂ Ë Î‡ÚËÚ (ÉÂÓıËÏËfl ÏÂÁÓÁÓÈÒÍËı…, 1984) ËÁ
ᇷ‡È͇θfl, ÒÓ‰Âʇ˘Ëı Nd 0.0024 Ë 0.004%, Â„Ó Ï‡ÍÒËÏË̇Î˚ Ì ӷ̇-
ÛÊÂÌ˚; ‚ ¯Ó¯ÓÌËÚÂ Ò Ó-‚‡ ëÚÓÏ·ÓÎË, ÒÓ‰Âʇ˘ÂÏ 0.005% Nd, χÍÒËÏË-
̇Î˚ ÚÓÊ Ì ӷ̇ÛÊÂÌ˚ (Francalanci, 1989); ‚ „‡ÌÓ‰ËÓËÚ ËÁ ·‡ÚÓÎË-
243
ÑÓÎË Ï‡ÒÒ
Sm, %
ÑÓÎË Ï‡ÒÒ
Sm, %
ëÓ‰ÂʇÌËÂ
ÏË̇ÎÓ‚, %
ÑÓÎË Ï‡ÒÒ
Sm, %
ëÓ‰ÂʇÌËÂ
ÏË̇ÎÓ‚, %
ÇÂıÌflfl ˜‡ÒÚ¸ ÍÓÌÚËÌÂÌ-
ڇθÌÓÈ ÍÓ˚
åË̇Î˚
ëÓ‰ÂʇÌËÂ
ÏË̇ÎÓ‚, %
ɇÌËÚÌÓ-„ÌÂÈÒÓ‚˚È ÒÎÓÈ
éÚËÚ 0.38 6⋅10
–5
0.04 0.0063 4.13 0.0048 3.2
êËÌÍÓÎËÚ 0.5 ç ÓÔ. ç ÓÔ. 6.9⋅10
–9
< 0.01 5.3⋅10
–9
<0.01
ŇÒÚÌÂÁËÚ 0.5 ç ÓÔ. ç ÓÔ. 4.2⋅10
–4
0.36 3.2⋅10
–4
0.28
ù‚ÍÒÂÌËÚ 0.7 ç ÓÔ. ç ÓÔ. 8.6⋅10
–6
0.01 6.6
.
10
–6
0.01
ÅÎÓÏÒڇ̉ËÌ 0.9 ç ÓÔ. ç ÓÔ. 1.2⋅10
–6
< 0.01 9⋅10
–7
< 0.01
ó‚ÍËÌËÚ 1 ç ÓÔ. ç ÓÔ. 5.5⋅10
–7
< 0.01 4.2⋅10
–7
< 0.01
àÚÚˇÎËÚ 1.16 ç ÓÔ. ç ÓÔ. 2.1⋅10
–5
0.04 1.6⋅10
–5
0.03
åÓ̇ˆËÚ 1.7 4.6⋅10
–5
0.15 0.0016 4.69 0.0013 3.88
î„ÛÒÓÌËÚ 2 ç ÓÔ. ç ÓÔ. 3.1⋅10
–6
0.01 2.4⋅10
–6
0.01
ɇ‰ÓÎËÌËÚ 2.27 ç ÓÔ. ç ÓÔ. 5.2⋅10
–6
0.02 4⋅10
-6
0.02
ÇÒÂ„Ó 1.06⋅10
–4
0.19 0.0083 9.26 0.0064 7.43
퇷Îˈ‡ 11.20
êÓθ χÍÒËÏË̇ÎÓ‚ Í‡Í ÌÓÒËÚÂÎÂÈ Sm ‚ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌڇθÌÓÈ ÍÓ˚
ëÓ‰ÂʇÌËÂ
Sm ‚ ÏËÌÂ-
‡Î‡ı, %
éÒ‡‰Ó˜Ì˚È ÒÎÓÈ
Ç ˆÂÎÓÏ
ÇÛÎ͇ÌÓ„ÂÌÌ˚ ÔÓÓ‰˚
Ç ˆÂÎÓÏ
åË̇Î˚
äËÒÎ˚ÂèÂÒÍË Ë ÔÂÒ˜‡ÌËÍË
éÚËÚ < 0.01 (7⋅10
–8
) < 0.01 (1.8⋅10
–8
) 2.33 (0.003) 0.11 (1⋅10
–4
) 0.4 (4⋅10
–4
)
åÓ̇ˆËÚ 0.98 (1.3⋅10
–4
) 017 (3.3⋅10
–5
) 4.44 (0.001) ç ÓÔ. 0.69 (1.2⋅10
–4
)
ÇÒÂ„Ó 0.98 (1.3⋅10
–4
) 0.17 (3.3⋅10
–5
) 6.77 (0.004) 0.11 (1⋅10
-4
) 1.09 (5.2⋅10
-4
)
퇷Îˈ‡ 11.21
ÑÓÎË Ï‡ÒÒ Nd (%), ÒÍÓ̈ÂÌÚËÓ‚‡ÌÌ˚ ‚ χÍÒËÏË̇·ı
„ÓÌ˚ı ÔÓÓ‰ ÓÒ‡‰Ó˜ÌÓ„Ó ÒÎÓfl
éÒ‡‰Ó˜Ì˚ ÔÓÓ‰˚
ë‰ÌËÂ
èËϘ‡ÌËÂ. á‰ÂÒ¸ Ë ‚ ÔÓÒÎÂ‰Û˛˘Ëı Ú‡·Îˈ‡ı ‚ ÒÍӷ͇ı – ÒÓ‰ÂʇÌË ÏË̇ÎÓ‚, %.
Ç ˆÂÎÓÏ
ÇÛÎ͇ÌÓ„ÂÌÌ˚ ÔÓÓ‰˚
Ç ˆÂÎÓÏ
åË̇Î˚
äËÒÎ˚ÂèÂÒÍË Ë ÔÂÒ˜‡ÌËÍË
éÚËÚ < 0.01 (7⋅10
–8
) < 0.01 (1.8⋅10
–8
) 2.19 (0.003) 0.09 (1⋅10
–4
) 0.31 (4⋅10
–4
)
åÓ̇ˆËÚ 0.58 (1.3⋅10
–4
) 0.1 (3.3⋅10
–5
) 3.27 (0.001) ç ÓÔ. 0.42 (1.2⋅10
–4
)
ÇÒÂ„Ó 0.58 (1.3⋅10
–4
) 0.1 (3⋅10
–5
) 5.46 (0.004) 0.09 (1⋅10
–4
) 0.73 (5⋅10
–4
)
퇷Îˈ‡ 11.22
ÑÓÎË Ï‡ÒÒ Sm (%), ÒÍÓ̈ÂÌÚËÓ‚‡ÌÌ˚ ‚ χÍÒËÏË̇·ı
„ÓÌ˚ı ÔÓÓ‰ ÓÒ‡‰Ó˜ÌÓ„Ó ÒÎÓfl
éÒ‡‰Ó˜Ì˚ ÔÓÓ‰˚
ë‰ÌËÂ
244
ɇÌÓ‰ËÓËÚ˚åË̇Î˚ ëËÂÌËÚ˚ɇÌËÚ˚
ù‚ÍÒÂÌËÚ 0.01 (8⋅10
–5
) ç ÓÔ. < 0.01 (8⋅10
–8
) 0.01 (5⋅10
–5
)
ÅÎÓÏÒڇ̉ËÌ < 0.01 (8.7⋅10
–6
) ç ÓÔ. 0.06 (3.3⋅10
–4
) < 0.01 (6.7⋅10
–6
)
àÚÚˇÎËÚ 0.09 (2⋅10
–4
) ç ÓÔ. ç ÓÔ. 0.06 (1.2⋅10
–4
)
éÚËÚ 5.42 (0.008) 2.74 (0.003) 11.5 (0.023) 4.35 (0.0058)
ŇÒÚÌÂÁËÚ 0.35 (4.7⋅10
–4
) ç ÓÔ. ç ÓÔ. 0.24 (2.9⋅10
–4
)
î„ÛÒÓÌËÚ 0.02 (1.5⋅10
–5
) 0.05 (3.2⋅10
–5
) < 0.01 (3.8⋅10
–6
) 0.02 (1.8⋅10
–5
)
ó‚ÍËÌËÚ < 0.01 (1.5⋅10
–6
) ç ÓÔ. 1.06 (6⋅10
–4
) 0.01 (3.2⋅10
–6
)
ɇ‰ÓÎËÌËÚ 0.14 (5⋅10
–5
) ç ÓÔ. 0.01 (3⋅10
–6
) 0.09 (3⋅10
–5
)
åÓ̇ˆËÚ 16.6 (0.0043) 2.09 (4⋅10
–4
) 6.86(0.0024) 12(0.0028)
ÇÒÂ„Ó 22.63 (0.013) 4.88 (0.0034) 19.48 (0.0263) 16.69 (0.0091)
퇷Îˈ‡ 11.23
ÑÓÎË Ï‡ÒÒ Nd (%), ÒÍÓ̈ÂÌÚËÓ‚‡ÌÌ˚ ‚ χÍÒËÏË̇·ı
χ„χÚ˘ÂÒÍËı ÔÓÓ‰ „‡ÌËÚÌÓ-„ÌÂÈÒÓ‚Ó„Ó ÒÎÓfl
凄χÚ˘ÂÒÍËÂ
ÔÓÓ‰˚ ‚ ˆÂÎÓÏ
ɇÌÓ‰ËÓËÚ˚åË̇Î˚ ëËÂÌËÚ˚ɇÌËÚ˚
éÚËÚ 4.05 (0.008) 1.39 (0.003) 8.7 (0.023) 2.98 (0.0058)
ŇÒÚÌÂÁËÚ 0.31 (4.7⋅10
–4
) ç ÓÔ. ç ÓÔ. 0.2 (2.9⋅10
–4
)
ù‚ÍÒÂÌËÚ 0.07 (8⋅10
–5
) ç ÓÔ. < 0.01 (8⋅10
–8
) 0.05 (5⋅10
–5
)
ÅÎÓÏÒڇ̉ËÌ 0.01 (8.7⋅10
–6
) ç ÓÔ. 0.3 (3.3⋅10
–4
) 0.01 (6.7⋅10
–6
)
ó‚ÍËÌËÚ < 0.01 (1.5⋅10
–6
) ç ÓÔ. 0.6 (0.0006) < 0.01(3.2⋅10
–6
)
àÚÚˇÎËÚ 0.31 (2⋅10
–4
) ç ÓÔ. ç ÓÔ. 0.19 (1.2⋅10
–4
)
åÓ̇ˆËÚ 9.75 (0.0043) 0.83 (0.0004) 4.08 (0.0024) 6.43 (0.0028)
î„ÛÒÓÌËÚ 0.04 (1.5⋅10
–5
) 0.08(3.2⋅10
–5
) 0.01 (3.8⋅10
–6
) 0.05 (1.8⋅10
–5
)
ɇ‰ÓÎËÌËÚ 0.15 (5⋅10
–5
) ç ÓÔ. 0.01 (3⋅10
–6
) 0.09 (3⋅10
–5
)
ÇÒÂ„Ó 14.69 (0.013) 2.3 (0.0034) 13.7 (0.026) 10 (0.0091)
퇷Îˈ‡ 11.24
ÑÓÎË Ï‡ÒÒ Sm (%), ÒÍÓ̈ÂÌÚËÓ‚‡ÌÌ˚ ‚ χÍÒËÏË̇·ı
χ„χÚ˘ÂÒÍËı ÔÓÓ‰ „‡ÌËÚÌÓ-„ÌÂÈÒÓ‚Ó„Ó ÒÎÓfl
凄χÚ˘ÂÒÍËÂ
ÔÓÓ‰˚ ‚ ˆÂÎÓÏ
臇Ò·̈˚ Ç ˆÂÎÓÏ
éÚÓÏÂÚ‡ÏÓÙ˘ÂÒÍË ÔÓÓ‰˚
Ç ˆÂÎÓÏ
åË̇Î˚
ɇÌËÚÓ-„ÌÂÈÒ˚åÂÚ‡ÔÂÒ˜‡ÌËÍË
éÚËÚ 1.05 4.67 4.39 4.33 15.3 4.2
(0.0012) (0.008) (0.0071) (0.0066) (0.008) (0.0056)
ŇÒÚÌÂÁËÚ ç ÓÔ. ç ÓÔ. ç ÓÔ. 0.86 ç ÓÔ. 0.82
(0.0012) (0.001)
åÓ̇ˆËÚ 1.5 3 (9⋅10
–4
) 2.82 10.1 0.02 9.43
(3⋅10
–4
)(8⋅10
–4
) (0.0027) (2⋅10
–6
) (0.0022)
ÇÒÂ„Ó 2.55 7.67 7.21 15.29 15.32 13.63
(0.0015) (0.0089) (0.0079) (0.0094) (0.008) (0.0079)
퇷Îˈ‡ 11.25
ÑÓÎË Ï‡ÒÒ Nd (%), ÒÍÓ̈ÂÌÚËÓ‚‡ÌÌ˚ ‚ χÍÒËÏË̇·ı
ÏÂÚ‡ÏÓÙ˘ÂÒÍËı ÔÓÓ‰ ÍÓÌÚËÌÂÌڇθÌÓÈ ÍÓ˚
臇ÏÂÚ‡ÏÓÙ˘ÂÒÍË ÔÓÓ‰˚
åÂÚ‡ËÓÎËÚ˚
Ú‡ ÇÓÒÚÓ˜Ì˚È èÂÌËÌÒÛÎfl êẨÊÂÒ (Gromet, Silver, 1983) ÒÓ‰ÂʇÌË Nd
0.0025%, χÍÒËÏË̇Î˚ Á‰ÂÒ¸ ÚËÚ‡ÌËÚ Ë ÓÚËÚ, ‰ÓÎË Ï‡ÒÒ Nd ‚ ÌËı ÒÓÓÚ‚ÂÚ-
ÒÚ‚ÂÌÌÓ 70 Ë 50 ÓÚÌ.%; ‚ ‰ËÓÔÒˉ-Ô·„ËÓÍ·ÁÓ‚ÓÏ Ë ‰ËÓÔÒˉ-Ò͇ÔÓÎËÚ-Ô·-
„ËÓÍ·Á‡‚ÓÏ Ô·„ËÓÒ·̈‡ı ËÁ ÄΉ‡ÌÒÍÓÈ ÙÎÓ„ÓÔËÚÓÌÓÒÌÓÈ ÔÓ‚Ë̈ËË
(èÂÚÓ‚‡, ëÏËÌÓ‚‡, 1982) ÒÓ‰ÂʇÌË Nd 0.0045 Ë 0.0039%; ‚ Ô‚ÓÏ Ï‡Í-
ÒËÏË̇ΠÚËÚ‡ÌËÚ, ‚ ÍÓÚÓÓÏ ÒÍÓ̈ÂÌÚËÓ‚‡ÌÓ 58% χÒÒ Nd, ‚Ó ‚ÚÓÓÏ
χÍÒËÏË̇Î˚ Ì ÛÒÚ‡ÌÓ‚ÎÂÌ˚; ‚ Ô·„ËÓ„ÌÂÈÒ ËÁ ë‚ÂÌÓ„Ó èË·‡È͇θfl
(å‡Í˚„Ë̇, ëÏËÌÓ‚‡, 1984) ÒÓ‰ÂʇÌË Nd 0.012%, χÍÒËÏË̇Î˚ Ó-
ÚËÚ („·‚Ì˚È) Ë ÚËÚ‡ÌËÚ (‚ÚÓÓÒÚÂÔÂÌÌ˚È), ‚ ÍÓÚÓ˚ı ÒÍÓ̈ÂÌÚËÓ‚‡ÌÓ
68% χÒÒ Nd.
ë‡Ï‡ËÈ. Ç ¯Ó¯ÓÌËÚÂ Ò Ó-‚‡ ëÚÓÏ·ÓÎË, ÒÓ‰Âʇ˘ÂÏ 9.5⋅10
–4
% Nd,
χÍÒËÏË̇Î˚ Ì ӷ̇ÛÊÂÌ˚ (Francalanci, 1989); ‚ „‡ÌÓ‰ËÓËÚ ËÁ ·‡-
ÚÓÎËÚ‡ ÇÓÒÚÓ˜Ì˚È èÂÌËÌÒÛÎfl êẨÊÂÒ (Gromet, Silver, 1983) ÒÓ‰ÂʇÌËÂ
Nd 4.3⋅10
–4
%, χÍÒËÏË̇ΠÚËÚ‡ÌËÚ, ‚ ÍÓÚÓÓÏ ÒÍÓ̈ÂÌÚËÓ‚‡ÌÓ 98%
χÒÒ Sm.
ùÔËÁӉ˘ÂÒÍË ÏË̇θÌ˚ ·‡Î‡ÌÒ˚ Óڇʇ˛Ú ‚ ÓÒÌÓ‚ÌÓÏ Ë̉˂ˉÛ-
‡Î¸Ì˚ ÓÒÓ·ÂÌÌÓÒÚË ËÁÛ˜ÂÌÌ˚ı „ÓÌ˚ı ÔÓÓ‰.
11.2.4. é·ÒÛʉÂÌË ÔÓÎÛ˜ÂÌÌ˚ı ‰‡ÌÌ˚ı
èË‚Ó‰ËÏ˚ ‰‡ÌÌ˚Â Ó Ò‰ÌÂÏ ÒÓ‰ÂʇÌËË Ce, Pr, Nd Ë Sm ‚ ‚ÂıÌÂÈ ˜‡-
ÒÚË ÍÓÌÚËÌÂÌڇθÌÓÈ ÍÓ˚ ·ÎËÁÍË Í ÎËÚ‡ÚÛÌ˚Ï. ùÚÓ ÍÓÒ‚ÂÌÌÓ Ò‚Ë‰Â-
ÚÂθÒÚ‚ÛÂÚ Ó ÚÓÏ, ˜ÚÓ ‰‡ÌÌ˚Â Ó Ò‰ÌÂÏ ÒÓ‰ÂʇÌËË Ce, Pr, Nd Ë Sm ‚ „Ó-
Ì˚ı ÔÓÓ‰‡ı ̇ ˝ÚÓÏ ˝Ú‡Ô ËÒÒΉӂ‡ÌËÈ ÏÓ„ÛÚ Ò˜ËÚ‡Ú¸Òfl ‰ÓÒÚ‡ÚÓ˜ÌÓ ÍÓ-
ÂÍÚÌ˚ÏË.
àÒıÓ‰Ì˚ ‰‡ÌÌ˚Â Ó ‚‡Ë‡ˆËflı ÒÓ‰ÂʇÌËÈ ‡ÍˆÂÒÒÓÌ˚ı ÏË̇ÎÓ‚ ‚
„ÓÌ˚ı ÔÓÓ‰‡ı, Í‡Í ÓÚϘ‡ÎÓÒ¸ ‚˚¯Â, ÔÂÛÏÂ̸¯ÂÌ˚, ÔÓ˝ÚÓÏÛ Ô˂‰ÂÌ-
Ì˚ Á‰ÂÒ¸ ÓˆÂÌÍË ÓÎË Ï‡ÍÒËÏË̇ÎÓ‚ Í‡Í ÌÓÒËÚÂÎÂÈ Ce, Pr, Nd Ë Sm – ÏË-
ÌËχθÌÓ ‚ÓÁÏÓÊÌ˚Â. éÚϘÂÌÌ˚ ÌÂÏÌÓ„Ó˜ËÒÎÂÌÌ˚ ÏË̇θÌ˚ ·‡-
·ÌÒ˚ Ce, Pr, Nd Ë Sm Óڇʇ˛Ú ‚ ÓÒÌÓ‚ÌÓÏ Ë̉˂ˉۇθÌ˚ ÓÒÓ·ÂÌÌÓÒÚË
ËÁÛ˜ÂÌÌ˚ı „ÓÌ˚ı ÔÓÓ‰. ëÓÔÓÒÚ‡‚ÎÂÌË Ëı ÔÓÁ‚ÓÎflÂÚ Ô‰ÔÓ·„‡Ú¸, ˜ÚÓ
Á̇˜ËÚÂθ̇fl Óθ χÍÒËÏË̇ÎÓ‚ ı‡‡ÍÚÂ̇ ‰Îfl „ÓÌ˚ı ÔÓÓ‰ Ò ÔÓ‚˚-
¯ÂÌÌ˚Ï ÒÓ‰ÂʇÌËÂÏ ÒÛÏÏ˚ ·ÌÚ‡ÌÓˉӂ.
245
臇Ò·̈˚
Ç ˆÂÎÓÏ
éÚÓÏÂÚ‡ÏÓÙ˘ÂÒÍË ÔÓÓ‰˚
Ç ˆÂÎÓÏ
åË̇Î˚
ɇÌËÚÓ-„ÌÂÈÒ˚åÂÚ‡ÔÂÒ˜‡ÌËÍË
éÚËÚ 1.34 4.75 4.5 4.92 11.3 4.43
(0.0012) (0.008) (0.0071) (0.0066) (0.008) (0.0056)
åÓ̇ˆËÚ 1.5 2.39 2.27 9 0.01 7.79
(0.0003) (0.0009) (0.0008) (0.0027) (2⋅10
–6
) (0.0022)
ŇÒÚÌÂÁËÚ ç ÓÔ. ç ÓÔ. ç ÓÔ. 1.18 (0.0012) ç ÓÔ. 1.04 (0.001)
ÇÒÂ„Ó 2.84 7.14 6.76 15.1 11.31 13.26
(0.0015) (0.0089) (0.0079) (0.0105) (0.008) (0.0088)
퇷Îˈ‡ 11.26
ÑÓÎË Ï‡ÒÒ Sm (%), ÒÍÓ̈ÂÌÚËÓ‚‡ÌÌ˚ ‚ χÍÒËÏË̇·ı ÏÂÚ‡ÏÓÙ˘ÂÒÍËı ÔÓÓ‰
臇ÏÂÚ‡ÏÓÙ˘ÂÒÍË ÔÓÓ‰˚
åÂÚ‡ËÓÎËÚ˚
11.2.5. Ç˚‚Ó‰˚
ë‰ÌË ÒÓ‰ÂʇÌËfl ‚ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌڇθÌÓÈ ÍÓ˚, %: Ce –
0.0063, Pr – 0.00087, Nd – 0.0029, Sm – 0.00057. É·‚Ì˚ ÍÓ̈ÂÌÚ‡ÚÓ˚
‚ÒÂı ˜ÂÚ˚Âı ˝ÎÂÏÂÌÚÓ‚ ÒËÂÌËÚ˚, ÓÒ‡‰Ó˜Ì˚ ÔÓÓ‰˚ Ë ÔÓ‰ÛÍÚ˚ Ëı ÏÂÚ‡-
ÏÓÙËÁχ. ÅÓθ¯Â ÔÓÎÓ‚ËÌ˚ χÒÒ ‚ÒÂı ˜ÂÚ˚Âı ˝ÎÂÏÂÌÚÓ‚ ÒÓÒ‰ÓÚÓ˜Â-
Ì˚ ‚ ÓÒ‡‰Ó˜Ì˚ı Ë Ô‡‡ÏÂÚ‡ÏÓÙ˘ÂÒÍËı ÔÓÓ‰‡ı: Ce – 55.8, Pr – 56.6, Nd –
57.6 Ë Sm – 55.9%.
Ç ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌڇθÌÓÈ ÍÓ˚ ‚ χÍÒËÏË̇·ı ÒÍÓ̈ÂÌÚË-
Ó‚‡ÌÓ 11.96% χÒÒ Ce, ‚ ÚÓÏ ˜ËÒΠÓÚËÚ – 5.64, ÏÓ̇ˆËÚ – 5.06, ·‡ÒÚÌÂ-
ÁËÚ – 1.26%; 12.06% χÒÒ Pr, ‚ ÚÓÏ ˜ËÒΠÏÓ̇ˆËÚ – 5.98, ÓÚËÚ – 4.86, ·‡-
ÒÚÌÂÁËÚ – 1.21; 9.13% χÒÒ Nd, ‚ ÚÓÏ ˜ËÒΠÏÓ̇ˆËÚ – 5.38, ÓÚËÚ – 3.48,
·‡ÒÚÌÂÁËÚ – 0.25, ËÚÚˇÎËÚ – 0.01, „‡‰ÓÎËÌËÚ – 0.01%; 7.43% χÒÒ Sm, ‚
ÚÓÏ ˜ËÒΠÏÓ̇ˆËÚ – 3.88, ÓÚËÚ – 3.2, ·‡ÒÚÌÂÁËÚ – 0.28, ËÚÚˇÎËÚ –
0.03, „‡‰ÓÎËÌËÚ – 0.02, ˝‚ÍÒÂÌËÚ 0.01, Ù„ÛÒÓÌËÚ – 0.01%. ùÚË ˆËÙ˚
ÏËÌËχθÌÓ ‚ÓÁÏÓÊÌ˚Â.
11.3. ÖÇêéèàâ, ÉÄÑéãàçàâ, íÖêÅàâ à Ñàëèêéáàâ
11.3.1. ë‰Ì ÒÓ‰ÂʇÌËÂ Ë ‡ÒÔ‰ÂÎÂÌË χÒÒ Eu, Gd, Tb Ë Dy
‚ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌڇθÌÓÈ ÍÓ˚
èË‚Ó‰ËÏ˚ Á‰ÂÒ¸ (Ú‡·Î. 11.27) Ò‰ÌË ÒÓ‰ÂʇÌËfl Eu, Gd, Tb Ë Dy ‚
‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌڇθÌÓÈ ÍÓ˚ Ë ‚ Ò·„‡˛˘Ëı  „ÓÌ˚ı ÔÓÓ‰‡ı ÒÓ-
ÓÚ‚ÂÚÒÚ‚Û˛Ú ÓÔÛ·ÎËÍÓ‚‡ÌÌ˚Ï ‡Ì¸¯Â (É˄Ӹ‚, 2003·), n⋅10
–4
%: Eu 1.3,
Gd 6.3, Tb 0.89 Ë Dy 4.8, ÌÓ ÓÌË ÌÂÒÍÓθÍÓ ·Óθ¯Â ÓÔÛ·ÎËÍÓ‚‡ÌÌ˚ı ‰Û„ËÏË
ËÒÒΉӂ‡ÚÂÎflÏË: Eu 0.88–1.21, Gd 2.8–4.21, Tb 0.48–0.7 Ë Dy 2.9–3.9
(Rudnick, Gao, 2004). é‰Ì‡ÍÓ ‡ÁÌˈ‡ ‚ ·Óθ¯ËÌÒÚ‚Â ÒÎÛ˜‡Â‚ Ì Ô‚ÓÒıÓ‰ËÚ
‚ÓÁÏÓÊÌ˚ı Ôӄ¯ÌÓÒÚÂÈ. ÇÒ ˜ÂÚ˚ ˝ÎÂÏÂÌÚ‡ «Ì‰ÓÒÚ‡ÚÓ˜Ì˚». àı
Ò‰ÌË ÒÓ‰ÂʇÌËfl ‚ ÒÓ‚ÓÍÛÔÌÓÒÚË ÍÓÌÚËÌÂÌڇθÌ˚ı ÓÒ‡‰Ó˜Ì˚ı ÔÓÓ‰ (Eu
9.4⋅10
–5
, Gd 4⋅10
–4
, Tb 6.9⋅10
–5
Ë Dy 3.6⋅10
–4
%) ÏÂ̸¯Â ÚÓ„Ó, ÍÓÚÓÓ ÏÓ„ÎÓ
·˚Ú¸ Û̇ÒΉӂ‡ÌÓ ÔË ‚˚‚ÂÚË‚‡ÌËË „‡ÌËÚÌÓ-„ÌÂÈÒÓ‚Ó„Ó ÒÎÓfl ÒÓ‚ÂÏÂÌ-
ÌÓ„Ó ÒÓÒÚ‡‚‡, ÒÓÓÚ‚ÂÚÒÚ‚ÂÌÌÓ, %: Eu – 1.1⋅10
–4
, Gd – 5.7⋅10
–4
, Tb – 7.7⋅10
–5
Ë
Dy – 4.2⋅10
–4
(‡Ò˜ÂÚ ËÁӇβÏËÌË‚˚Ï ÏÂÚÓ‰ÓÏ).
É·‚Ì˚ ÍÓ̈ÂÌÚ‡ÚÓ˚ ‚ÒÂı ˜ÂÚ˚Âı ˝ÎÂÏÂÌÚÓ‚ ÒËÂÌËÚ˚, ÌÓ Óθ Ëı
Í‡Í ÌÓÒËÚÂÎÂÈ Eu, Gd, Tb Ë Dy Ó˜Â̸ χ·. ÅÓθ¯Â ÔÓÎÓ‚ËÌ˚ χÒÒ ‚ÒÂı ˜Â-
Ú˚Âı ˝ÎÂÏÂÌÚÓ‚ ÒÓÒ‰ÓÚÓ˜ÂÌÓ ‚ ÏÂÚ‡ÏÓÙ˘ÂÒÍËı ÔÓÓ‰‡ı, %: Eu – 67.46,
Gd – 70.93, Tb – 64.3 Ë Dy – 68.2.
11.3.2. ÑÓÎË Ï‡ÒÒ Eu Ë Gd, ÒÍÓ̈ÂÌÚËÓ‚‡ÌÌ˚ ‚ χÍÒËÏË̇·ı
ùÚË ˝ÎÂÏÂÌÚ˚ χÍÒËχθÌÓ ÍÓ̈ÂÌÚËÛ˛ÚÒfl ‚ ‰ÍÓÁÂÏÂθÌ˚ı ÏËÌÂ-
‡Î‡ı, ÌÓ ÔÓ‚˚¯ÂÌÌÓ Ëı ÒÓ‰ÂʇÌË ı‡‡ÍÚÂÌÓ Ú‡ÍÊ ‰Îfl ÌËÓ·Ë‚˚ı,
Ú‡ÌÚ‡ÎÓ‚˚ı, ˆËÍÓÌË‚˚ı, ÚËÚ‡ÌÓ‚˚ı, Û‡ÌÓ‚˚ı, ÚÓË‚˚ı Ë ÌÂÍÓÚÓ˚ı
͇θˆË‚˚ı ÏË̇ÎÓ‚. äÓÏ ÚÓ„Ó, ÔÓ‚˚¯ÂÌÌ˚ ÒÓ‰ÂʇÌËfl Eu Ë Gd ˜‡Ò-
ÚÓ ÓÚϘ‡˛ÚÒfl ‚ „ˉÓÍÒËÎÒÓ‰Âʇ˘Ëı ˆÂÔӘ˜Ì˚ı Ë ÎËÒÚÓ‚˚ı ÒËÎË͇ڇı
246
247
Dy
Gd
ÑÓÎË Ï‡ÒÒ, %
Tb
Gd
Tb Dy Eu
퇷Îˈ‡ 11.27
ê‡ÒÔ‰ÂÎÂÌË Eu, Gd, Tb Ë Dy ‚ ‡ÒÒӈˇˆËË „ÓÌ˚ı ÔÓÓ‰ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌڇθÌÓÈ ÍÓ˚
ÉÓÌ˚Â ÔÓÓ‰˚
å‡ÒÒ‡
ÔÓÓ‰, %
ë‰Ì ÒÓ‰ÂʇÌËÂ, n⋅10
–4
%
Eu
èÂÒÍË Ë ÔÂÒ˜‡ÌËÍË 5.11 0.84 2.8 0.7 2.9 3.31 2.27 4 3.1
ÉÎËÌ˚ Ë „ÎËÌËÒÚ˚ Ò·̈˚ 10.4 1.2 5.8 0.83 4.4 9.62 9.56 9.7 9.6
䇷Ó̇ÚÌ˚ ÔÓÓ‰˚ 3.85 0.5 1.5 0.38 2.9 1.48 0.92 1.6 2.3
äÂÏÌËÒÚ˚ ÔÓÓ‰˚ 0.33 0.28 ç ÓÔ. 0.22 1.5 0.07 ç ÓÔ. 0.1 0.1
ù‚‡ÔÓËÚ˚ 0.26 ç ÓÔ. ç ÓÔ. ç ÓÔ. ç ÓÔ. ç ÓÔ. ç ÓÔ. ç ÓÔ. ç ÓÔ.
äËÒÎ˚ ‚ÛÎ͇ÌËÚ˚ 0.44 1.5 5 0.82 6 0.51 0.35 0.4 0.6
ë‰ÌË ‚ÛÎ͇ÌËÚ˚ 1.13 1.2 4.5 0.71 3 1.05 0.81 0.9 0.7
éÒÌÓ‚Ì˚ ‚ÛÎ͇ÌËÚ˚ 2.11 1.6 5.1 0.95 5.1 2.6 1.71 2.3 2.3
ɇÌËÚ˚ 8.21 1.4 6.8 1.1 5 8.86 8.85 10.2 8.6
ɇÌÓ‰ËÓËÚ˚ 3.38 1.4 6.1 1.3 5.2 3.65 3.27 5 3.7
ŇÁËÚ˚ 1.5 1.3 5.2 0.83 2.5 1.5 1.24 1.4 0.8
ëËÂÌËÚ˚ 0.05 1.8 10 1.6 7 0.07 0.08 0.1 0.1
ìθڇ·‡ÁËÚ˚ 0.05 0.24 0.93 0.2 0.28 0.01 0.01 < 0.1 < 0.1
åÂÚ‡ÔÂÒ˜‡ÌËÍË 2.92 0.76 4.3 0.48 4.9 1.71 1.99 1.6 3
臇„ÌÂÈÒ˚ Ë Ô‡‡Ò·̈˚ 30.56 1.4 7.5 0.94 5.7 32.99 36.32 32.4 36.5
åÂڇ͇·Ó̇ÚÌ˚ ÔÓÓ‰˚ 1.13 0.6 2.2 0.15 2.1 0.52 0.39 0.2 0.5
ÜÂÎÂÁËÒÚ˚ ÔÓÓ‰˚ 0.38 ç ÓÔ. ç ÓÔ. ç ÓÔ. ç ÓÔ. ç ÓÔ. ç ÓÔ. ç ÓÔ. ç ÓÔ.
ɇÌËÚÓ-„ÌÂÈÒ˚ 23.21 1.5 8.1 0.94 5.2 26.84 29.79 24.6 25.3
åÂÚ‡ËÓÎËÚ˚ 0.66 1.3 3.9 0.68 ç ÓÔ. 0.66 0.41 0.5 ç ÓÔ.
åÂÚ‡‡Ì‰ÂÁËÚ˚ 1.03 1.5 ç ÓÔ. 1.5 ç ÓÔ. 1.19 ç ÓÔ. 1.7 ç ÓÔ.
åÂÚ‡·‡ÁËÚ˚ 3.29 1.4 3.9 0.88 4.2 3.55 2.03 3.3 2.9
ÇÂıÌflfl ˜‡ÒÚ¸ ÍÓÌÚËÌÂÌڇθÌÓÈ ÍÓ˚ 100 1.297 6.31 0.887 4.77 100.19 100 99.9 100.1
éÒ‡‰Ó˜Ì˚ ÔÓÓ‰˚ 19.95 0.94 4.03 0.689 3.62 14.48 12.75 15.4 15.1
ÇÛÎ͇ÌËÚ˚ ÓÒ‡‰Ó˜ÌÓ„Ó ÒÎÓfl 3.68 1.47 4.91 0.861 4.56 4.16 2.87 3.6 3.6
éÒ‡‰Ó˜Ì˚È ÒÎÓÈ ‚ ˆÂÎÓÏ 23.63 1 4.17 0.716 3.77 18.64 15.62 19.0 18.7
凄χÚËÚ˚ „‡ÌËÚÌÓ-„ÌÂÈÒÓ‚Ó„Ó ÒÎÓfl 13.19 1.39 6.41 1.12 4.76 14.09 13.45 16.7 13.2
臇ÏÂÚ‡ÏÓÙËÚ˚ 34.99 1.3 6.98 0.866 5.46 35.22 38.7 34.2 40
éÚÓÏÂÚ‡ÏÓÙËÚ˚ 28.19 1.48 7.22 0.947 4.77 32.24 32.23 30.1 28.2
ɇÌËÚÌÓ-„ÌÂÈÒÓ‚˚È ÒÎÓÈ ‚ ˆÂÎÓÏ 76.37 1.38 6.97 0.94 5.08 81.55 84.38 80.9 81.4
Fe Ë Mg. ɇÌ˘Ì˚ ‰Îfl χÍÒËÏË̇ÎÓ‚ ÒÓ‰ÂʇÌËfl (É˄Ӹ‚, 1999) ÒÓ-
ÓÚ‚ÂÚÒÚ‚ÂÌÌÓ Eu 0.01 Ë Gd 0.03%. 肇fl ˆËÙ‡ ÌÓ‚‡fl, ÔË Â ÓÔ‰ÂÎÂÌËË
‚ ͇˜ÂÒÚ‚Â ˝Ú‡ÎÓÌÌÓ„Ó ÏË̇· ·˚Î ‚˚·‡Ì ‚ÂÈ̯ÂÌÍËÚ (χÍÒËχθÌÓÂ
ÒÓ‰ÂʇÌË Eu 0.98%). Ç ‰‡ÌÌÓÈ ‡·ÓÚ ۘÚÂÌ˚ ÚÓθÍÓ Ú ‰ÍÓÁÂÏÂθÌ˚Â
ÏË̇Î˚, ÍÓÚÓ˚ ӷ˚˜ÌÓ fl‚Îfl˛ÚÒfl ‚ÓÔË‚˚ÏË Ë „‡‰ÓÎËÌË‚˚ÏË Ï‡Í-
ÒËÏË̇·ÏË, ˜‡˘Â ‚ÒÂ„Ó ÏÓ̇ˆËÚ Ë ÓÚËÚ. Ç „‡ÌËÚÓˉ‡ı χÍÒËÏË̇-
ÎÓÏ ˝ÚËı ˝ÎÂÏÂÌÚÓ‚ ·˚‚‡ÂÚ ÚËÚ‡ÌËÚ, ÌÓ ‰‡ÌÌ˚ı ‰Îfl ÓÔ‰ÂÎÂÌËfl Â„Ó ÓÎË ‚
˝ÚÓÏ Í‡˜ÂÒÚ‚Â ÔÓ͇ ̉ÓÒÚ‡ÚÓ˜ÌÓ.
ë‰Ì ÒÓ‰ÂʇÌË χÍÒËÏË̇ÎÓ‚ ‚ „ÓÌ˚ı ÔÓÓ‰‡ı ÓÔ‰ÂÎÂÌÓ
ÔÓ ÂÁÛÎ¸Ú‡Ú‡Ï ÏË̇Îӄ˘ÂÒÍËı ‡Ì‡ÎËÁÓ‚ (‚ ÓÒÌÓ‚ÌÓÏ ÍÓ΢ÂÒÚ‚ÂÌ-
Ì˚ı), ÓÔÛ·ÎËÍÓ‚‡ÌÌ˚ı ‚ ÎËÚ‡ÚÛÂ. è‚ÓËÒÚÓ˜ÌËÍË Ô˂‰ÂÌ˚ ‚ Ô‰-
¯ÂÒÚ‚Û˛˘Ëı ‡Á‰Â·ı, ‚ ˜‡ÒÚÌÓÒÚË ‚ ‡Á‰ÂΠ6.2.2. ëӄ·ÒÌÓ ÔÓÎÛ˜ÂÌÌ˚Ï
‰‡ÌÌ˚Ï, Óθ χÍÒËÏË̇ÎÓ‚ Í‡Í ÌÓÒËÚÂÎÂÈ Eu Ë Gd ÒÛ˘ÂÒÚ‚ÂÌ̇ ‚ „‡-
ÌËÚÌÓ-„ÌÂÈÒÓ‚ÓÏ ÒÎÓÂ Ë ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌڇθÌÓÈ ÍÓ˚ ‚ ˆÂÎÓÏ
248
ÑÓÎË Ï‡ÒÒ
Eu, %
ÑÓÎË Ï‡ÒÒ
Eu, %
ëÓ‰ÂʇÌËÂ
ÏË̇ÎÓ‚, %
ÑÓÎË Ï‡ÒÒ
Eu, %
ëÓ‰ÂʇÌËÂ
ÏË̇ÎÓ‚, %
ÇÂıÌflfl ˜‡ÒÚ¸ ÍÓÌÚËÌÂÌ-
ڇθÌÓÈ ÍÓ˚
åË̇Î˚
ëÓ‰ÂʇÌËÂ
ÏË̇ÎÓ‚, %
ɇÌËÚÌÓ-„ÌÂÈÒÓ‚˚È ÒÎÓÈ
éÚËÚ 0.019 6⋅10
–5
0.01 0.0063 0.86 0.0048 0.7
ÅÎÓÏÒڇ̉ËÌ 0.02 ç ÓÔ. ç ÓÔ. 1.2⋅10
–6
< 0.01 9⋅10
–7
< 0.01
êËÌÍÓÎËÚ 0.03 ç ÓÔ. ç ÓÔ. 6.9⋅10
–9
< 0.01 5.3⋅10
–9
< 0.01
àÚÚˇÎËÚ 0.042 ç ÓÔ. ç ÓÔ. 2.1⋅10
–5
0.01 1.6⋅10
–5
0.01
åÓ̇ˆËÚ 0.09 4.6⋅10
–5
0.04 0.0016 1.03 0.0013 0.9
ŇÒÚÌÂÁËÚ 0.1 ç ÓÔ. ç ÓÔ. 4.2⋅10
–4
0.3 3.2⋅10
–4
0.25
ó‚ÍËÌËÚ 0.13 ç ÓÔ. ç ÓÔ. 5.5⋅10
–7
< 0.01 4.2⋅10
–7
< 0.01
î„ÛÒÓÌËÚ 0.3 ç ÓÔ. ç ÓÔ. 3.1⋅10
–6
0.01 2.4⋅10
–6
0.01
ëÛÏχ 1.06⋅10
–4
0.05 0.0083 2.21 0.0064 1.87
퇷Îˈ‡ 11.28
êÓθ χÍÒËÏË̇ÎÓ‚ Í‡Í ÌÓÒËÚÂÎÂÈ Eu ‚ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌڇθÌÓÈ ÍÓ˚
ëÓ‰ÂʇÌËÂ
Eu ‚ ÏËÌÂ-
‡Î‡ı, %
éÒ‡‰Ó˜Ì˚È ÒÎÓÈ
ÑÓÎË Ï‡ÒÒ
Gd, %
ÑÓÎË Ï‡ÒÒ
Gd, %
ëÓ‰ÂʇÌËÂ
ÏË̇ÎÓ‚, %
ÑÓÎË Ï‡ÒÒ
Gd, %
ëÓ‰ÂʇÌËÂ
ÏË̇ÎÓ‚, %
ÇÂıÌflfl ˜‡ÒÚ¸ ÍÓÌÚËÌÂÌ-
ڇθÌÓÈ ÍÓ˚
åË̇Î˚
ëÓ‰ÂʇÌËÂ
ÏË̇ÎÓ‚, %
ɇÌËÚÌÓ-„ÌÂÈÒÓ‚˚È ÒÎÓÈ
éÚËÚ 0.19 6⋅10
–5
0.03 0.0063 1.71 0.0048 1.45
ŇÒÚÌÂÁËÚ 0.2 ç ÓÔ. ç ÓÔ. 4.2⋅10
–4
0.12 3.2⋅10
–4
0.1
ó‚ÍËÌËÚ 0.7 ç ÓÔ. ç ÓÔ. 5.5⋅10
–7
< 0.01 4.2⋅10
–7
< 0.01
ù‚ÍÒÂÌËÚ 1 ç ÓÔ. ç ÓÔ. 8.6⋅10
–6
0.01 6.6⋅10
–6
0.01
ÅÎÓÏÒڇ̉ËÌ 1.1 ç ÓÔ. ç ÓÔ. 1.2⋅10
–6
< 0.01 9⋅10
–7
< 0.01
åÓ̇ˆËÚ 1.2 4.6⋅10
–5
0.13 0.0016 2.74 0.0013 2.48
ɇ‰ÓÎËÌËÚ 1.9 ç ÓÔ. ç ÓÔ. 5.2⋅10
–6
0.01 4⋅10
–6
0.01
äÒÂÌÓÚËÏ 2 1⋅10
–5
0.05 5⋅10
–5
0.14 3.7⋅10
–5
0.13
àÚÚˇÎËÚ 2.06 ç ÓÔ. ç ÓÔ. 2.1⋅10
–5
0.06 1.6⋅10
–5
0.05
î„ÛÒÓÌËÚ 3 ç ÓÔ. ç ÓÔ. 3.1⋅10
–6
0.01 2.4⋅10
–6
0.01
ÇÒÂ„Ó 1.06⋅10
–4
0.21 0.0083 4.8 0.0064 4.24
퇷Îˈ‡ 11.29
êÓθ χÍÒËÏË̇ÎÓ‚ Í‡Í ÌÓÒËÚÂÎÂÈ Gd ‚ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌڇθÌÓÈ ÍÓ˚
ëÓ‰ÂʇÌËÂ
Gd ‚ ÏËÌÂ-
‡Î‡ı, %
éÒ‡‰Ó˜Ì˚È ÒÎÓÈ
(Ú‡·Î. 11.28, 11.29). àÁ „ÓÌ˚ı ÔÓÓ‰ ÓÒ‡‰Ó˜ÌÓ„Ó ÒÎÓfl ËÁÛ˜ÂÌ˚ ÚÓθÍÓ ÔÂÒ-
ÍË, ÍËÒÎ˚Â Ë Ò‰ÌË ‚ÛÎ͇ÌËÚ˚. êÓθ χÍÒËÏË̇ÎÓ‚ ̇˷ÓΠÁ̇˜Ë-
ÚÂθ̇ ‚ ÒÎÂ‰Û˛˘Ëı „ÓÌ˚ı ÔÓÓ‰‡ı: ÍËÒÎ˚ı ‚ÛÎ͇ÌËÚ‡ı (Ú‡·Î. 11.30,
11.31), „‡ÌËÚ‡ı, ÒËÂÌËÚ‡ı (Ú‡·Î. 11.32, 11.33), „‡ÌËÚÓ-„ÌÂÈÒ‡ı (Ú‡·Î. 11.34,
11.35). Ç ‰ÓÔÓÎÌÂÌËÂ Í ‰‡ÌÌ˚Ï Ú‡·Î. 11.34 Ë 11.35 ÓÚÏÂÚËÏ, ˜ÚÓ ‚ ÏÂÚ‡·‡ÁË-
Ú‡ı ÛÒÚ‡ÌÓ‚ÎÂÌ ÏÓ̇ˆËÚ (҉̠ÒÓ‰ÂʇÌË 4⋅10
–8
%), ÌÓ ÒÍÓ̈ÂÌÚËÓ-
‚‡ÌÌ˚ ‚ ÌÂÏ ‰ÓÎË Ï‡ÒÒ Eu Ë Gd < 0.01%.
249
Ç ˆÂÎÓÏ
ÇÛÎ͇ÌÓ„ÂÌÌ˚ ÔÓÓ‰˚
Ç ˆÂÎÓÏ
åË̇Î˚
äËÒÎ˚ÂèÂÒÍË Ë ÔÂÒ˜‡ÌËÍË
éÚËÚ < 0.01 (7⋅10
–8
) < 0.01 (1.8⋅10
–8
) 0.38 (0.003) 0.02 (1⋅10
–4
) 0.05 (4⋅10
–4
)
åÓ̇ˆËÚ 0.14 (1.3⋅10
–4
) 0.03 (3.3⋅10
–5
) 0.6 (0.001) ç ÓÔ. 0.07 (1.2⋅10
–4
)
ÇÒÂ„Ó 0.14 (1.3⋅10
–4
) 0.03 (3.3⋅10
–5
) 0.98 (0.004) 0.02 (1⋅10
–4
) 0.12 (5.2⋅10
–4
)
퇷Îˈ‡ 11.30
ÑÓÎË Ï‡ÒÒ Eu (%), ÒÍÓ̈ÂÌÚËÓ‚‡ÌÌ˚ ‚ χÍÒËÏË̇·ı
„ÓÌ˚ı ÔÓÓ‰ ÓÒ‡‰Ó˜ÌÓ„Ó ÒÎÓfl
éÒ‡‰Ó˜Ì˚ ÔÓÓ‰˚
ë‰ÌËÂ
èËϘ‡ÌËÂ. á‰ÂÒ¸ Ë ‚ ÔÓÒÎÂ‰Û˛˘Ëı Ú‡·Îˈ‡ı ‚ ÒÍӷ͇ı – ÒÓ‰ÂʇÌË ÏË̇ÎÓ‚, %.
Ç ˆÂÎÓÏ
ÇÛÎ͇ÌÓ„ÂÌÌ˚ ÔÓÓ‰˚
Ç ˆÂÎÓÏ
åË̇Î˚
äËÒÎ˚ÂèÂÒÍË Ë ÔÂÒ˜‡ÌËÍË
éÚËÚ < 0.01 (7⋅10
–8
) < 0.01(1.8⋅10
–8
) 1.14 (0.003) 0.04 (1⋅10
–4
) 0.16 (4⋅10
–4
)
åÓ̇ˆËÚ 0.56 (1.3⋅10
–4
) 0.1 (3.3⋅10
–5
) 2.4 (0.001) ç ÓÔ. 0.29 (1.2⋅10
–4
)
äÒÂÌÓÚËÏ 0.29 (4⋅10
–5
) 0.05 (1⋅10
–4
) 0.12 (3⋅10
–5
) ç ÓÔ. 0.02 (3.6⋅10
–6
)
ÇÒÂ„Ó 0.85 (1.3⋅10
–4
) 0.15 (3⋅10
–5
) 3.66 (0.004) 0.04 (1⋅10
–4
) 0.47 (5⋅10
–4
)
퇷Îˈ‡ 11.31
ÑÓÎË Ï‡ÒÒ Gd (%), ÒÍÓ̈ÂÌÚËÓ‚‡ÌÌ˚ ‚ χÍÒËÏË̇·ı
„ÓÌ˚ı ÔÓÓ‰ ÓÒ‡‰Ó˜ÌÓ„Ó ÒÎÓfl
éÒ‡‰Ó˜Ì˚ ÔÓÓ‰˚
ë‰ÌËÂ
ɇÌÓ‰ËÓËÚ˚åË̇Î˚ ëËÂÌËÚ˚ɇÌËÚ˚
éÚËÚ 1.09 (0.008) 0.41 (0.003) 2.43 (0.023) 0.79 (0.0058)
ÅÎÓÏÒڇ̉ËÌ < 0.01 (8.7⋅10
–6
) ç ÓÔ. 0.04 (3.3⋅10
–4
) < 0.01 (6.7⋅10
–6
)
àÚÚˇÎËÚ 0.06 (2⋅10
–4
) ç ÓÔ. ç ÓÔ. 0.04 (1.2⋅10
–4
)
åÓ̇ˆËÚ 2.76 (0.0043) 0.26 (4⋅10
–4
) 1.2 (0.0024) 1.8 (0.0028)
ŇÒÚÌÂÁËÚ 0.34 (4.7⋅10
–4
) ç ÓÔ. ç ÓÔ. 0.21 (2.9⋅10
–4
)
ó‚ÍËÌËÚ < 0.01 (1.5⋅10
–6
) ç ÓÔ. 0.43 (6⋅10
–4
) < 0.01 (3.2⋅10
–6
)
î„ÛÒÓÌËÚ 0.03 (1.5⋅10
–5
) 0.07 (3.2⋅10
–5
) 0.01 (3.8⋅10
–6
) 0.04 (1.8⋅10
–5
)
ÇÒÂ„Ó 4.28 (0.013) 0.74 (0.0034) 4.11 (0.0263) 2.88 (0.0091)
퇷Îˈ‡ 11.32
ÑÓÎË Ï‡ÒÒ Eu (%), ÒÍÓ̈ÂÌÚËÓ‚‡ÌÌ˚ ‚ χÍÒËÏË̇·ı
χ„χÚ˘ÂÒÍËı ÔÓÓ‰ „‡ÌËÚÌÓ-„ÌÂÈÒÓ‚Ó„Ó ÒÎÓfl
凄χÚ˘ÂÒÍËÂ
ÔÓÓ‰˚ ‚ ˆÂÎÓÏ
250
ɇÌÓ‰ËÓËÚ˚åË̇Î˚ ëËÂÌËÚ˚ɇÌËÚ˚
éÚËÚ 2.24 (0.008) 0.93 (0.003) 8.4 (0.023) 1.72 (0.0058)
ŇÒÚÌÂÁËÚ 0.14 (4.7⋅10
–4
) ç ÓÔ. ç ÓÔ. 0.09 (2.9⋅10
–4
)
ó‚ÍËÌËÚ < 0.01 (1.5⋅10
–6
) ç ÓÔ. 0.81 (0.0006) < 0.01 (3.2⋅10
–6
)
ù‚ÍÒÂÌËÚ 0.12 (8⋅10
–5
) ç ÓÔ. < 0.01 (8⋅10
–8
) 0.08(5
.
10
–5
)
ÅÎÓÏÒڇ̉ËÌ 0.01 (8.7⋅10
–6
) ç ÓÔ. 0.7 (3.3⋅10
–4
) 0.01 (6.7⋅10
–6
)
åÓ̇ˆËÚ 7.59 (0.0043) 0.79 (0.0004) 5.54 (0.0024) 5.25 (0.0028)
ɇ‰ÓÎËÌËÚ 0.14 (5⋅10
–5
) ç ÓÔ. 0.01 (3⋅10
–6
) 0.09 (3⋅10
–5
)
äÒÂÌÓÚËÏ 0.59 (0.0002) 0.01 (3⋅10
–6
) 0.01 (2.7⋅10
–6
) 0.31 (1.3⋅10
–4
)
àÚÚˇÎËÚ 0.61 (2⋅10
–4
) ç ÓÔ. ç ÓÔ. 0.39 (1.2⋅10
–4
)
î„ÛÒÓÌËÚ 0.07 (1.5⋅10
–5
) 0.16 (3.2⋅10
–5
) 0.02 (3.8⋅10
–6
) 0.08 (1.8⋅10
–5
)
ÇÒÂ„Ó 11.51 (0.013) 1.89 (0.0034) 15.49 (0.026) 8.02 (0.0091)
퇷Îˈ‡ 11.33
ÑÓÎË Ï‡ÒÒ Gd (%), ÒÍÓ̈ÂÌÚËÓ‚‡ÌÌ˚ ‚ χÍÒËÏË̇·ı
χ„χÚ˘ÂÒÍËı ÔÓÓ‰ „‡ÌËÚÌÓ-„ÌÂÈÒÓ‚Ó„Ó ÒÎÓfl
凄χÚ˘ÂÒÍËÂ
ÔÓÓ‰˚ ‚ ˆÂÎÓÏ
臇Ò·̈˚ Ç ˆÂÎÓÏ
éÚÓÏÂÚ‡ÏÓÙ˘ÂÒÍË ÔÓÓ‰˚
Ç ˆÂÎÓÏ
åË̇Î˚
ɇÌËÚÓ-„ÌÂÈÒ˚åÂÚ‡ÔÂÒ˜‡ÌËÍË
éÚËÚ 0.3 1.09 1.04 0.84 1.17 0.71
(0.0012) (0.008) (0.0071) (0.0066) (0.008) (0.0056)
åÓ̇ˆËÚ 0.36 0.58 0.55 1.62 < 0.01 1.32
(3⋅10
–4
)(9⋅10
–4
)(8⋅10
–4
) (0.0027) (2⋅10
–6
) (0.0022)
ŇÒÚÌÂÁËÚ ç ÓÔ. ç ÓÔ. ç ÓÔ. 0.8 ç ÓÔ. 0.67
(0.0012) (0.001)
ÇÒÂ„Ó 0.66 1.67 1.59 3.26 1.17 2.7
(0.0015) (0.0089) (0.0079) (0.0094) (0.008) (0.0079)
퇷Îˈ‡ 11.34
ÑÓÎË Ï‡ÒÒ Eu (%), ÒÍÓ̈ÂÌÚËÓ‚‡ÌÌ˚ ‚ χÍÒËÏË̇·ı ÏÂÚ‡ÏÓÙ˘ÂÒÍËı ÔÓÓ‰
臇ÏÂÚ‡ÏÓÙ˘ÂÒÍË ÔÓÓ‰˚
åÂÚ‡ËÓÎËÚ˚
臇Ò·̈˚
Ç ˆÂÎÓÏ
éÚÓÏÂÚ‡ÏÓÙ˘ÂÒÍË ÔÓÓ‰˚
Ç ˆÂÎÓÏ
åË̇Î˚
ɇÌËÚÓ-„ÌÂÈÒ˚åÂÚ‡ÔÂÒ˜‡ÌËÍË
éÚËÚ 0.53 2.03 1.93 1.55 3.9 1.48
(0.0012) (0.008) (0.0071) (0.0066) (0.008) (0.0056)
ŇÒÚÌÂÁËÚ ç ÓÔ. ç ÓÔ. ç ÓÔ. 0.3 ç ÓÔ. 0.28
(0.0012) (0.001)
åÓ̇ˆËÚ 0.84 1.44 1.37 4 (0.0027) 0.01 3.67
(0.0003) (0.0009) (0.0008) (2⋅10
–6
) (0.0022)
äÒÂÌÓÚËÏ ç ÓÔ. ç ÓÔ. ç ÓÔ. 0.2 ç ÓÔ. 0.17
(7.5⋅10
–5
) (6.2⋅10
–5
)
ÇÒÂ„Ó 1.37 3.47 3.3 6.05 3.9 5.6
(0.0015) (0.0089) (0.0079) (0.0105) (0.008) (0.0088)
퇷Îˈ‡ 11.35
ÑÓÎË Ï‡ÒÒ Gd (%), ÒÍÓ̈ÂÌÚËÓ‚‡ÌÌ˚ ‚ χÍÒËÏË̇·ı ÏÂÚ‡ÏÓÙ˘ÂÒÍËı ÔÓÓ‰
臇ÏÂÚ‡ÏÓÙ˘ÂÒÍË ÔÓÓ‰˚
åÂÚ‡ËÓÎËÚ˚