Григорьев Н.А. Распределение химических элементов в верхней части континентальной коры
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231
Y La Y LaSc
ÉÓÌ˚Â ÔÓÓ‰˚
Sc
ÑÓÎË Ï‡ÒÒ, %
èÂÒÍË Ë ÔÂÒ˜‡ÌËÍË 5.11 6 29 20 1.97 5.8 3.2
ÉÎËÌ˚ Ë „ÎËÌËÒÚ˚Â
Ò·̈˚ 10.4 15 31 48 10 12.6 15.4
䇷Ó̇ÚÌ˚ ÔÓÓ‰˚ 3.85 1.7 30 7 0.42 4.5 0.8
äÂÏÌËÒÚ˚ ÔÓÓ‰˚ 0.33 4.5 ç ÓÔ. 16 0.1 ç ÓÔ. 0.2
ù‚‡ÔÓËÚ˚ 0.26 ç ÓÔ. ç ÓÔ. ç ÓÔ. ç ÓÔ. ç ÓÔ. ç ÓÔ.
äËÒÎ˚ ‚ÛÎ͇ÌËÚ˚ 0.44 4.2 24 31 0.12 0.4 0.4
ë‰ÌË ‚ÛÎ͇ÌËÚ˚ 1.13 15 19 28 1.09 0.8 1
éÒÌÓ‚Ì˚ ‚ÛÎ͇ÌËÚ˚ 2.11 31 25 19 4.19 2.1 1.2
ɇÌËÚ˚ 8.21 6.5 50 48 3.42 16 12.2
ɇÌÓ‰ËÓËÚ˚ 3.38 13 36 51 2.82 4.8 5.3
ŇÁËÚ˚ 1.5 30 23 17 2.89 1.3 0.8
ëËÂÌËÚ˚ 0.05 3 17 45 0.01 < 0.1 0.1
ìθڇ·‡ÁËÚ˚ 0.05 12 2 3.9 0.04 < 0.1 < 0.1
åÂÚ‡ÔÂÒ˜‡ÌËÍË 2.92 5.4 15 22 1.01 1.7 2
臇„ÌÂÈÒ˚ Ë Ô‡‡-
Ò·̈˚ 30.56 16 24 32 31.34 28.6 30.2
åÂڇ͇·Ó̇ÚÌ˚Â
ÔÓÓ‰˚ 1.13 1.8 4 26 0.13 0.2 0.9
ÜÂÎÂÁËÒÚ˚ ÔÓÓ‰˚ 0.38 ç ÓÔ. 20 ç ÓÔ ç ÓÔ. 0.3 ç ÓÔ.
ɇÌËÚÓ-„ÌÂÈÒ˚ 23.21 21 17 33 31.24 15.4 23.6
åÂÚ‡ËÓÎËÚ˚ 0.66 8.6 53 20 0.36 1.4 0.4
åÂÚ‡‡Ì‰ÂÁËÚ˚ 1.03 11 24 34 0.73 1 1.1
åÂÚ‡·‡ÁËÚ˚ 3.29 34 24 12 7.17 3.1 1.2
ÇÂıÌflfl ˜‡ÒÚ¸ ÍÓÌÚË-
ÌÂÌڇθÌÓÈ ÍÓ˚ 100 15.6 25.61 32.38 99.04 100 100
éÒ‡‰Ó˜Ì˚ ÔÓÓ‰˚ 19.95 9.7 29.37 31.76 12.49 22.9 19.6
ÇÛÎ͇ÌËÚ˚ ÓÒ‡‰Ó˜-
ÌÓ„Ó ÒÎÓfl 3.68 23 23.04 23.2 5.4 3.3 2.6
éÒ‡‰Ó˜Ì˚È ÒÎÓÈ ‚
ˆÂÎÓÏ 23.63 11.7 28.39 30.43 17.89 26.2 22.2
凄χÚËÚ˚ „‡ÌËÚÌÓ-
„ÌÂÈÒÓ‚Ó„Ó ÒÎÓfl 13.19 10.9 43.03 45.08 9.17 22.1 18.3
臇ÏÂÚ‡ÏÓÙËÚ˚ 34.99 14.4 22.57 30.63 32,48 30.8 33.1
éÚÓÏÂÚ‡ÏÓÙËÚ˚ 28.19 22 18.92 30.29 39.5 20.9 26.4
ɇÌËÚÌÓ-„ÌÂÈÒÓ‚˚È
ÒÎÓÈ ‚ ˆÂÎÓÏ 76.37 16.6 24.75 32.99 81.15 73.8 77.8
퇷Îˈ‡ 11.1
ê‡ÒÔ‰ÂÎÂÌË χÒÒ Sc, Y Ë La ‚ ‡ÒÒӈˇˆËË „ÓÌ˚ı ÔÓÓ‰ ‚ÂıÌÂÈ ˜‡ÒÚË
ÍÓÌÚËÌÂÌڇθÌÓÈ ÍÓ˚
å‡ÒÒ‡
ÔÓÓ‰, %
ë‰Ì ÒÓ‰ÂʇÌËÂ, n⋅10
–4
%
å‡ÍÒËÏË̇·ÏË Sc, Y Ë La ÏÓ„ÛÚ ·˚Ú¸ Ì ÚÓθÍÓ Ëı ÒÓ·ÒÚ‚ÂÌÌ˚ ÏË̇-
Î˚, ÌÓ Ë ÌÂÍÓÚÓ˚ ˜ÛÊËÂ. чÌÌ˚ı Ó ‚‡Ë‡ˆËflı Ò͇̉Ë‚˚ı ÏË̇ÎÓ‚ ‚
„ÓÌ˚ı ÔÓÓ‰‡ı χÎÓ, ‡ ÒÂ‰Ë ÌÂÒ͇̉Ë‚˚ı ÌÂÚ Ú‡ÍËı, „‰Â ·˚ ÔÂӷ·‰‡ÎÓ
ÒÓ‰ÂʇÌË Sc > 0.3%, ÔÓ˝ÚÓÏÛ ‚ÓÔÓÒ Ó ÓÎË Ò͇̉Ë‚˚ı χÍÒËÏË̇ÎÓ‚
‚ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌڇθÌÓÈ ÍÓ˚ ÔÓ͇ ÓÒÚ‡ÂÚÒfl ÓÚÍ˚Ú˚Ï. ë‰ÌËÂ
ÒÓ‰ÂʇÌËfl χÍÒËÏË̇ÎÓ‚ Y Ë La ‚ „ÓÌ˚ı ÔÓÓ‰‡ı ‡ÒÒ˜ËÚ‡Ì˚ ÔÓ ÓÔÛ·-
ÎËÍÓ‚‡ÌÌ˚Ï ÂÁÛÎ¸Ú‡Ú‡Ï ÍÓ΢ÂÒÚ‚ÂÌÌ˚ı ÏË̇Îӄ˘ÂÒÍËı ‡Ì‡ÎËÁÓ‚
·ÓΠ˜ÂÏ 2480 ÔÓ· „ÓÌ˚ı ÔÓÓ‰. àÒÚÓ˜ÌËÍË ËÒıÓ‰Ì˚ı ‰‡ÌÌ˚ı Ô˂‰Â-
Ì˚ ‚ Ô‰¯ÂÒÚ‚Û˛˘Ëı ‡Á‰Â·ı, ‚ ˜‡ÒÚÌÓÒÚË ‚ ‡Á‰ÂΠ6.2.2.
ëӄ·ÒÌÓ ÔÓÎÛ˜ÂÌÌ˚Ï ‰‡ÌÌ˚Ï, Óθ χÍÒËÏË̇ÎÓ‚ Í‡Í ÌÓÒËÚÂÎÂÈ Y Ë
La ÒÛ˘ÂÒÚ‚ÂÌ̇ ‚ „‡ÌËÚÌÓ-„ÌÂÈÒÓ‚ÓÏ ÒÎÓÂ Ë ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌڇθ-
ÌÓÈ ÍÓ˚ ‚ ˆÂÎÓÏ (Ú‡·Î. 11.2, 11.3). Ç „ÓÌ˚ı ÔÓÓ‰‡ı ÓÒ‡‰Ó˜ÌÓ„Ó ÒÎÓfl ˝Ú‡
Óθ ÏËÌËχθ̇ (Ú‡·Î. 11.4, 11.5). é̇ χÍÒËχθ̇ ‚ ÒËÂÌËÚ‡ı Ë „‡ÌË-
232
ÑÓÎË Ï‡ÒÒ
Y, %
ÑÓÎË Ï‡ÒÒ
Y, %
ëÓ‰ÂʇÌËÂ
ÏË̇ÎÓ‚, %
ÑÓÎË Ï‡ÒÒ
Y, %
ëÓ‰ÂʇÌËÂ
ÏË̇ÎÓ‚, %
ÇÂıÌflfl ˜‡ÒÚ¸ ÍÓÌÚËÌÂÌ-
ڇθÌÓÈ ÍÓ˚
åË̇Î˚
ëÓ‰ÂʇÌËÂ
ÏË̇ÎÓ‚, %
ɇÌËÚÌÓ-„ÌÂÈÒÓ‚˚È ÒÎÓÈ
ó‚ÍËÌËÚ 0.47 ç ÓÔ. ç ÓÔ. 5.5⋅10
–7
<0.01 4.2⋅10
–7
< 0.01
éÚËÚ 1 6⋅10
–5
0.02 0.0063 2.52 0.0048 1.85
ì‡ÌËÌËÚ 1.5 9.3⋅10
–7
< 0.01 8.6⋅10
–6
0.01 6.6⋅10
–6
< 0.01
åÓ̇ˆËÚ 2.9 4.6
.
10
–5
0.05 0.0016 1.86 0.0013 1.45
ꇷ‰ÓÙ‡Ì 6 ç ÓÔ. ç ÓÔ. 4.7⋅10
–7
< 0.01 3.3⋅10
–7
< 0.01
ÑÂÎÓÂ̈ËÚ 8.4 ç ÓÔ. ç ÓÔ. 8.6⋅10
–9
< 0.01 6.6⋅10
–9
< 0.01
ù‚ÍÒÂÌËÚ 10.2 ç ÓÔ. ç ÓÔ. 8.6⋅10
–6
0.04 6.6⋅10
–6
0.03
î„ÛÒÓÌËÚ 18.2 ç ÓÔ. ç ÓÔ. 3.1⋅10
–6
0.02 2.4⋅10
–6
0.02
àÚÚˇÎËÚ 22.8 ç ÓÔ. ç ÓÔ. 2.1⋅10
–5
0.19 1.6⋅10
–5
0.14
ÅÎÓÏÒڇ̉ËÌ 26.5 ç ÓÔ. ç ÓÔ. 1.2⋅10
–6
0.01 9⋅10
–7
0.01
ɇ‰ÓÎËÌËÚ 33 ç ÓÔ. ç ÓÔ. 5.2⋅10
–6
0.07 4⋅10
–6
0.06
äÒÂÌÓÚËÏ 48.2 1⋅10
–5
0.17 4.6⋅10
–5
0.89 3.7⋅10
–5
0.69
ÇÒÂ„Ó 1⋅10
–4
0.24 0.008 5.61 0.0062 4.25
퇷Îˈ‡ 11.2
êÓθ χÍÒËÏË̇ÎÓ‚ Í‡Í ÌÓÒËÚÂÎÂÈ Y ‚ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌڇθÌÓÈ ÍÓ˚
ëÓ‰ÂʇÌËÂ
Y ‚ ÏËÌÂ-
‡Î‡ı, %
éÒ‡‰Ó˜Ì˚È ÒÎÓÈ
ÑÓÎË Ï‡ÒÒ
La, %
ÑÓÎË Ï‡ÒÒ
La, %
ëÓ‰ÂʇÌËÂ
ÏË̇ÎÓ‚, %
ÑÓÎË Ï‡ÒÒ
La, %
ëÓ‰ÂʇÌËÂ
ÏË̇ÎÓ‚, %
ÇÂıÌflfl ˜‡ÒÚ¸ ÍÓÌÚËÌÂÌ-
ڇθÌÓÈ ÍÓ˚
åË̇Î˚
ëÓ‰ÂʇÌËÂ
ÏË̇ÎÓ‚, %
ɇÌËÚÌÓ-„ÌÂÈÒÓ‚˚È ÒÎÓÈ
àÚÚˇÎËÚ 0.32 ç ÓÔ. ç ÓÔ. 2.1⋅10
–5
< 0.01 1.6⋅10
–5
< 0.01
î„ÛÒÓÌËÚ 1.1 ç ÓÔ. ç ÓÔ. 3.1⋅10
–6
< 0.01 2.4⋅10
–6
< 0.01
éÚËÚ 4 6⋅10
–5
0.08 0.0063 7.64 0.0048 6
ɇ‰ÓÎËÌËÚ 5.7 ç ÓÔ. ç ÓÔ. 5.2⋅10
–6
0.01 4⋅10
–6
0.01
ó‚ÍËÌËÚ 9 ç ÓÔ. ç ÓÔ. 5.5⋅10
–7
< 0.01 4.2⋅10
–7
< 0.01
åÓ̇ˆËÚ 13 4.6⋅10
–5
0.2 0.0016 6.3 0.0013 5.28
ŇÒÚÌÂÁËÚ 14 ç ÓÔ. ç ÓÔ. 0.00042 1.78 0.00032 1.4
ÇÒÂ„Ó 1.1⋅10
–4
0.28 0.0084 15.73 0.0064 12.69
퇷Îˈ‡ 11.3
êÓθ χÍÒËÏË̇ÎÓ‚ Í‡Í ÌÓÒËÚÂÎÂÈ La ‚ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌڇθÌÓÈ ÍÓ˚
ëÓ‰ÂʇÌËÂ
La ‚ ÏËÌÂ-
‡Î‡ı, %
éÒ‡‰Ó˜Ì˚È ÒÎÓÈ
Ç ˆÂÎÓÏ
ÇÛÎ͇ÌÓ„ÂÌÌ˚ ÔÓÓ‰˚
233
Ç ˆÂÎÓÏ
åË̇Î˚
äËÒÎ˚ÂèÂÒÍË Ë ÔÂÒ˜‡ÌËÍË
éÚËÚ < 0.01 (7⋅10
–8
) < 0.01 (1.8⋅10
–8
) 1.25 (0.003) 0.05 (1⋅10
–4
) 0.17 (4⋅10
–4
)
ì‡ÌËÌËÚ ç ÓÔ. ç ÓÔ. 0.03 (5⋅10
–5
) ç ÓÔ. < 0.01 (6⋅10
–6
)
åÓ̇ˆËÚ 0.13 (1.3⋅10
–4
) 0.03 (3.3⋅10
–5
) 1.21 (0.001) ç ÓÔ. 0.15 (1.2⋅10
–4
)
äÒÂÌÓÚËÏ 0.66 (4⋅10
–5
) 0.17 (1⋅10
–5
) 0.6 (3⋅10
–5
) ç ÓÔ. 0.08 (3.6⋅10
–6
)
ÇÒÂ„Ó 0.79 (1.3⋅10
–4
) 0.2 (4.3⋅10
–5
) 3.09 (0.0041) 0.05 (1⋅10
–4
) 0.4 (5.2⋅10
–4
)
퇷Îˈ‡ 11.4
ÑÓÎË Ï‡ÒÒ Y (%), ÒÍÓ̈ÂÌÚËÓ‚‡ÌÌ˚ ‚ ËÚÚË‚˚ı χÍÒËÏË̇·ı
ÍÓÌÚËÌÂÌڇθÌ˚ı ÔÓÓ‰ ÓÒ‡‰Ó˜ÌÓ„Ó ÒÎÓfl
éÒ‡‰Ó˜Ì˚ ÔÓÓ‰˚
ë‰ÌËÂ
èËϘ‡ÌËÂ. á‰ÂÒ¸ Ë ‚ ÔÓÒÎÂ‰Û˛˘Ëı Ú‡·Îˈ‡ı ‚ ÒÍӷ͇ı – ÒÓ‰ÂʇÌË ÏË̇ÎÓ‚, %.
Ç ˆÂÎÓÏ
ÇÛÎ͇ÌÓ„ÂÌÌ˚ ÔÓÓ‰˚
Ç ˆÂÎÓÏ
åË̇Î˚
äËÒÎ˚ÂèÂÒÍË Ë ÔÂÒ˜‡ÌËÍË
éÚËÚ < 0.01 (7⋅10
–8
) < 0.01 (1.8⋅10
–8
) 3.87 (0.003) 0.14 (1⋅10
–4
) 0.7 (4⋅10
–4
)
åÓ̇ˆËÚ 0.85 (1.3⋅10
–4
) 0.13 (3.3⋅10
–5
) 4.19 (0.001) ç ÓÔ. 0.68 (1⋅10
–4
)
ÇÒÂ„Ó 0.85 (1⋅10
–4
) 0.13 (3⋅10
–5
) 8.06 (0.004) 0.14 (1⋅10
–4
) 1.38 (5⋅10
–4
)
퇷Îˈ‡ 11.5
ÑÓÎË Ï‡ÒÒ La (%), ÒÍÓ̈ÂÌÚËÓ‚‡ÌÌ˚ ‚ ·ÌÚ‡ÌÓ‚˚ı χÍÒËÏË̇·ı
ÍÓÌÚËÌÂÌڇθÌ˚ı ÔÓÓ‰ ÓÒ‡‰Ó˜ÌÓ„Ó ÒÎÓfl
éÒ‡‰Ó˜Ì˚ ÔÓÓ‰˚
ë‰ÌËÂ
ɇÌÓ‰ËÓËÚ˚åË̇Î˚ ëËÂÌËÚ˚ɇÌËÚ˚
ó‚ÍËÌËÚ < 0.01 (1.5⋅10
–6
) ç ÓÔ. 0.17 (6⋅10
–4
) < 0.01 (3.2⋅10
–6
)
éÚËÚ 1.6 (0.008) 0.83 (0.003) 13.53 (0.023) 1.35(0.0058)
ì‡ÌËÌËÚ 0.02 (7.8⋅10
–5
) ç ÓÔ. ç ÓÔ. 0.02 (4.9⋅10
–5
)
åÓ̇ˆËÚ 2.49 (0.0043) 0.32 (4⋅10
–4
) 4.09 (0.0024) 1.89 (0.0028)
ꇷ‰ÓÙ‡Ì < 0.01 (4⋅10
–6
) ç ÓÔ. ç ÓÔ. < 0.01 (2.5⋅10
–6
)
ÑÂÎÓÂ̈ËÚ ç ÓÔ. ç ÓÔ. 0.06 (1.3⋅10
–5
) < 0.01 (5⋅10
–8
)
ù‚ÍÒÂÌËÚ 0.16 (8⋅10
–5
) ç ÓÔ. < 0.01 (8⋅10
–8
) 0.12 (5⋅10
–5
)
î„ÛÒÓÌËÚ 0.06 (1.5⋅10
–5
) 0.16 (3.2⋅10
–5
) 0.04 (3.8⋅10
–6
) 0.08 (1.8⋅10
–5
)
àÚÚˇÎËÚ 0.91 (2⋅10
–4
) ç ÓÔ. ç ÓÔ. 0.64 (1.2⋅10
–4
)
ÅÎÓÏÒڇ̉ËÌ 0.05 (8.7⋅10
–6
) ç ÓÔ. 5.14 (3.3⋅10
–4
) 0.04 (6.7⋅10
–6
)
ɇ‰ÓÎËÌËÚ 0.33 (5⋅10
–5
) ç ÓÔ. 0.06 (3⋅10
–6
) 0.23 (3⋅10
–5
)
äÒÂÌÓÚËÏ 1.93 (2⋅10
–4
) 0.04 (3⋅10
–6
) 0.08 (2.7⋅10
–6
) 1.46 (1.3⋅10
–4
)
ÇÒÂ„Ó 7.55 (0.013) 1.35 (0.0034) 23.17 (0.026) 5.83 (0.0089)
퇷Îˈ‡ 11.6
ÑÓÎË Ï‡ÒÒ Y (%), ÒÍÓ̈ÂÌÚËÓ‚‡ÌÌ˚ ‚ ËÚÚË‚˚ı χÍÒËÏË̇·ı
χ„χÚ˘ÂÒÍËı ÔÓÓ‰ „‡ÌËÚÌÓ-„ÌÂÈÒÓ‚Ó„Ó ÒÎÓfl
凄χÚ˘ÂÒÍËÂ
ÔÓÓ‰˚ ‚ ˆÂÎÓÏ
臇Ò·̈˚
234
ɇÌÓ‰ËÓËÚ˚åË̇Î˚ ëËÂÌËÚ˚ɇÌËÚ˚
àÚÚˇÎËÚ 0.01 (2⋅10
–4
) ç ÓÔ. ç ÓÔ. 0.01 (1.2⋅10
–4
)
î„ÛÒÓÌËÚ < 0.01 (1.5⋅10
–5
) 0.01 (3.2⋅10
–5
) < 0.01 (3.8⋅10
–6
) < 0.01 (1.8⋅10
–5
)
éÚËÚ 6.67 (0.008) 2.35 (0.003) 20.44 (0.023) 5.16 (0.0058)
ɇ‰ÓÎËÌËÚ 0.06 (5⋅10
–5
) ç ÓÔ. < 0.01 (3⋅10
–6
) 0.04 (3⋅10
–5
)
ó‚ÍËÌËÚ < 0.01 (1.5⋅10
–6
) ç ÓÔ. 1.2 (0.0006) 0.01 (3.2⋅10
–6
)
åÓ̇ˆËÚ 11.65 (0.0043) 1.02 (0.0004) 6.93 (0.0024) 8.09 (0.0028)
ŇÒÚÌÂÁËÚ 1.37 (0.00047) ç ÓÔ. ç ÓÔ. 0.9 (0.00029)
ÇÒÂ„Ó 19.76 (0.013) 3.38 (0.0034) 28.57 (0.026) 14.21 (0.0091)
퇷Îˈ‡ 11.7
ÑÓÎË Ï‡ÒÒ La (%), ÒÍÓ̈ÂÌÚËÓ‚‡ÌÌ˚ ‚ ·ÌÚ‡ÌÓ‚˚ı χÍÒËÏË̇·ı
χ„χÚ˘ÂÒÍËı ÔÓÓ‰ „‡ÌËÚÌÓ-„ÌÂÈÒÓ‚Ó„Ó ÒÎÓfl
凄χÚ˘ÂÒÍËÂ
ÔÓÓ‰˚ ‚ ˆÂÎÓÏ
Ç ˆÂÎÓÏ
éÚÓÏÂÚ‡ÏÓÙ˘ÂÒÍË ÔÓÓ‰˚
Ç ˆÂÎÓÏ
åË̇Î˚
ɇÌËÚÓ-„ÌÂÈÒ˚åÂÚ‡ÔÂÒ˜‡ÌËÍË
éÚËÚ 0.8 3.33 3.09 3.88 1.51 2.95
(0.0012) (0.008) (0.0071) (0.0066) (0.008) (0.0056)
ì‡ÌËÌËÚ ç ÓÔ. ç ÓÔ. ç ÓÔ. < 0.01 ç ÓÔ. < 0.01
(6⋅10
–7
)(5⋅10
–7
)
åÓ̇ˆËÚ 0.58 1.09 1.01 4.61 < 0.01 3.36
(3⋅10
–4
)(9⋅10
–4
)(8⋅10
–4
) (0.0027) (2⋅10
–6
) (0.0022)
äÒÂÌÓÚËÏ ç ÓÔ. ç ÓÔ. ç ÓÔ. 2.13 ç ÓÔ. 1.57
(7.5⋅10
–5
) (6.2⋅10
–5
)
ÇÒÂ„Ó 1.38 4.42 4.1 10.62 1.51 7.88
(0.0015) (0.0089) (0.0079) (0.0094) (0.008) (0.0079)
퇷Îˈ‡ 11.8
ÑÓÎË Ï‡ÒÒ Y (%), ÒÍÓ̈ÂÌÚËÓ‚‡ÌÌ˚ ‚ ËÚÚË‚˚ı χÍÒËÏË̇·ı
ÏÂÚ‡ÏÓÙ˘ÂÒÍËı ÔÓÓ‰ „‡ÌËÚÌÓ-„ÌÂÈÒÓ‚Ó„Ó ÒÎÓfl
臇ÏÂÚ‡ÏÓÙ˘ÂÒÍË ÔÓÓ‰˚
åÂÚ‡ËÓÎËÚ˚
臇Ò·̈˚ Ç ˆÂÎÓÏ
éÚÓÏÂÚ‡ÏÓÙ˘ÂÒÍË ÔÓÓ‰˚
Ç ˆÂÎÓÏ
åË̇Î˚
ɇÌËÚÓ-„ÌÂÈÒ˚åÂÚ‡ÔÂÒ˜‡ÌËÍË
éÚËÚ 2.18 10 9.16 8 16 7.47
(0.0012) (0.008) (0.0071) (0.0066) (0.008) (0.0056)
åÓ̇ˆËÚ 1.77 3.66 3.36 10.64 0.01 9.53
(0.0003) (0.0009) (0.0008) (0.0027) (2⋅10
–6
) (0.0022)
ŇÒÚÌÂÁËÚ ç ÓÔ. ç ÓÔ. ç ÓÔ. 5.09 ç ÓÔ. 4.67
(0.0012) (0.001)
ÇÒÂ„Ó 3.95 13.66 12.52 23.73 16.01 21.67
(0.0015) (0.0089) (0.0079) (0.0105) (0.008) (0.0088)
퇷Îˈ‡ 11.9
ÑÓÎË Ï‡ÒÒ La (%), ÒÍÓ̈ÂÌÚËÓ‚‡ÌÌ˚ ‚ ·ÌÚ‡ÌÓ‚˚ı χÍÒËÏË̇·ı
ÏÂÚ‡ÏÓÙ˘ÂÒÍËı ÔÓÓ‰ „‡ÌËÚÌÓ-„ÌÂÈÒÓ‚Ó„Ó ÒÎÓfl
臇ÏÂÚ‡ÏÓÙ˘ÂÒÍË ÔÓÓ‰˚
åÂÚ‡ËÓÎËÚ˚
Ú‡ı (Ú‡·Î. 11.6, 11.7), ‡ ÒÂ‰Ë ÏÂÚ‡ÏÓÙ˘ÂÒÍËı ÔÓÓ‰ – ‚ „‡ÌËÚÓ-„ÌÂÈÒ‡ı
(Ú‡·Î. 11.8, 11.9). Ç ‰ÓÔÓÎÌÂÌËÂ Í ‰‡ÌÌ˚Ï Ú‡·Î. 11.8 Ë 11.9 ÓÚÏÂÚËÏ, ˜ÚÓ ‚ ÏÂ-
Ú‡·‡ÁËÚ‡ı ÛÒÚ‡ÌÓ‚ÎÂÌ ÏÓ̇ˆËÚ (҉̠ÒÓ‰ÂʇÌË 4⋅10
–8
%), ÌÓ ÒÍÓ̈ÂÌÚ-
ËÓ‚‡ÌÌ˚ ‚ ÌÂÏ ‰ÓÎË Ï‡ÒÒ Y Ë La < 0.01%.
11.1.3. é·ÒÛʉÂÌË ÔÓÎÛ˜ÂÌÌ˚ı ‰‡ÌÌ˚ı
èË‚Ó‰ËÏ˚ Á‰ÂÒ¸ ‰‡ÌÌ˚Â Ó Ò‰ÌÂÏ ÒÓ‰ÂʇÌËË Sc, Y Ë La ‚ „ÓÌ˚ı ÔÓ-
Ó‰‡ı ÔÓ‰Ó·Ì ÔÓÎÛ˜ÂÌÌ˚ı ‰Û„ËÏË ‡‚ÚÓ‡ÏË, ÌÓ ÌÛʉ‡˛ÚÒfl ‚ ÛÚÓ˜ÌÂ-
ÌËË. ç‡Ë·ÓΠ‚ÂÓflÚÌÓ ÔÂÛÏÂ̸¯ÂÌË Ò‰ÌÂ„Ó ÒÓ‰ÂʇÌËfl Sc Ë Y ‚ ÒËÂ-
ÌËÚ‡ı, Y – „‡ÌËÚÓ-„ÌÂÈÒ‡ı, La – „‡ÌËÚ‡ı. çÓ ‰Îfl ÍÓÂ͈ËË ÓÚϘÂÌÌ˚ı
‰‡ÌÌ˚ı ÌÛÊÌÓ Ì ÚÓθÍÓ Ì‡ÍÓÔÎÂÌË ‡Ì‡ÎËÚ˘ÂÒÍËı ‰‡ÌÌ˚ı, ÌÓ Ë Òӂ¯ÂÌ-
ÒÚ‚Ó‚‡ÌË ÏÓ‰ÂÎË ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌڇθÌÓÈ ÍÓ˚. ÇÓÔÓÒ Ó ÓÎË
χÍÒËÏË̇ÎÓ‚ ‚ ͇˜ÂÒÚ‚Â ÌÓÒËÚÂÎÂÈ Sc ÔÓ͇ ÓÒÚ‡ÂÚÒfl ÓÚÍ˚Ú˚Ï. ç‡Ë·Ó-
Π‡ˆËÓ̇θÌ˚È ÔÛÚ¸ Â„Ó Â¯ÂÌËfl – ÓÔ‰ÂÎÂÌË Á‡ÍÓÌÓÏÂÌÓÒÚÂÈ ‚‡Ë-
‡ˆËÈ ÒÓ‰ÂʇÌËfl Ò͇̉Ë‚˚ı ‡ÁÌӂˉÌÓÒÚÂÈ ÓÚÌÓÒËÚÂθÌÓ ‡ÒÔÓÒÚ‡ÌÂÌ-
Ì˚ı ÏË̇ÎÓ‚, ÌÓ ‰Îfl ˝ÚÓ„Ó ÌÂÓ·ıÓ‰Ëχ ÔÓÒÚ‡Ìӂ͇ ÒÔˆˇθÌ˚ı ËÒÒΉÓ-
‚‡ÌËÈ. àÒıÓ‰Ì˚ ‰‡ÌÌ˚Â Ó ‚‡Ë‡ˆËflı ÒÓ‰ÂʇÌËÈ Ï‡ÍÒËÏË̇ÎÓ‚ Y Ë La ‚
„ÓÌ˚ı ÔÓÓ‰‡ı ÔÓÎÛ˜ÂÌ˚ ÏËÍÓÓ·Ó„‡ÚËÚÂθÌ˚ÏË ÏÂÚÓ‰‡ÏË. Å˚ÎË Û˜ÚÂÌ˚
Î˯¸ ˜‡ÒÚˈ˚ ÍÛÔÌÓÒÚ¸˛ 50–250 ËÎË > 30–50 ÏÍÏ. í‡ÍËÏ Ó·‡ÁÓÏ, ÔÓÎÛ-
˜ÂÌÌ˚ ‰‡ÌÌ˚ ÒÓÓÚ‚ÂÚÒÚ‚Û˛Ú Ì ËÒÚËÌÌ˚Ï, ‡ ÏËÌËχθÌÓ ‚ÓÁÏÓÊÌ˚Ï Á̇-
˜ÂÌËflÏ ÒÓ‰ÂʇÌËfl χÍÒËÏË̇ÎÓ‚ Y Ë La ‚ „ÓÌ˚ı ÓÚÒÛÚÒÚÛ˛Ú.
ÇÓÁÏÓÊÌÓÒÚË ÒÓÔÓÒÚ‡‚ÎÂÌËfl ÔÓÎÛ˜ÂÌÌ˚ı ‰‡ÌÌ˚ı Ò ÂÁÛθڇڇÏË ÓÔÂ-
‰ÂÎÂÌËÈ ÏË̇θÌ˚ı ·‡Î‡ÌÒÓ‚ Sc, Y Ë La ‚ ÍÓÌÍÂÚÌ˚ı ‡ÁÌÓÒÚflı „ÓÌ˚ı
ÔÓÓ‰ χÎ˚. èÓ Ï‡„χÚ˘ÂÒÍËÏ Ë ÏÂÚ‡ÏÓÙ˘ÂÒÍËÏ ÔÓÓ‰‡Ï ‰‡ÌÌ˚ ˝ÔË-
ÁӉ˘ÂÒÍËÂ, ‡ ÔÓ ÓÒ‡‰Ó˜Ì˚Ï ÔÓÓ‰‡Ï ÓÚÒÛÚÒÚ‚Û˛Ú.
ë͇̉ËÈ. åË̇θÌ˚ ·‡Î‡ÌÒ˚ ÓÔ‰ÂÎÂÌ˚ ËÒÍβ˜ËÚÂθÌÓ ‚ ÔÓ·‡ı
„ÓÌ˚ı ÔÓÓ‰ Ò ÒÓ‰ÂʇÌËÂÏ Sc, ·ÎËÁÍËÏ Í Í·ÍÓ‚ÓÏÛ (É˄Ӹ‚, 1999).
ÇÓ ‚ÒÂı ÒÎÛ˜‡flı Sc ̇ıÓ‰ËÚÒfl ‚ ˜ÛÊËı ÏË̇·ı. Ç ¯Ó¯ÓÌËÚ‡ı, „‡ÌËÚ‡ı,
„‡ÌÓ‰ËÓËÚ‡ı, Ûθڇ·‡ÁËÚ‡ı ÏË̇·ÏË-ÍÓ̈ÂÌÚ‡ÚÓ‡ÏË fl‚Îfl˛ÚÒfl ‡Ï-
ÙË·ÓÎ˚ Ë Òβ‰˚. Ç ÏÂÚ‡ÒÓχÚËÚ‡ı ë‚ÂÚÎËÌÒÍÓ„Ó ÁÓÎÓÚÓÛ‰ÌÓ„Ó ÏÂÒÚÓ-
ÓʉÂÌËfl Ë ÔÓ‰ÛÍÚ‡ı Ëı ‚˚‚ÂÚË‚‡ÌËfl ÏË̇·ÏË-ÍÓ̈ÂÌÚ‡ÚÓ‡ÏË Sc
fl‚Îfl˛ÚÒfl Ú‡ÍÊ ÚËÚ‡ÌËÚ, ÛÚËÎ, ˆËÍÓÌ, Ӊ̇ÍÓ ÒÓ‰ÂʇÌË Sc ‚ ˝ÚËı ÏËÌÂ-
‡Î‡ı Ì‚˚ÒÓÍÓÂ. å‡ÍÒËÏË̇Î˚ Ì ӷ̇ÛÊÂÌ˚.
àÚÚËÈ. àÁ ‚ÛÎ͇ÌÓ„ÂÌÌ˚ı ÔÓÓ‰ ËÁÛ˜ÂÌ Î˯¸ ˛ÒÍËÈ „ˇÎÓËÓÎËÚ ËÁ
ᇷ‡È͇θfl (ÉÂÓıËÏËfl ÏÂÁÓÁÓÈÒÍËı…, 1984), „‰Â ÒÓ‰ÂʇÌË Y 0.008%. å‡Í-
ÒËÏË̇Î˚ Ì ӷ̇ÛÊÂÌ˚. Ñ‚‡ ·‡Î‡ÌÒ‡ Y ‚ „‡ÌËÚ‡ı ÓÔ‰ÂÎË· Ç.ç. 臂-
ÎÓ‚‡ (ëÓÎÓ‰Ó‚ Ë ‰., 1987). ëÓ‰ÂʇÌË Y ÔÓ‚˚¯ÂÌÌÓÂ: 0.0078 Ë 0.0096%.
å‡ÍÒËÏË̇Î˚ ˆËÚÓÎËÚ, ÚÓËÚ Ë Fe-ÚÓËÚ, ‚ Ó‰ÌÓÈ ËÁ ÔÓ· ¢ ÍÓÎÛÏ·ËÚ
Ë ÔËÓıÎÓ. Ç Ï‡ÍÒËÏË̇·ı ÒÍÓ̈ÂÌÚËÓ‚‡ÌÓ 48 Ë 41% χÒÒ Y. à.ç. ÅÛ-
¯ÎflÍÓ‚˚Ï (ÅÛ¯ÎflÍÓ‚, ëÓ·Ó΂, 1976) ËÁÛ˜ÂÌ˚ „‡ÌÓ‰ËÓËÚ Ë Í‚‡ˆÂ‚˚È
‰ËÓËÚ ÇÂıËÒÂÚÒÍÓ„Ó Ï‡ÒÒË‚‡ ̇ ì‡ÎÂ. ëÓ‰ÂʇÌË Y ÔÓÌËÊÂÌÌÓ 0.00091
Ë 0.002%. å‡ÍÒËÏË̇Î˚ Ì ÛÒÚ‡ÌÓ‚ÎÂÌ˚. Ç.à. äÓ‚‡ÎÂÌÍÓ Ò ÍÓÎ΄‡ÏË
(1970) ËÁÛ˜ÂÌ˚ ‰‚ ÔÓ·˚ ˘ÂÎÓ˜Ì˚ı Ô„χÚËÚÓ‚ ËÁ ëË·ËË. ëÓ‰ÂʇÌË Y
ÔÓ‚˚¯ÂÌÌÓÂ: 0.014 Ë 0.032%. å‡ÍÒËÏËÌ‡ΠˆËÍÓÌ. Ç ÌÂÏ ÒÍÓ̈ÂÌÚËÓ‚‡-
ÌÓ 79 Ë 50% χÒÒ Y. Ç.Ä. å‡Í˚„ËÌÓÈ Ò ÒÓ‡‚ÚÓ‡ÏË (1980) ËÁÛ˜ÂÌ˚ 4 ÔÓ·˚
Ô‡‡ÏÂÚ‡ÏÓÙ˘ÂÒÍËı ÔÓÓ‰ ï‡Ï‡‰‡·‡ÌÒÍÓ„Ó Ï‡ÒÒË‚‡ ‚ ëË·ËË. ëÓ‰Âʇ-
235
ÌË Y ÓÍÓÎÓÍ·ÍÓ‚ÓÂ: 0.0016–0.0035%. å‡ÍÒËÏË̇Î˚ Ì ÛÒÚ‡ÌÓ‚ÎÂÌ˚.
àÁÛ˜ÂÌ˚: Í‚‡ˆÂ‚Ó-‰ËÓÔÒˉӂ˚È Ô·„ËÓÒ·̈ ËÁ ÄΉ‡ÌÒÍÓÈ ÙÎÓ„ÓÔËÚÓ-
ÌÓÒÌÓÈ ÔÓ‚Ë̈ËË (èÂÚÓ‚‡, ëÏËÌÓ‚‡, 1982) Ë Ï˄χÚËÚ ËÁ ë‚ÂÌÓ„Ó èË-
·‡È͇θfl (å‡Í˚„Ë̇, ëÏËÌÓ‚‡, 1984). ëÓ‰ÂʇÌË Y ‚ Ô‚ÓÏ Ô‡ÍÚ˘ÂÒ-
ÍË Í·ÍÓ‚Ó (0.0023%), ‚Ó ‚ÚÓÓÏ – ÔÓ‚˚¯ÂÌÌÓ (0.0077%). Ç Ô‚ÓÏ Ï‡Í-
ÒËÏË̇Î˚ Ì ÛÒÚ‡ÌÓ‚ÎÂÌ˚, ‚Ó ‚ÚÓÓÏ – χÍÒËÏËÌ‡Π‡Ô‡ÚËÚ, ‚ ÍÓÚÓÓÏ
ÒÍÓ̈ÂÌÚËÓ‚‡ÌÓ 45% χÒÒ Y. àÁÛ˜ÂÌ Í‚‡ˆÂ‚Ó-Òβ‰ËÒÚ˚È ÏÂÚ‡ÒÓχÚËÚ
ë‚ÂÚÎËÌÒÍÓ„Ó ÁÓÎÓÚÓÛ‰ÌÓ„Ó ÏÂÒÚÓÓʉÂÌËfl Ò ÒÓ‰ÂʇÌËÂÏ Y 0.0025% (äÓ-
Ó‚Ó-χÌÚËÈÌÓÂ…, 1989). å‡ÍÒËÏË̇Î˚ Ì ӷ̇ÛÊÂÌ˚.
ã‡ÌÚ‡Ì. àÁ ‚ÛÎ͇ÌÓ„ÂÌÌ˚ı ÔÓÓ‰ ËÁÛ˜ÂÌ˚ Î˯¸ „ˇÎÓËÓÎËÚ Ë Î‡ÚËÚ ËÁ
ᇷ‡È͇θfl (ÉÂÓıËÏËfl ÏÂÁÓÁÓÈÒÍËı…, 1984). á‰ÂÒ¸ ÒÓ‰ÂʇÌË La ÒÓÓÚ‚ÂÚ-
ÒÚ‚ÂÌÌÓ 0.002 Ë 0.0041%. å‡ÍÒËÏË̇Î˚ Ì ӷ̇ÛÊÂÌ˚. ÇÓ ‚Íβ˜ÂÌËflı
ÔÂˉÓÚËÚÓ‚ ËÁ ‚ÛÎ͇Ì˘ÂÒÍËı ¯Î‡ÍÓ‚ á‡Ô‡‰ÌÓÈ ÉÂχÌËË, ÒÓ‰Âʇ˘Ëı
1.6
.
10
–4
% La, Â„Ó Ï‡ÍÒËÏË̇Î˚ Ì ÛÒÚ‡ÌÓ‚ÎÂÌ˚ (Stosch, Seck, 1980). ç ӷ-
̇ÛÊÂÌ˚ ÓÌË Ë ‚ Ô·„ËÓÒ·̈‡ı ËÁ ÄΉ‡ÌÒÍÓÈ ÙÎÓ„ÓÔËÚÓÌÓÒÌÓÈ ÔÓ‚ËÌ-
ˆËË, ÒÓ‰Âʇ˘Ëı 0.0041% La (èÂÚÓ‚‡, ëÏËÌÓ‚‡, 1982). Ç.Ä. å‡Í˚„Ë̇ Ë
Ç.Ç. ëÏËÌÓ‚‡ (1984) ËÁÛ˜ËÎË ‰‚ ÔÓ·˚ Ô·„ËÓ„ÌÂÈÒÓ‚ Ë Ó‰ÌÛ – Ï˄χÚËÚ‡
ËÁ ë‚ÂÌÓ„Ó èË·‡È͇θfl Ò ÒÓ‰ÂʇÌËÂÏ La 0.006–0.0093%. å‡ÍÒËÏËÌÂ-
‡Î ÓÚËÚ. Ç ÌÂÏ ÒÍÓ̈ÂÌÚËÓ‚‡ÌÓ 56–61% χÒÒ La.
Ç ˆÂÎÓÏ, Ә‚ˉÌÓ, ˜ÚÓ ÌÂÏÌÓ„Ó˜ËÒÎÂÌÌ˚ ÏË̇θÌ˚ ·‡Î‡ÌÒ˚ ÓÚ‡-
ʇ˛Ú ‚ ÓÒÌÓ‚ÌÓÏ Ë̉˂ˉۇθÌ˚ ÓÒÓ·ÂÌÌÓÒÚË ËÁÛ˜ÂÌÌ˚ı „ÓÌ˚ı ÔÓÓ‰.
éÌË Ò‚Ë‰ÂÚÂθÒÚ‚Û˛Ú Ó ÒÎÓÊÌ˚ı Á‡ÍÓÌÓÏÂÌÓÒÚflı ‚‡Ë‡ˆËÈ ÓÎË Ï‡ÍÒËÏË-
̇ÎÓ‚ Í‡Í ÌÓÒËÚÂÎÂÈ Y Ë La.
11.1.4. Ç˚‚Ó‰˚
Ç ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌڇθÌÓÈ ÍÓ˚ ҉̠ÒÓ‰ÂʇÌËÂ, %: Sc –
0.0016, Y – 0.0026 Ë La – 0.0032. É·‚Ì˚ ÍÓ̈ÂÌÚ‡ÚÓ˚ Sc ÓÒÌÓ‚Ì˚ χ„-
χÚ˘ÂÒÍË ÔÓÓ‰˚ Ë ÔÓ‰ÛÍÚ˚ Ëı ÏÂÚ‡ÏÓÙËÁχ. É·‚Ì˚ ÍÓ̈ÂÌÚ‡ÚÓ˚
Y Ë La „‡ÌËÚ˚ Ë „‡ÌÓ‰ËÓËÚ˚. É·‚Ì˚ ÌÓÒËÚÂÎË Sc, Y Ë La – ÏÂÚ‡ÏÓÙË-
˜ÂÒÍË ÔÓÓ‰˚. Ç ÌËı ̇ıÓ‰ËÚÒfl ·Óθ¯Â ÔÓÎÓ‚ËÌ˚ χÒÒ ‰‡ÌÌ˚ı ˝ÎÂÏÂÌÚÓ‚:
Sc 71.98, Y 51.7 Ë La 59.5%.
êÓθ χÍÒËÏË̇ÎÓ‚ Í‡Í ÌÓÒËÚÂÎÂÈ Sc ÓÔ‰ÂÎËÚ¸ Ì ۉ‡ÎÓÒ¸. Ç Ï‡Í-
ÒËÏË̇·ı ÒÍÓ̈ÂÌÚËÓ‚‡ÌÓ 4.25% χÒÒ Y, ‚ ÚÓÏ ˜ËÒΠ‚ ÓÚËÚ – 1.85,
ÏÓ̇ˆËÚ – 1.45, ÍÒÂÌÓÚËÏ – 0.69, ËÚÚˇÎËÚ – 0.14, „‡‰ÓÎËÌËÚ – 0.06,
˝‚ÍÒÂÌËÚ – 0.03, Ù„ÛÒÓÌËÚ – 0.02, ·ÎÓÏÒڇ̉ËÌ – 0.01%. Ç Ï‡ÍÒËÏË-
̇·ı ÒÍÓ̈ÂÌÚËÓ‚‡ÌÓ 12.69% χÒÒ La, ‚ ÚÓÏ ˜ËÒΠ‚ ÓÚËÚ – 6, ÏÓ̇-
ˆËÚ – 5.28, ·‡ÒÚÌÂÁËÚ – 1.4, „‡‰ÓÎËÌËÚ – 0.01%. ùÚË ˆËÙ˚ ÏËÌËχθÌÓ
‚ÓÁÏÓÊÌ˚Â.
11.2. ñÖêàâ, èêÄáEéÑàå, çÖéÑàå, ëÄåÄêàâ
11.2.1. ë‰Ì ÒÓ‰ÂʇÌËÂ Ë ‡ÒÔ‰ÂÎÂÌË χÒÒ Ce, Pr, Nd Ë Sm
‚ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌڇθÌÓÈ ÍÓ˚
èË‚Ó‰ËÏ˚ Á‰ÂÒ¸ (Ú‡·Î. 11.10) ‰‡ÌÌ˚Â Ó Ò‰ÌËı ÒÓ‰ÂʇÌËflı Ce, Pr, Nd,
Sm ‚ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌڇθÌÓÈ ÍÓ˚ Ë ‚ Ò·„‡˛˘Ëı  „ÓÌ˚ı ÔÓÓ‰‡ı
ÒÓÓÚ‚ÂÚÒÚ‚Û˛Ú ‰‡ÌÌ˚Ï, ÓÔÛ·ÎËÍÓ‚‡ÌÌ˚Ï ‡Ì¸¯Â (É˄Ӹ‚, 2003·):
236
237
Sm
Pr
ÑÓÎË Ï‡ÒÒ, %
Nd
Pr
Nd Sm Ce
퇷Îˈ‡ 11.10
ê‡ÒÔ‰ÂÎÂÌË Ce, Pr, Nd Ë Sm ‚ ‡ÒÒӈˇˆËË „ÓÌ˚ı ÔÓÓ‰ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌڇθÌÓÈ ÍÓ˚
ÉÓÌ˚Â ÔÓÓ‰˚
å‡ÒÒ‡
ÔÓÓ‰, %
ë‰Ì ÒÓ‰ÂʇÌËÂ, n⋅10
–4
%
Ce
èÂÒÍË Ë ÔÂÒ˜‡ÌËÍË 5.11 39 4.3 16 3.8 3.2 2.5 2.8 3.4
ÉÎËÌ˚ Ë „ÎËÌËÒÚ˚ Ò·̈˚ 10.4 75 10 36 8 12.4 12 12.8 14.6
䇷Ó̇ÚÌ˚ ÔÓÓ‰˚ 3.85 12 2.6 6.6 1.9 0.7 1.2 0.9 1.3
äÂÏÌËÒÚ˚ ÔÓÓ‰˚ 0.33 15 ç ÓÔ. 7 ç ÓÔ. 0.1 ç ÓÔ. 0.1 ç ÓÔ.
ù‚‡ÔÓËÚ˚ 0.26 ç ÓÔ. ç ÓÔ. ç ÓÔ. ç ÓÔ. ç ÓÔ. ç ÓÔ. ç ÓÔ. ç ÓÔ.
äËÒÎ˚ ‚ÛÎ͇ÌËÚ˚ 0.44 58 10 27 5.2 0.4 0.5 0.4 0.4
ë‰ÌË ‚ÛÎ͇ÌËÚ˚ 1.13 50 4 20 4.3 0.9 0.5 0.8 0.9
éÒÌÓ‚Ì˚ ‚ÛÎ͇ÌËÚ˚ 2.11 43 4.7 21 5.1 1.4 1.1 1.5 1.9
ɇÌËÚ˚ 8.21 72 7.4 31 7.5 9.4 7 8.7 10.8
ɇÌÓ‰ËÓËÚ˚ 3.38 75 6.4 23 8.2 4 2.5 2.7 4.9
ŇÁËÚ˚ 1.5 48 5 22 5.3 1.1 0.9 1.1 1.4
ëËÂÌËÚ˚ 0.05 95 10 42 10 0.1 0.1 0.1 0.1
ìθڇ·‡ÁËÚ˚ 0.05 8.6 1.4 4.8 0.83 < 0.1 < 0.1 < 0.1 < 0.1
åÂÚ‡ÔÂÒ˜‡ÌËÍË 2.92 37 5.2 24 3.4 1.7 1.7 2.4 1.7
臇„ÌÂÈÒ˚ Ë Ô‡‡Ò·̈˚ 30.56 76 11 36 6.4 36.8 38.6 37.7 34.4
åÂڇ͇·Ó̇ÚÌ˚ ÔÓÓ‰˚ 1.13 51 4.6 23 2.4 0.9 0.6 0.9 0.5
ÜÂÎÂÁËÒÚ˚ ÔÓÓ‰˚ 0.38 ç ÓÔ. ç ÓÔ. ç ÓÔ. ç ÓÔ. ç ÓÔ. ç ÓÔ. ç ÓÔ. ç ÓÔ.
ɇÌËÚÓ-„ÌÂÈÒ˚ 23.21 65 11 32 5.1 23.9 29.4 25.4 20.8
åÂÚ‡ËÓÎËÚ˚ 0.66 43 3.1 11 2.7 0.5 0.2 0.2 0.3
åÂÚ‡‡Ì‰ÂÁËÚ˚ 1.03 69 ç ÓÔ. ç ÓÔ. 2.6 1.1 ç ÓÔ. ç ÓÔ. 0.5
åÂÚ‡·‡ÁËÚ˚ 3.29 26 3.2 13 3.7 1.4 1.2 1.5 2.1
ÇÂıÌflfl ˜‡ÒÚ¸ ÍÓÌÚËÌÂÌڇθÌÓÈ ÍÓ˚ 100 63.07 8.7 29.19 5.69 100 100 100 100
éÒ‡‰Ó˜Ì˚ ÔÓÓ‰˚ 19.95 51.65 6.82 24.26 5.51 16.4 15.7 16.6 19.3
ÇÛÎ͇ÌËÚ˚ ÓÒ‡‰Ó˜ÌÓ„Ó ÒÎÓfl 3.68 47 5.12 21.4 4.87 2.7 2.1 2.7 3.2
éÒ‡‰Ó˜Ì˚È ÒÎÓÈ ‚ ˆÂÎÓÏ 23.63 50.92 6.55 23.81 5.41 19.1 17.8 19.3 22.5
凄χÚËÚ˚ „‡ÌËÚÌÓ-„ÌÂÈÒÓ‚Ó„Ó ÒÎÓfl 13.19 69.9 6.86 27.87 7.41 14.6 10.5 12.6 17.2
臇ÏÂÚ‡ÏÓÙËÚ˚ 34.99 71.11 10.19 34.19 5.95 39.4 40.9 41 36.6
éÚÓÏÂÚ‡ÏÓÙËÚ˚ 28.19 60.07 9.5 28.13 4.79 26.9 30.8 27.1 23.7
ɇÌËÚÌÓ-„ÌÂÈÒÓ‚˚È ÒÎÓÈ ‚ ˆÂÎÓÏ 76.37 66.83 9.36 30.86 5.77 80.9 82.2 80.7 77.5
Ce 0.0063 Ë Nd 0.0029% ̇ıÓ‰flÚÒfl ‚ ԉ·ı ‚Â΢ËÌ: Ce 0.00575–0.00664, Nd
0.000256–0.00304%, ÓÔÛ·ÎËÍÓ‚‡ÌÌ˚ı ‰Û„ËÏË ËÒÒΉӂ‡ÚÂÎflÏË (Rudnick, Gao,
2004); Pr 0.00087 Ë Sm 0.000569% ÌÂÒÍÓθÍÓ ·Óθ¯Â ‚Â΢ËÌ, ÔÛ·ÎËÍÓ‚‡‚¯Ëı-
Òfl ‰Û„ËÏË ËÒÒΉӂ‡ÚÂÎflÏË: Pr 0.00063–0.00071 Ë Sm 0.000459–0.000509
(Rudnick, Gao, 2004). ê‡ÒÔ‰ÂÎÂÌË Ce, Pr , Nd Ë Sm ‚ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌ-
ڇθÌÓÈ ÍÓ˚ ÔÓ˜ÚË ÒÓÓÚ‚ÂÚÒÚ‚ÛÂÚ Ú·ӂ‡ÌËflÏ „ÂÓıËÏ˘ÂÒÍÓ„Ó ·‡Î‡ÌÒ‡.
ë‰Ì ÒÓ‰ÂʇÌË ‚Ó ‚ÒÂÈ ‡ÒÒӈˇˆËË ÓÒ‡‰Ó˜Ì˚ı ÔÓÓ‰ (Ce 0.0052, Pr
0.00068, Nd 0.0024 Ë Sm 0.00055%) ·ÎËÁÍÓ Í ÚÓÏÛ, ÍÓÚÓÓ ÏÓ„ÎÓ ·˚Ú¸ Û̇ÒÎÂ-
‰Ó‚‡ÌÓ ÔË ‚˚‚ÂÚË‚‡ÌËË „‡ÌËÚÌÓ-„ÌÂÈÒÓ‚Ó„Ó ÒÎÓfl ÒÓ‚ÂÏÂÌÌÓ„Ó ÒÓÒÚ‡‚‡ (Ce
0.0055, Pr 0.00077, Nd 0.0025, Sm 0.00047% (‡Ò˜ÂÚ ËÁӇβÏËÌË‚˚Ï ÏÂÚÓ‰ÓÏ).
É·‚Ì˚ ÍÓ̈ÂÌÚ‡ÚÓ˚ ‚ÒÂı ˜ÂÚ˚Âı ˝ÎÂÏÂÌÚÓ‚ – ÒËÂÌËÚ˚, ÓÒ‡‰Ó˜Ì˚Â
ÔÓÓ‰˚ Ë ÔÓ‰ÛÍÚ˚ Ëı ÏÂÚ‡ÏÓÙËÁχ. ÅÓθ¯Â ÔÓÎÓ‚ËÌ˚ χÒÒ ‚ÒÂı ˜ÂÚ˚Âı
˝ÎÂÏÂÌÚÓ‚ ÒÓÒ‰ÓÚÓ˜ÂÌ˚ ‚ ÓÒ‡‰Ó˜Ì˚ı Ë Ô‡‡ÏÂÚ‡ÏÓÙ˘ÂÒÍËı ÔÓÓ‰‡ı:
Ce 55.8, Pr 56.6, Nd 57.6 Ë Sm 55.9%.
11.2.2. ÑÓÎË Ï‡ÒÒ Ce Ë Pr, ÒÍÓ̈ÂÌÚËÓ‚‡ÌÌ˚ ‚ χÍÒËÏË̇·ı
Ce Ë Pr χÍÒËχθÌÓ ÍÓ̈ÂÌÚËÛ˛ÚÒfl ‚ ˆÂË‚˚ı ÏË̇·ı, ÌÓ ‚˚ÒÓ-
ÍÓ Ëı ÒÓ‰ÂʇÌË ı‡‡ÍÚÂÌÓ Ú‡ÍÊ ‰Îfl ËÚÚË‚˚ı, ÌËÓ·Ë‚˚ı, Ú‡ÌÚ‡ÎÓ-
‚˚ı, ˆËÍÓÌË‚˚ı, ÚËÚ‡ÌÓ‚˚ı, Û‡ÌÓ‚˚ı, ÚÓË‚˚ı, ÌÂÍÓÚÓ˚ı ͇θˆËÂ-
‚˚ı ÏË̇ÎÓ‚. èÓ‚˚¯ÂÌÌÓ ÒÓ‰ÂʇÌË Ce Ë Pr ˜‡ÒÚÓ ÓÚϘ‡ÂÚÒfl ‚ „ˉÓ-
ÍÒËÎÒÓ‰Âʇ˘Ëı ˆÂÔӘ˜Ì˚ı Ë ÎËÒÚÓ‚˚ı ÒËÎË͇ڇı Fe Ë Mg. ɇÌ˘Ì˚Â
‰Îfl ˆÂË‚˚ı Ë Ô‡ÁÂÓ‰ËÏÓ‚˚ı χÍÒËÏË̇ÎÓ‚ ÒÓ‰ÂʇÌËfl ÒÓÓÚ‚ÂÚÒÚ‚ÂÌ-
ÌÓ: Ce 0.5 Ë Pr 0.06% (É˄Ӹ‚, 1999). Ç ‰‡ÌÌÓÈ ‡·ÓÚ ۘÚÂÌ˚ ÚÓθÍÓ ÚÂ
χÍÒËÏË̇Î˚, „‰Â ҉̠ÒÓ‰ÂʇÌË Ce Ë Pr ·Óθ¯Â ÓÚϘÂÌÌÓ„Ó. ÑÎfl
ÓÔ‰ÂÎÂÌËfl Ëı ÓÎË ËÒÔÓθÁÓ‚‡Ì˚ ÓÔÛ·ÎËÍÓ‚‡ÌÌ˚ ÂÁÛθڇÚ˚ ÍÓ΢ÂÒÚ-
‚ÂÌÌ˚ı ÏË̇Îӄ˘ÂÒÍËı ‡Ì‡ÎËÁÓ‚ „ÓÌ˚ı ÔÓÓ‰. è‚ÓËÒÚÓ˜ÌËÍË Ï‡ÚÂ-
ˇÎÓ‚ Ô˂‰ÂÌ˚ ‚ Ô‰¯ÂÒÚ‚Û˛˘Ëı ‡Á‰Â·ı, ‚ ˜‡ÒÚÌÓÒÚË ‚ ‡Á‰ÂΠ6.2.2,
‡ Ú‡ÍÊ 12.2.2.
ëӄ·ÒÌÓ ÔÓÎÛ˜ÂÌÌ˚Ï ‰‡ÌÌ˚Ï, Óθ χÍÒËÏË̇ÎÓ‚ Í‡Í ÌÓÒËÚÂÎÂÈ Ce Ë
Pr ÒÛ˘ÂÒÚ‚ÂÌ̇ ‚ „‡ÌËÚÌÓ-„ÌÂÈÒÓ‚ÓÏ ÒÎÓÂ Ë ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌڇθÌÓÈ
ÍÓ˚ ‚ ˆÂÎÓÏ (Ú‡·Î. 11.11, 11.12). àÁ „ÓÌ˚ı ÔÓÓ‰ ÓÒ‡‰Ó˜ÌÓ„Ó ÒÎÓfl ËÁÛ˜ÂÌ˚
ÚÓθÍÓ ÔÂÒÍË, ÍËÒÎ˚Â Ë Ò‰ÌË ‚ÛÎ͇ÌËÚ˚. êÓθ χÍÒËÏË̇ÎÓ‚ ̇˷ÓÎÂÂ
Á̇˜ËÚÂθ̇ ‚ ÍËÒÎ˚ı ‚ÛÎ͇ÌËÚ‡ı (Ú‡·Î. 11.13, 11.14). Ç „‡ÌËÚÌÓ-„ÌÂÈÒÓ‚ÓÏ
ÒÎÓ Óθ χÍÒËÏË̇ÎÓ‚ χÍÒËχθ̇ ‚ ÒËÂÌËÚ‡ı Ë „‡ÌËÚ‡ı (Ú‡·Î. 11.15,
11.16), ‡ ÒÂ‰Ë ÏÂÚ‡ÏÓÙ˘ÂÒÍËı ÔÓÓ‰ ‚ „‡ÌËÚÓ-„ÌÂÈÒ‡ı Ë ÏÂÚ‡ËÓÎËÚ‡ı
(Ú‡·Î. 11.17, 11.18). Ç ‰ÓÔÓÎÌÂÌËÂ Í ‰‡ÌÌ˚Ï Ú‡·Î. 11.17, 11.18 ÓÚÏÂÚËÏ, ˜ÚÓ ‚
ÏÂÚ‡·‡ÁËÚ‡ı ÛÒÚ‡ÌÓ‚ÎÂÌ ÏÓ̇ˆËÚ (҉̠ÒÓ‰ÂʇÌË 4⋅10
–8
%), ÌÓ ÒÍÓ̈ÂÌ-
ÚËÓ‚‡ÌÌ˚ ‚ ÌÂÏ ‰ÓÎË Ï‡ÒÒ Ce Ë Pr < 0.01%.
ÇÓÁÏÓÊÌÓÒÚË ÒÓÔÓÒÚ‡‚ÎÂÌËfl ÔÓÎÛ˜ÂÌÌ˚ı ‰‡ÌÌ˚ı Ò ÂÁÛθڇڇÏË ËÁÛ˜Â-
ÌËfl ‡ÒÔ‰ÂÎÂÌËfl Ce Ë Pr ÔÓ ÏËÌÂ‡Î‡Ï „ÓÌ˚ı ÔÓÓ‰ ÏËÌËχθÌ˚Â. Ç
·Óθ¯ËÌÒÚ‚Â ÒÎÛ˜‡Â‚ ËÎË Ì‰ÓÒÚ‡ÚÓ˜ÌÓ ‰‡ÌÌ˚ı ‰Îfl ‡Ò˜ÂÚ‡ ÏË̇θÌ˚ı
·‡Î‡ÌÒÓ‚, ËÎË ‚ÂÎËÍË Ôӄ¯ÌÓÒÚË ÓÔ‰ÂÎÂÌËfl ÒÓ‰ÂʇÌËÈ Ce Ë Pr ‚ ÏËÌÂ-
‡Î‡ı. Ä‚ÚÓÓÏ Û˜ÚÂÌÓ ‚ÒÂ„Ó 9 ÏË̇θÌ˚ı ·‡Î‡ÌÒÓ‚ (Ce – 7 Ë Pr – 2), „‰Â
ÒÛÏÏ˚ ‰ÓÎÂÈ Ï‡ÒÒ Ce Ë Pr, ÒÍÓ̈ÂÌÚËÓ‚‡ÌÌ˚ı ‚ ÏË̇·ı, Ì ‚˚ıÓ‰flÚ Á‡
Ô‰ÂÎ˚ 90–110% ÓÚ Ï‡ÒÒ ˝ÚËı ˝ÎÂÏÂÌÚÓ‚, ÒÓÓÚ‚ÂÚÒÚ‚Û˛˘Ëı ÂÁÛθڇڇÏ
‡Ì‡ÎËÁÓ‚ ËÁÛ˜ÂÌÌ˚ı ÔÓ· „ÓÌ˚ı ÔÓÓ‰.
238
239
ÑÓÎË Ï‡ÒÒ
Ce, %
ÑÓÎË Ï‡ÒÒ
Ce, %
ëÓ‰ÂʇÌËÂ
ÏË̇ÎÓ‚, %
ÑÓÎË Ï‡ÒÒ
Ce, %
ëÓ‰ÂʇÌËÂ
ÏË̇ÎÓ‚, %
ÇÂıÌflfl ˜‡ÒÚ¸ ÍÓÌÚËÌÂÌ-
ڇθÌÓÈ ÍÓ˚
åË̇Î˚
ëÓ‰ÂʇÌËÂ
ÏË̇ÎÓ‚, %
ɇÌËÚÌÓ-„ÌÂÈÒÓ‚˚È ÒÎÓÈ
ì‡ÌËÌËÚ 0.8 9.3⋅10
–7
< 0.01 8.6⋅10
–6
< 0.01 6.6⋅10
–6
< 0.01
ÅÎÓÏÒڇ̉ËÌ 1.2 ç ÓÔ. ç ÓÔ. 1.2⋅10
–6
< 0.01 9⋅10
–7
< 0.01
èËÓıÎÓ 1.4 ç ÓÔ. ç ÓÔ. 1.3⋅10
–6
< 0.01 1⋅10
–6
< 0.01
àÚÚˇÎËÚ 1.8 ç ÓÔ. ç ÓÔ. 2.1⋅10
–5
0.01 1.6⋅10
–5
< 0.01
ù‚‰Ë‡ÎËÚ 2.7 ç ÓÔ. ç ÓÔ. 1.5⋅10
–5
0.01 1.1⋅10
–5
< 0.01
î„ÛÒÓÌËÚ 3.8 ç ÓÔ. ç ÓÔ. 3.1⋅10
–6
< 0.01 2.4⋅10
–6
< 0.01
ɇ‰ÓÎËÌËÚ 4.5 ç ÓÔ. ç ÓÔ. 5.2⋅10
–6
<0.01 4
.
10
–7
< 0.01
êËÌÍÓÎËÚ 6.7 ç ÓÔ. ç ÓÔ. 6.9⋅10
–9
< 0.01 5.3⋅10
–9
< 0.01
éÚËÚ 7.4 6⋅10
–5
0.09 0.0063 6.96 0.0048 5.64
ãÓÔ‡ËÚ 14 ç ÓÔ. ç ÓÔ. 1.3⋅10
–6
< 0.01 1⋅10
–6
< 0.01
ó‚ÍËÌËÚ 18.1 ç ÓÔ. ç ÓÔ. 5.5⋅10
–7
< 0.01 4.2⋅10
–7
< 0.01
åÓ̇ˆËÚ 24.5 4.6⋅10
–5
0.22 0.0016 5.85 0.0013 5.06
ŇÒÚÌÂÁËÚ 24.9 ç ÓÔ. ç ÓÔ. 4.2⋅10
–4
1.56 3.2⋅10
–4
1.26
ꇷ‰ÓÙ‡Ì 27.6 ç ÓÔ. ç ÓÔ. 4.3⋅10
–7
< 0.01 3.3⋅10
–7
< 0.01
ÇÂÈ̯ÂÌÍËÚ 28.1 ç ÓÔ. ç ÓÔ. 4.8⋅10
–8
< 0.01 3.7⋅10
–8
< 0.01
ÇÒÂ„Ó 1⋅10
–4
0.31 0.0084 14.39 0.0065 11.96
퇷Îˈ‡ 11.11
êÓθ χÍÒËÏË̇ÎÓ‚ Í‡Í ÌÓÒËÚÂÎÂÈ Ce ‚ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌڇθÌÓÈ ÍÓ˚
ëÓ‰ÂʇÌËÂ
Ce ‚ ÏËÌÂ-
‡Î‡ı, %
éÒ‡‰Ó˜Ì˚È ÒÎÓÈ
ÑÓÎË Ï‡ÒÒ
Pr, %
ÑÓÎË Ï‡ÒÒ
Pr, %
ëÓ‰ÂʇÌËÂ
ÏË̇ÎÓ‚, %
ÑÓÎË Ï‡ÒÒ
Pr, %
ëÓ‰ÂʇÌËÂ
ÏË̇ÎÓ‚, %
ÇÂıÌflfl ˜‡ÒÚ¸ ÍÓÌÚËÌÂÌ-
ڇθÌÓÈ ÍÓ˚
åË̇Î˚
ëÓ‰ÂʇÌËÂ
ÏË̇ÎÓ‚, %
ɇÌËÚÌÓ-„ÌÂÈÒÓ‚˚È ÒÎÓÈ
ÅÎÓÏÒڇ̉ËÌ 0.07 ç ÓÔ. ç ÓÔ. 1.2⋅10
–6
< 0.01 9⋅10
–7
< 0.01
àÚÚˇÎËÚ 0.23 ç ÓÔ. ç ÓÔ. 2.1⋅10
–5
0.01 1.6⋅10
–5
< 0.01
éÚËÚ 0.88 6⋅10
–5
0.08 0.0063 5.9 0.0048 4.86
î„ÛÒÓÌËÚ 1.1 ç ÓÔ. ç ÓÔ. 3.1⋅10
–6
< 0.01 2.4⋅10
–6
< 0.01
ó‚ÍËÌËÚ 1.68 ç ÓÔ. ç ÓÔ. 5.5⋅10
–7
< 0.01 4.2⋅10
–7
< 0.01
ɇ‰ÓÎËÌËÚ 2.3 ç ÓÔ. ç ÓÔ. 5.2⋅10
–6
0.01 4⋅10
–6
0.01
ŇÒÚÌÂÁËÚ 3.3 ç ÓÔ. ç ÓÔ. 4.2⋅10
–4
1.47 3.2⋅10
–4
1.21
åÓ̇ˆËÚ 4 4.6⋅10
–5
0.28 0.0016 6.81 0.0013 5.98
ÇÒÂ„Ó 1.06⋅10
–4
0.36 0.0084 14.2 0.0065 12.06
퇷Îˈ‡ 11.12
êÓθ χÍÒËÏË̇ÎÓ‚ Í‡Í ÌÓÒËÚÂÎÂÈ Pr ‚ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌڇθÌÓÈ ÍÓ˚
ëÓ‰ÂʇÌËÂ
Pr ‚ ÏËÌÂ-
‡Î‡ı, %
éÒ‡‰Ó˜Ì˚È ÒÎÓÈ
Ç ˆÂÎÓÏ
ÇÛÎ͇ÌÓ„ÂÌÌ˚ ÔÓÓ‰˚
Ç ˆÂÎÓÏ
åË̇Î˚
äËÒÎ˚ÂèÂÒÍË Ë ÔÂÒ˜‡ÌËÍË
ì‡ÌËÌËÚ ç ÓÔ. ç ÓÔ. 0.01 (5⋅10
–5
) ç ÓÔ. < 0.01 (6⋅10
–6
)
éÚËÚ < 0.01(7⋅10
–8
) < 0.01 (1.8⋅10
–8
) 3.83 (0.003) 0.15 (1⋅10
–4
) 0.63 (4⋅10
–4
)
åÓ̇ˆËÚ 0.82 (1.3⋅10
–4
) 0.16 (3.3⋅10
–5
) 4.22 (0.001) ç ÓÔ. 0.63 (1.2⋅10
–4
)
ÇÒÂ„Ó 0.82 (1.3⋅10
–4
) 0.16 (3.3⋅10
–5
) 8.06 (0.0041) 0.15 (1⋅10
–4
) 1.26 (5⋅10
–4
)
퇷Îˈ‡ 11.13
ÑÓÎË Ï‡ÒÒ Ce (%), ÒÍÓ̈ÂÌÚËÓ‚‡ÌÌ˚ ‚ χÍÒËÏË̇·ı „ÓÌ˚ı ÔÓÓ‰
ÓÒ‡‰Ó˜ÌÓ„Ó ÒÎÓfl ÍÓÌÚËÚÂÌڇθÌÓÈ ÍÓ˚
éÒ‡‰Ó˜Ì˚ ÔÓÓ‰˚
ë‰ÌËÂ
èËϘ‡ÌËÂ. á‰ÂÒ¸ Ë ‚ ÔÓÒÎÂ‰Û˛˘Ëı Ú‡·Îˈ‡ı ‚ ÒÍӷ͇ı – ÒÓ‰ÂʇÌË ÏË̇ÎÓ‚, %.
240
Ç ˆÂÎÓÏ
ÇÛÎ͇ÌÓ„ÂÌÌ˚ ÔÓÓ‰˚
Ç ˆÂÎÓÏ
åË̇Î˚
äËÒÎ˚ÂèÂÒÍË Ë ÔÂÒ˜‡ÌËÍË
ì‡ÌËÌËÚ ç ÓÔ. ç ÓÔ. < 0.01 (5⋅10
–5
) ç ÓÔ. < 0.01 (6⋅10
–6
)
éÚËÚ < 0.01 (7⋅10
–8
) < 0.01 (1.8⋅10
–8
) 2.64 (0.003) 0.22 (1⋅10
–4
) 0.69 (4⋅10
–4
)
åÓ̇ˆËÚ 1.21 (1.3⋅10
–4
) 0.19 (3.3⋅10
–5
) 4 (0.001) ç ÓÔ. 0.94 (1.2⋅10
–4
)
ÇÒÂ„Ó 1.21 (1.3⋅10
–4
) 0.19 (3.3⋅10
–5
) 6.64 (0.004) 0.22 (1⋅10
–4
) 1.63 (1.6⋅10
–4
)
퇷Îˈ‡ 11.14
ÑÓÎË Ï‡ÒÒ Pr (%), ÒÍÓ̈ÂÌÚËÓ‚‡ÌÌ˚ ‚ χÍÒËÏË̇·ı „ÓÌ˚ı ÔÓÓ‰
ÓÒ‡‰Ó˜ÌÓ„Ó ÒÎÓfl ÍÓÌÚËÚÂÌڇθÌÓÈ ÍÓ˚
éÒ‡‰Ó˜Ì˚ ÔÓÓ‰˚
ë‰ÌËÂ
ɇÌÓ‰ËÓËÚ˚
åË̇Î˚
ëËÂÌËÚ˚ɇÌËÚ˚
ì‡ÌËÌËÚ 0.01 (7.8⋅10
–5
) ç ÓÔ. ç ÓÔ. 0.01 (4.9⋅10
–5
)
ÅÎÓÏÒڇ̉ËÌ < 0.01 (8.7⋅10
–6
) ç ÓÔ. 0.04 (3.3⋅10
–4
) < 0.01 (6.7⋅10
–6
)
èËÓıÎÓ < 0.01 (5⋅10
–6
) < 0.01 (2⋅10
–6
) 0.01 (1⋅10
–4
) < 0.01 (4⋅10
–6
)
àÚÚˇÎËÚ 0.05 (2⋅10
–4
) ç ÓÔ. ç ÓÔ. 0.03(1.2⋅10
–4
)
ù‚‰Ë‡ÎËÚ ç ÓÔ. ç ÓÔ. 6.54 (0.023) 0.03 (8.7⋅10
–5
)
î„ÛÒÓÌËÚ 0.01 (1.5⋅10
–5
) 0.02 (3.2⋅10
–5
) < 0.01 (3.8⋅10
–6
) 0.01 (1.8⋅10
–5
)
ɇ‰ÓÎËÌËÚ 0.03 (5⋅10
–5
) ç ÓÔ. < 0.01 (3⋅10
–6
) 0.02 (3⋅10
–5
)
êËÌÍÓÎËÚ < 0.01 (7⋅10
–8
) ç ÓÔ. ç ÓÔ. < 0.01 (4⋅10
–8
)
éÚËÚ 8.22 (0.008) 2.96 (0.003) 17.92 (0.023) 6.13 (0.0058)
ãÓÔ‡ËÚ < 0.01 (1.8⋅10
–6
) < 0.01 (6⋅10
–7
) 2.51 (0.0017) 0.02(7.7⋅10
–6
)
ó‚ÍËÌËÚ < 0.01 (1.5⋅10
–6
) ç ÓÔ. 1.14 (6⋅10
–4
) 0.01 (3.2⋅10
–6
)
åÓ̇ˆËÚ 14.63 (0.0043) 1.31 (4⋅10
–4
) 6.19 (0.0024) 9.8 (0.0028)
ŇÒÚÌÂÁËÚ 1.63 (4.7⋅10
–4
) ç ÓÔ. ç ÓÔ. 1.03 (2.9⋅10
–4
)
ꇷ‰ÓÙ‡Ì 0.02 (4⋅10
–6
) ç ÓÔ. ç ÓÔ. 0.01 (2.5⋅10
–6
)
ÇÂÈ̯ÂÌÍËÚ < 0.01 (4.5⋅10
–7
) ç ÓÔ. ç ÓÔ. < 0.01 (2.8⋅10
–7
)
ÇÒÂ„Ó 24.6 (0.0131) 4.29 (0.0034) 34.35 (0.052) 17.1 (0.009)
퇷Îˈ‡ 11.15
ÑÓÎË Ï‡ÒÒ Ce (%), ÒÍÓ̈ÂÌÚËÓ‚‡ÌÌ˚ ‚ χÍÒËÏË̇·ı
χ„χÚ˘ÂÒÍËı ÔÓÓ‰ „‡ÌËÚÌÓ-„ÌÂÈÒÓ‚Ó„Ó ÒÎÓfl
凄χÚ˘ÂÒÍËÂ
ÔÓÓ‰˚ ‚ ˆÂÎÓÏ
ɇÌÓ‰ËÓËÚ˚
åË̇Î˚
ëËÂÌËÚ˚ɇÌËÚ˚
ÅÎÓÏÒڇ̉ËÌ < 0.01 (8.7⋅10
–6
) ç ÓÔ. 0.02 (3.3⋅10
–4
) < 0.01 (6.7⋅10
–6
)
àÚÚˇÎËÚ 0.06 (2⋅10
–4
) ç ÓÔ. ç ÓÔ. 0.04 (1.2⋅10
–4
)
éÚËÚ 9.51 (0.008) 4.13 (0.003) 20.2 (0.023) 7.4 (0.0058)
î„ÛÒÓÌËÚ 0.02 (1.5⋅10
–5
) 0.06 (3.2⋅10
–5
) < 0.01 (3.8⋅10
–6
) 0.03 (1.8⋅10
–5
)
ó‚ÍËÌËÚ < 0.01 (1.5⋅10
–6
) ç ÓÔ. 1.01 (6⋅10
–4
) 0.01 (3.2⋅10
–6
)
ɇ‰ÓÎËÌËÚ 0.16 (5⋅10
–5
) ç ÓÔ. 0.01 (3⋅10
–6
) 0.1 (3⋅10
–5
)
ŇÒÚÌÂÁËÚ 2.1 (4.7⋅10
–4
) ç ÓÔ. ç ÓÔ. 1.39 (2.9⋅10
–4
)
åÓ̇ˆËÚ 23.24 (0.0043) 2.5 (4⋅10
–4
) 9.6 (0.0024) 16.2 (0.0028)
ÇÒÂ„Ó 35.1 (0.013) 6.68 (0.0033) 30.9 (0.0263) 25.2 (0.009)
퇷Îˈ‡ 11.16
ÑÓÎË Ï‡ÒÒ Pr (%), ÒÍÓ̈ÂÌÚËÓ‚‡ÌÌ˚ ‚ χÍÒËÏË̇·ı
χ„χÚ˘ÂÒÍËı ÔÓÓ‰ „‡ÌËÚÌÓ-„ÌÂÈÒÓ‚Ó„Ó ÒÎÓfl
凄χÚ˘ÂÒÍËÂ
ÔÓÓ‰˚ ‚ ˆÂÎÓÏ