Baeckvall J.-E. (ed.) Modern Oxidation Methods
Подождите немного. Документ загружается.
– [Ru
3
O(OCOCF
2
CF
2
CF
3
)
6
(Et
2
O)
3
]
þ
267
– RuO
4
-promoted oxidation 241
– [Ru(OAc)
3
(CO
3
)] 254
– Ru
2
(OAc)
4
Cl 259
– Ru(OEP)(PPh
3
)
3
265
– Ru(OH)
2
/Al
2
O
3
264
– Ru(OH)
3
-Al
2
O
3
161
– Ru(OH)
x
/Al
2
O
3
267
– Ru(PMe
3
)
2
Cl
2
(eda)
(eda¼ethylenediamine) 251
– Ru(PPh
3
)
3
(CO)H
2
251
– Ru-polyoxometalate 340
– Ru-porphyrin complex 208, 245f., 259ff.
– Ru(pybox)(Pydic) complex 249
– Ru/quinone system 156
– Ru-substituted polyoxometalate 208
– Ru/TEMPO system 156
– Ru(TMP)Cl
2
-catalyzed oxidation 246
– Ru(TMP)(O)
2
259ff.
– Ru(TPFPP)(CO) (TPFPP¼tetrakis
(pentafluorophenyl)porphyrinato) 265ff.
– Ru(TPP)(O)
2
(TPP¼5,10,15,20-
tetraphenylporphyrinato) 264
– Shvo Ru-catalyst 154
– TEMPO 155
ruthenium glycolate 24
ruthenium oxide 74
ruthenium-exchanged hydrotalcite
(Ru-HT) 162
– Mg
6
Al
2
Ru
0.5
(OH)
16
CO
3
162
s
salen-based system 381ff.
sandwich-type polyoxometalate 318
scandium triflate (Sc(OTf)
3
) 286
seleninic acid 132ff.
selenium
– SeO
2
/TBHP system 204
sesquiterpene 433
sexipyridine ligand 73
Sharpless-Katsuki protocol
– asymmetric epoxidation (AE) 39
Shvo Ru-catalyst 154
silica gelsupported cinchona alkaloid [SGS-
(DHQD)
2
PHAL]-OsO
4
22
silica–PEG/PPG–H
5
PV
2
Mo
10
O
40
343
silicodecatungstate [c-SiW
10
O
34
(H
2
O)
2
]
4
44
sodium
– Na
2
CrO
4
/acetic anhydride 204
sodium percarbonate (SPC) 60
solid support 63
solid-liquid reaction 341
solvent 61
solvent-anchored supported liquid phase
catalysis 343
steroid monooxygenase (SMO) 299, 360
stilbene 391
trans-stilbene 24
stoichiometric reaction 278, 301
streptavidin
– vanadyl-loaded 297
styrene 25, 393
– epoxidation 93
– oxidation 388
sulfide 409ff.
– aerobic oxidation 294
– oxidation to sulfone 280
– oxidation to sulfoxide 277ff., 410
sulfone 280, 409
2-sulfonyloxaziridine 301
sulfoxidation 137, 277ff.
– alkane catalyzed by vanadium 214f.
– asymmetric 285
– enantioselective 285
– H
2
O
2
-based 287ff.
– ionic liquid 291
– Pt-catalyzed 285
– thioether in fluorinated alcohol solvent 136
– V-catalyzed 214f., 285
sulfoxide 283, 322, 409f.
supercritical carbon dioxide 343
superoxide dismutase (SOD) enzyme 372
superoxocobalt(III) complex 196
support
– bearing alkene 19
– nitrogen-group donating 16
– solid 63
t
TADOOH 326
TBHP 76
TEMPH 157
TEMPO (2,2
0
,6,6
0
-tetramethylpiperidine-N-
oxyl radical) 147ff., 165ff., 337, 354
TEMPOH (2,2
0
,6,6
0
-tetramethylpiperidine-N-
oxyl hydroxylamine) 156, 173
terephthalic acid (TPA) 194ff.
terminal oxidant 3, 41f., 62, 80
– alkyl hydroperoxide 295
– dioxygen 208
– environmentally friendly 3
– H
2
O
2
42, 280
– molecular oxygen 293
– sodium percarbonate (SPC) 60
terpyridine 74
testosterone 435
tetraazacycloalkane derivative 385
Index
j
463
a,a,a
0
,a
0
-tetrabromoxylene 218
tetra-n-butylammoniumperruthenate
(TBAP) 157
tetrahydrofuran lactone 103
tetrahydroquinoline 258
meso-tetrakismesitylporphyrin dianion (tmp)
160
N,N,N
0
,N
00
-tetrakis(2-pyridylmethyl)-1,2-
ethylenediamine (tpen) 406
N,N,N
0
,N
00
-tetrakis(2-pyridylmethyl)-1,3-
propanediamine (tptn) 405
tetralin 441
tetramethylammoniumhydroxide 153
7,8,15,16-tetraoxadispiro[5.2.5.2]
hexadecane 139
tetraphenylporphyrin (TPP) 49, 264
tetra-n-propylammoniumperruthenate
(TPAP) 157ff.
thioether 285
– sulfoxidation in fluorinated alcohol
solvent 136
thiol
– oxidation to disulfide 138
thiophene S-oxide 428
thiophenol
– oxidation to disulfide 138
ticlodipine 428
titanium
– asymmetric epoxidation 40
– di-m-oxo titanium complex 410
– oxidation 282
– oxo complex 282
– TiCl
4
-promoted reaction of N-cyanomethyl-
N-methylaniline 257
– Ti(O
i
Pr)
4
296f.
titanium silicalite TS-1 178
titanium(IV)-silicate catalyst (TS-1) 39, 79
TMSOOTMS 249
para-toluenesulfonic acid 136
p-toluic acid (PTA) 194ff.
o-toluic acid 194
TPA
– see terephthalic acid
– see trispicolylamine
– see tris(2-pyridylmethyl)amine
[(TPA)Fe(CH
3
CN)
2
](OTf)
2
(TPA¼
trispicolylamine) 67
TPAP ((n-Pr
4
N)(RuO
4
)) 249ff.
TPP (5,10,15,20-
tetraphenylporphyrinato) 49, 264
transition metal
– catalyst 280
transition metal-catalyzed epoxidation
– alkene 37ff.
transition state
– epoxidation 98
– spiro and planar 92
N,N,N-1,3,5-trialkylated flavin 289ff., 302
N,N,N,-3,5,10-trialkylated flavin 286ff., 304
tri-azacycloalkane derivative 385
1,4,7-triazacyclononane (TACN) 50, 374
– N-alkylated (TMTACN) 50
tricaprylylmethylammonium chloride 153
endo-tricyclo[5.2.1.0]decane 212
2,2,2-trifluoroethanol (TFE) 117ff., 134
trifluorotoluene (TFT) 190
1,4,7-trimethyl-1,4,7-triazacyclononane
(tmtacn) 374f., 405
– chiral tmtacn based ligand 394
N,N
0
,N
00
-trimethyl-1,4,7-
triazacyclononane 387
trispicolylamine (TPA) ligand 67
tris(2-pyridylmethyl)amine (TPA) 265
tris-pyrrolidine-1,4,7-triazacyclononane 394
tungstate-exchanged Mg-Al layered double
hydroxide (LDH) 303
tungsten
– epoxidation 42
– (n-hexyl
4
N)
3
[PO
4
(W(O)(O
2
)
2
)
4
]42
– g-[H
2
SiV
2
W
10
O
40
]
4
329, 342
– [{g-H
2
SiTi
2
W
10
O
38
}
2
(m-O)
2
]
8
compound 329
– Keggin-type silicodecatungstate
[g-SiW
10
O
34
(H
2
O)
2
]
4
44, 328f.
– [M
3
(H
2
O)
3
PW
9
O
37
]
6
334
– [M
4
(H
2
O)
2
P
2
W
18
O
68
]
10
319
– Ph
2
PO
2
[WO(O
2
)
2
]
2
281
– {PO
4
[WO(O
2
)
2
]}
3
327
– {PO
4
[W(O)(O
2
)
2
]
4
}
3
42
– PW
9
-Fe
2
Ni heteropolyanion 193
– [PW
12
O
40
]
3
327
– Q
3
PW
12
O
40
281
– Se-contaning peroxotungstate [SeO
4
{WO
(O
2
)
2
}]
2
– [TM(H
2
O)H
2
W
17
O
55
F
6
]
q
329
– Venturello-type peroxo complex Q
3
{(PO
4
)[W
(O)(O
2
)
2
]
4
}Q¼N-(n-C
16
H
33
) pyridinium
281
– W(VI) peroxo complex 177
– {[(WZn
3
(H
2
O)
2
][(ZnW
9
O
34
)
2
]}
12
320f.,
331ff.
– {[(WZnMn(II)
2
(H
2
O)
2
][(ZnW
9
O
34
)
2
]}
12
polyoxometalate 330
– {[(WZnMn
2
(H
2
O)
2
][(ZnW
9
O
34
)
2
]}
12
342f.
– WZnMn
2
(ZnW
9
O
34
)
2
2
281
– [WZnRu
2
(OH)(H
2
O)(ZnW
9
O
34
)
2
]
11
247,
267
464
j
Index
– {[(WZnTM
2
(H
2
O)
2
][(ZnW
9
O
34
)
2
]}
q
318,
330f.
u
urea/hydrogen peroxide (UHP) 55ff., 409
v
(þ)-valencene 437ff.
vanadium 175
– alkane sulfoxidation 214ff.
– enantioselective sulfoxidation 285
– VO(acac)
2
215f.
vanadyl acetylacetonate 3f.
vanadium-containing Keggin-type
polyoxometalate 333
vanadium-substituted polyoxomolybdate 321
vancomycin-type antibiotic 428
Venturello anion 46
Venturello catalyst 42f.
Venturello-type peroxo complex 281
verbenol 439ff.
(þ)-cis-verbenol 441
(þ)-verbenone 441
vinylcylohexane 340
vinylcylohexene 340
4-vinylcyclohexene 390
w
Wacker reaction oxidation
– terminal alkene 334
water oxidation center (WOC) 372
Wells-Dawson-type polyoxometalate 318
x
xanthene
– Mars–van Krevelen-type oxygenation 338
m-xylene 194
o-xylene 194
p-xylene (PX) 194ff.
y
ynone 204
z
zeolite
– NaY 63
Index
j
465