Schottky contacts
outdiffusion. An activation energy of 1.4 eV is associated with the
electrical degradation [8]. Thus, GaAs/Ti/Pt/Au interfacial reac-
tions show slight, if any, metallurgical differences with non-Au
contacts, but can have large electrical differences. The evidence
for Pt as an effective diffusion barrier is not compelling.
Metal reactivity with Ga or As is what drives the interfacial
reactions with GaAs. Examples of M/GaAs interfaces that react
at relatively low temperatures have been given (Au, Pt). A few
generalisations about M/GaAs reactions can give some insight,
though they are no substitute for a yet-to-exist complete pic-
ture. Stable end-reaction phases exist for many metals, which
provide a powerful driving force for interfacial reactions with
GaAs. Interfacial intermixing occurs readily at low temperat-
ures for many metals, affecting electrical properties, but also
providing reaction pathways. Reactions beyond the thin interfa-
cial layers depend on diffusion of M, Ga or As. Ga generally
diffuses faster than As, as seen in the GaAs/Pt, GaAs/Ti reac-
tions. Metals that diffuse faster than Ga, generally those with
weaker M-M bonds, react at relatively low temperatures. M-M
bond strength, in turn, generally correlates with the heat of vapour-
isation of the metal. Due to the lower mobility of As, M-As
phases tend to form at the original GaAs interface and the M-Ga
phases form above the M-As phases. For metals that do not dif-
fuse readily at low temperatures (<400
◦
C), GaAs decomposition
with Ga and As outdiffusion becomes important at higher temper-
atures. This outdiffusion is suppressed to the greatest extent by the
use of amorphous refractory metals. Complete characterisation of
M-GaAs reactions with intermediate and final phases is complex
and less easily generalisable.
Among refractory Schottky metal contacts, Mo, Ta and W
are stable at temperatures below 700
◦
C. Ta interfacial reactions
occur at 700
◦
C in seconds, while Mo and W interfacial reac-
tions occur between 750 and 800
◦
C. All of these metals show
strong polycrystalline signals in X-ray diffraction.
WSi and WSiN can be deposited as amorphous metals for
optimum composition. The optimum composition of tungsten
silicide is W
0.45
Si. For lower tungsten fractions, the film will
either contain crystalline W phases or recrystallise at lower-than-
optimum temperatures. For higher-than-optimum W composition,
the film recrystallises to form WSi
2
. For the optimum composition,
WSi remains amorphous up to about 850
◦
C. WSiN also remains
amorphous up to 850
◦
C and its recrystallisation is less strongly
dependent on composition. Other refractory metal alloys such as
WN and TiW are sometimes used as well. However, these films are
at least partially crystalline as deposited. At high enough temper-
atures, usually 900
◦
C and above, GaAs decomposition becomes
213