Confirming Pages
524 APPENDIX A Measurement Fundamentals
The seven base units we use to define mass, length, time, temperature, electric
current, amount of substance, and luminous intensity are the kilogram, meter, second,
Kelvin, ampere, mole, and candela. These units form the basis for the International
System of Units, abbreviated SI, from the French Le Systeme International d’Unites.
The kilogram is the only unit defined in terms of a material standard. It is
established by a platinum-iridium prototype in the laboratory of the Bureau des
Poids et Mesures in Paris. Unfortunately, the name kilogram is confusing since it
contains the prefix kilo, which conflicts with the SI prefixing conventions described
in Section A.1.1 .
The meter is defined as 1,650,763.73 wavelengths of the emission resulting
from the transition between the 2p
10
and 5d
5
electron energy levels of the krypton
86 atom. This atomic standard for the meter was proposed long ago by Maxwell
(1873) but not implemented until 1960. The earlier meter definition, the distance
between two scribed lines on a platinum-iridium bar, like the kilogram, required a
prototype for the definition. Now the practical measurement of the unit is deliber-
ately separated from the definition, making the definition independent of a unique
prototype. An alternative standard meter was defined in 1983 as the length of the
path traveled by light in vacuum during a time interval of 1/299,792,458 sec.
The second is defined as the duration of 9,192,631,770 periods of the radiation
corresponding to the transition between the two hyperfine levels of the ground state
of the cesium 133 atom. The definition of the second was previously based on the
mean solar second, which was defined as a fraction (1/86,400) of the earth’s daily
rotation. Irregularities in the earth’s rotation amounting to 1 or 2 seconds per year
limited accuracy.
The unit of absolute thermodynamic temperature is the Kelvin. The Kelvin scale
has an absolute zero of 0 K, and no temperatures exist below this level. There is a
misconception that all molecular motion ceases at this value. Actually, the molecular
energy is at a minimum. A standard fixed calibration point on the temperature scale
is the triple point of water, which is set at a value of 273.16 K to maintain consis-
tency with the Celsius scale. Although the Kelvin scale is established using only the
absolute zero and triple points, additional fixed points have been defined based on
the boiling and melting points of other materials. These points are useful when cali-
brating temperature measurement devices. Temperature in Kelvin and temperature in
degrees Celsius are related by the following equation:
T
C
T
K
273.15–=
(A.1)
where T
K
is the Kelvin temperature and T
C
is the Celsius temperature expressed in
degrees Celsius ( C). Note that the triple point of water is 0.01 C, corresponding to
273.16 K. The Celsius temperature scale is sometimes referred to as the centigrade
scale because it is calibrated to the 100 C temperature interval between the freezing
point of water (0 C) and the boiling point of water (100 C). An interval or differ-
ence of temperature (Δ T ) has the same value in both the Celsius and Kelvin scales
(Δ T
C
Δ T
K
).
The ampere is defined as the constant current that, if maintained in two straight
parallel conductors of infinite length and negligible circular cross section and placed
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