Firing characteristics
69
atmosphere and protected to some extent against extreme temperature. Pots
whose cores are black or dark grey probably contain carbon derived from
the incomplete burning of organic material in the fabric. As this carbon is
burnt it will take oxygen and this can lead to local reduction of the fabric
and hence a grey colour. As firing continues, however, oxygen in the kiln
atmosphere may oxidise the core leading to the development of brown and
red colours. Next one describes the margins of the pot, that is the zones
between the core and the surfaces, if there are any differences between them
and the core. No difference between core and margins may indicate either
that firing conditions were held long enough for the fired vessel to reach an
equilibrium, or (with some grey and black fabrics) may indicate a very short
firing. If the inner and outer margins are of different colour, this may suggest
that the mouth of the pot was closed in some way, perhaps by being fired
inverted on the kiln floor or as part of a stack of
vessels.
Finally, the colour
of the surfaces of the pot are described, if different from the margins. A
difference between surface and margin colour suggests a short-lived change
in firing conditions; perhaps the kiln was opened up whilst the pottery was
still hot, allowing oxygen to rush in. This would produce a browner or
redder surface. Deliberate reduction can be achieved by throwing green
timber onto the fire at the end of the firing, giving rise to vessels which might
have oxidised margins and cores but reduced, and therefore greyer, surfaces.
For any one pottery fabric the colour range will be dependent on firing
conditions, the iron content of the clay and the way in which the iron is
distributed within the clay (that is, does it occur as discrete inclusions or is it
bound to clay minerals and is it already in an oxidised state?). Therefore, if
one knows that the fabric is from the same clay source then changes in
colour must be directly related to changes in firing. For fully oxidised wares
a rough estimate of firing temperature can be obtained by retiring samples at
known temperatures for a standard time. Conversely, if samples of
different
fabrics are refired at the same temperature and conditions then their result-
ing colour will be related directly to difference in iron content between the
fabrics.
Hardness
The hardness of materials can be measured in a variety of means but in
pottery studies the most commonly used means is Mohs' hardness scale, or a
simplification of it (see p. 138). A pot's hardness is determined by attempting
to scratch the pot surface with progressively harder materials, starting with
talc and ending with diamond. The hardness is defined by the number of the
material which just failed to scratch the surface. Hardness provides a rough
indication of firing temperature and may be of value in the classification of
high-fired wares, such as stonewares and porcelains, but it is rarely a deter-
mining feature in the classification of fabric groups.