276 7 Tool Life Behaviour
amounts of Si, Mo, V, Nb, Ti, Al or Co (e.g. X5CrNi18-10, material no.: 1.4301;
X6CrNiMoTi17-12-2, material no.: 1.4571). They are not magnetic and cannot be
hardened by means of heat treatment. In an annealed state, they are characterized by
very good toughness properties which are retained even at extremely low tempera-
tures. Especially given a high carbon content, they tend when cold-formed towards
considerable strain hardening. Through cold-forming, therefore, their strength val-
ues can be increased dramatically. When strain-induced martensite forms, however,
the strain is reduced to a very considerable degree.
Among the products made from the abovementioned corrosion-resistant steels
are household devices, razor blades, knives, surgical instruments, parts for automo-
bile construction, agricultural and materials handling technology, mechanical and
plant engineering and devices and instruments for the food industry, the chemical
industry, the textile industry and for shipbuilding [Stah01].
A further group of corrosion-resistant steels are the ferritic-austenitic steel
materials, also either referred to as duplex steels (e.g. X2CrNiMoN22-5-3, mate-
rial no.: 1.4462) or super duplex steels (e.g. X2CrNiMoCuWN25-7-4, material
no.: 1.4501). The name “duplex” refers to their two-phase crystalline structure con-
sisting of ferrite and austenite. These steels have optimal properties at a balanced
ferrite/austenite ratio of approximately 50/50%. In comparison to normal austenitic
steels, the duplex steels contain less nickel (about 4–8%), though usually a
significantly higher amount of chromium (about 18–25%). In order to increase their
resistance to intercrystalline corrosion, a certain amount of nickel is exchanged
for additional nitrogen as an austenite former and molybdenum. The optimal
microstructure is created by means of a heat-treatment at 1000–1100
◦
C. These steels
find the most use in the gas and oil industry, in the petrochemical industry, in chem-
ical tankers and in sewage treatment plant construction. In comparison to austenitic
rustproof steels, the duplex materials have a strain limit which is almost double as
high (R
p0,2
about 400–550 MPa) given similar or markedly higher strength values.
Heat-resistant steels are mainly ferritic and austenitic steels with a high resis-
tance against oxidation as well as against the influence of hot gases and combustion
products above 550
◦
C. As a rule, the heat-resistant ferritic steels contain at least
12% chromium as well as aluminium and silicon (e.g. X10CrAlSi13, material
no.: 1.4724; X10CrAlSi25, material no.: 1.4762). Heat-resistant austenitic steels
are additionally alloyed with at least 9% nickel (e.g. X8CrNiTi18-10, material no.:
1.4878; X15CrNiSi25-21, material no.: 1.4841). These steel types are used, for
example, in ovens and apparatus construction for annealing bells, baskets and tubes
[Stah01].
The high-temperature steels are mainly martensitic and austenitic steel types
with a high long-time rupture strength with a long-term mechanical strain above
500
◦
C. Among the products made from high-temperature martensitic steels (e.g.
X20CrMoV11-1, material no.: 1.4922; X20CrMoWV12-1, material no.: 1.4935)
are components for thermal power plants, steam boilers and turbines, as well as for
the chemical industry and nuclear technology. High-temperature austenitic steels
(e.g. X6CrNi18-10, material no.: 1.4948; X5NiCrTi26-15, material no. 1.4980) are
used in the construction of pressure vessels and armatures, pressure tanks and steam