Heitjans P., Karger J. (Eds.). Diffusion in Condensed Matter: Methods, Materials, Models
Подождите немного. Документ загружается.
Index
acoustic microscopy 466
activation energy 19, 344, 813
activation enthalpy 18
activation volume 19, 40, 268
adsorbate-adsorbate interactions 288
Ag/Ag(111) 320
0.5Ag
2
S·0.5GeS
2
877
0.3Ag
2
SO
4
·0.7AgPO
3
884
alloys
binary 49, 53
ordered 78
aluminium 39, 77
amino acid 729
amorphous alloys 259
anomalous diffusion 417–421, 428,
434, 441, 448, 479, 488, 731, 797,
803, 806, 867, 904
anticorrelation in anomalous diffusion
801
antiphase boundaries 77
antistructure defects 71, 72, 78
antistructure-bridge mechanism 46,
81
Arrhenius law 18, 289, 746, 753, 813,
925
association degree 220
asymmetric double well potential
(ADWP) model 836, 866, 888
Auger electron spectroscopy (AES)
14
autocorrelation function 817, 920, see
also correlation function
electric field 625
light intensity 625
orientation 636
average
ensemble 919, 923
time 923
β-NMR
method 380–384
relaxation 370, 383, 384, 403, 407,
409
spectrometer 383
β-radiation asymmetry 383
β-relaxation 520
β-titanium 77
B2 structure 71, 72, 76, 78
backbone of percolation cluster 900
BaF
2
394
ballistic diffusion 867
binary intermetallics 42
binary non-electrolyte mixtures 573
blocking factor 104, 150
Bloembergen-Purcell-Pound (BPP)
behaviour 369, 819
body-centered cubic metals 34
Boltzmann-Matano method 49, 294,
498
bond percolation 901
Boson peak 520
Bragg equation 108
Brillouin lines 581, 604
Brownian dynamics simulation method
687
Brownian motion 472, 632, 717, 794
CaF
2
391
caloric glass transition temperature
255
capacitance 907
capillary electrophoresis 738
cation sublattice 209
central limit theorem 420, 423, 625,
799
charge diffusion coefficient 126, 127,
148
956 Index
charge of transport 222, 238
chemical diffusion 6, 49, 556
chemical diffusion coefficient 231
chemical potential 8, 226, 291, 918,
941
Chudley-Elliott model 69, 71, 102,
130, 149, 150
cobalt oxide 217
CoGa 82
coherent diffuse scattering 153
coherent quasielastic scattering 149
coherent scattering function 102, 150
collective diffusion 495, 641, 648, 747,
772
coefficient of 289, 646, 771, 778
colloidal rods 666
colloidal spheres 676
colloidal systems 619
collective diffusion 641
interdiffusion 651
rotational diffusion 658
self-diffusion 637
component diffusion coefficient 10
compressibility, isentropic 607
computer simulations see simulations
concept of mismatch and relaxation
(CMR) 867, 874
conductivity
electrical 219, 905, 906
frequency dependence 768, 861
thermal 597
conductivity spectroscopy 861
continuity equation 5
continuous time random walk model
824
continuum percolation 902
copper 77
correlated jumps 118, 124, 127, 858
correlation effects 127
correlation factor 19, 222, 773, 816,
848
correlation function 369, 515, 525,
527, 582, 915, 916, 919–921, 923
long-time tail 633
of coverage 291
of current density 864
Van Hove 66, 96, 98, 921, 935, 937
velocity auto- 928, 930
correlation length 897
correlation technique 582–587
correlation time 369, 586, 832
correlator 594
Coulomb interaction 215, 819, 830
Coulomb lattice gas 820, 840
Coulomb trap 835
counterion model 835, 866
coupled diffusion in B2 intermetallics
44
coupling concept 866
coverage 290
critical fluctuation 295
fluctuation 290, 293
step 299
Co-Zr glasses 268
critical concentration 896, 901, 902
critical dimension 808
critical exponent 897, 905
critical percolation path 832
critical slowing down 600, 650, 703
critical-path approach 763
cross coefficients 236
crossover time 905
Cu
3
Au rule 47
current density autocorrelation function
864
D0
3
structure 84
Darken equation 51, 296, 433, 557,
562, 573, 941
Darken-Manning relation 52
Darwin width 110
dc conductivity plateau 862
de Broglie wavelength 99, 919
Debye length 720
Debye-H¨uckel-Onsager-Falkenhagen
effect 859
Debye-Waller factor 67, 70, 74, 99,
113, 119, 138
defect chemistry 210
defect cluster 226
defect structure 210, 215
demixing 234, 236, 240, 703
density distribution 931
detailed balance 71, 767, 786
dichalcogenides 386
dielectric loss 835, 863
Index 957
differential effective-medium theory
849
diffusant 6
diffuse scattering 76
diffuser 6
diffusion
ambipolar 227
anomalous 417–421, 428, 434, 441,
448, 479, 488, 731, 797, 803, 867
cation 217, 224
chemical 226
collective 495, 641
continuous jump 371
correlated diffusion anisotropy
431–432
effective diffusivity 428
experimental methods 10
field-assisted 717
in aluminium 39
in amorphous alloys 262
in B2 intermetallics 44, 78
in bcc metals 35
in D0
3
intermetallics 84
in fcc metals 33
in gallium arsenide 184
in germanium 183
in L1
2
intermetallics 49
in lead 41
in liquids 251
in membranes 471
in nickel 31
in niobium 28, 29
in polymers 447, 519, 531, 675, 733,
843
in regular pore networks 427
in semiconductors 165
in silicon 166
in silver 38
in zeolites 427, 925
interstitial-substitutional 168
intracrystalline self-diffusion 429,
430, 445
isotope effects 13, 30, 253, 265, 272
lateral 477, 493
long-range 133
low-dimensional 371
molecular mechanism 132
multicomponent 427
mutual 556, 569, 600
normal 417–420, 426, 435, 450, 479,
555, 777, 798, 799
on percolation clusters 904
oxidation-enhanced 174
oxidation-retarded 174
oxygen 222, 223
pressure dependence 18
proton diffusion 131
reactive 54
rotational 477, 491, 635
single-file diffusion 434–437, 775
solute diffusion 35
solvent diffusion 35
surface diffusion 285, 302, 339
through membranes 500
transport diffusion 432–434, 943
diffusion coefficient 904, 921, 929, 931,
941
chemical 6, 8, 151, 227, 244
collective 289, 646, 780
distinct-diffusion 570, 571
foreign atom 8
frequency dependence 762
impurity 8
in grain boundaries 338
interdiffusion 654
self-diffusion 7
Stokes-Einstein 630
thermodynamic 561
tracer 7, 219, 286, 478
transport 941
vacancy 231
diffusion coefficient tensor 4, 439, 676
diffusion entropy 18
diffusion equation 5, 289, 494, 632,
752, 798, 928, see also Fick’s
second law
error function solution 6
source solution 230
thin-film solution 5
diffusion length 5, 479
diffusion mechanisms 23
diffusion-limited reaction 806–808
diffusional line broadening 70, 72, 94
diffusivity 4
effective 41, 170, 348, 420, 429, 453
thermal 597
958 Index
diffusivity tensor 4, 439, 676
direct current NMR (DCNMR) 718,
725
disorder models 753, 820
disordered solids
homogeneously 402
inhomogeneously 367, 390
disordered systems 372, 746, 753, 813,
857, 895
dispersive transport 822
dissociative mechanism 26
distribution of site energies 257
divacancy mechanism 25
dopant diffusion 172, 235
Doppler drive 111
double differential scattering cross-
section 95
drift flux 230, 232, 236
drift velocity 237, 717–720
dynamic conductivity 817
dynamic light scattering (DLS) 579,
589–597, 624
coherence 593
dynamic percolation 846
dynamic rotational disorder 153
dynamic structure factor 94, 521–526,
531, 538, 545, 568, 626, see also
scattering function
distinct 628
self- 628
dynamic structure model 840
effective activation energy 273
effective charge 236, 239
effective diffusivity 41, 170, 348, 420,
429, 453
effective-medium approximation 746,
758, 762, 912
self-consistency condition 761, 787
Einstein diffusion coefficient 8
Einstein relation 227, 420, 434, 555,
717, 903, 920
Einstein-Debye relation 635
Einstein-Smoluchowski relation 19,
see also Einstein relation
elastic incoherent structure factor
(EISF) 98, 119, 138, 139, 141
electric potential 226, 236
electric potential gradient 228
electro-osmosis 726, 737
electrochemical potential 226
electrokinetic potential 720
electrolyte solution 566, 574
electron hole 211, 212
electron microprobe analysis (EMPA)
14
electrophoresis 718
electrophoretic NMR (ENMR) 717
elementary diffusion step 65, 66, 68
encounter model 124, 128, 370
energy resolution 98
ensemble
canonical 917
microcanonical 917
entanglements 513, 531, 543
enthalpy of migration 22
entropic forces 529
entropy of migration 22
equivalent circuit model 906
error function solution 6
escape rate 121
eucryptite 405
excess charge 210, 228, 231
excess volume 269
exchange mechanism
interstitial-substitutional 26
ring 127
face-centered cubic metals 32
fast solute diffusion 40
FeAl 78
Fe
3
Al 80
Fermi level effect 172
Fe
3
Si 84
Fick’s first law 4, 494, 559, 798
non-local 643
Fick’s second law 5, 6, 165, 494, 752
field-assisted diffusion 717
Fisher model 337, 338
five-frequency model 36, 233
fixed-window method 113
fluctuation-dissipation relation 632
fluorescence correlation spectroscopy
(FCS) 669
fluorescence recovery after photo-
bleaching (FRAP) 481, 497,
661
forced Rayleigh scattering 613
Index 959
Fourier time window 100, 106
fractal 793
chemical kinetics 806
fractal dimension 446, 793, 897, 898,
904
fractional Brownian motion 794
fragile glass 254
fragile supercooled melt 880
Frank-Turnbull mechanism 26, 168
free induction decay (FID) 376, 400
free-volume model 253, 486
Frenkel
defects 211
equilibrium 210, 212
Γ -space 918
generalized force 919
Gibbs free energy of activation 19
Gibbs free energy of binding 24
Gibbs free energy of migration 22
glass
electrolyte 403
ion-conducting 402, 819
metallic 259
oxide 403, 405, 884
glass transition 255, 272, 519, 638
Gorski effect 16
grain boundary 337
diffusion coefficient 338
in nanocrystalline materials 352,
390, 391
large-angle 345, 346
segregation 339, 353, 357, 361
segregation energy 353
segregation factor 339, 353
small-angle 345, 346
width 338, 343, 911
grain boundary diffusion 337
activation energy 344
anisotropy 345
Arrhenius law 344
atomistic mechanisms 347, 362
comparison with bulk, surface, liquid
344
empirical rules 344
in intermetallic compounds 361
in moving boundaries 362
kinetic regimes 347
orientation dependence 346
Green-Kubo relation 495, 568, 638,
920
Grotthuß mechanism 131
growth constant 54
gyromagnetic ratio see magnetogyric
ratio
Harrison’s classification 348
Hart’s formula 349
Hartley-Crank relation 557
Hausdorff dimension 793
Haven ratio 127, 137, 148, 817, 865
Henry isotherm (of grain boundary
segregation) 358
heterodyne technique 587
homodyne technique 587
hopping rate see jump rate
H/Si(111) 308
Huang scattering 119, 153, 155
hybrid solutes 41
hydrodynamic function 678
hydrodynamic interaction 637, 659
hydrogen bond 131
hydrogen diffusion 29, 115
immobile (trapped) state 121
impedance spectroscopy 861
impurity diffusion
in grain boundaries 339
in metals 35, 77
in oxides 216
in semiconductors 168, 172, 177,
182, 183, 196
impurity diffusion coefficient 8
impurity-vacancy binding 219
impurity-vacancy pair 233, 239
incoherent scattering function 97–99,
102, 133, 141, 154, 818
incoherent structure factor see
incoherent scattering function
infinite percolation cluster 896
intercalation 367
intercalation compounds 384
graphite 384
titanium disulfide 386
interdiffusion 6, 49, 187, 263, 556, 651,
654
interdiffusion coefficient 6, 8, 191, 654
interfacial region 50, 352, 367, 390
960 Index
diffusion in 392, 908
intermediate dynamic structure factor
521
intermediate scattering function 73,
95, 100, 523, 818, 828
internal interfaces 360, 367
density of 367
interstitial cation 213, 217
interstitial diffusion 27, 242, 745
interstitial impurities 165
interstitial mechanism 23
interstitial-substitutional exchange
mechanism 26
interstitialcy mechanism 25
intrinsic diffusion coefficient 10
inversion-recovery experiment 378
ion-conducting glasses 402, 819, 861
ion-conducting materials 861
ion-conducting polymers 843
ionic conductivity 126, 224, 817, 861,
908
ionic mobility 717, 729, 737
ionic self-diffusion coefficient 717, 729
irreversible processes 564, 919
isotope effects 13, 30, 253, 265, 272
Jonscher power law 863, see also
universal dielectric response
jump length 7, 20, 105, 866, 903
jump rate 19–23, 65, 70–73, 124, 233,
373, 763, 866
jump relaxation 823, 866
jump vector 20, 65, 67, 68, 102, 140
kick-out mechanism 26, 168
kink atoms 286
Kirkendall effect 10, 51
opposite 263
Kirkwood-Buff theory 575
K
2
O·2BaO·4SiO
2
885
Kohlrausch behavior 255, 521, 866
Kohlrausch-Williams-Watts (KWW)
behavior see Kohlrausch
behavior
Kr¨oger-Vink
diagram 214
notation 210
Kubo formula 817, 941
Lamb-M¨oßbauer factor 67
Landau-Placzek ratio 582, 606
Langevin equation 530, 632
Langmuir-Hinshelwood reaction 808
lanthanum gallate 216, 225, 235
Laplace transformation 644, 760
Larmor condition 421
Larmor precession 74, 516
Larmor precession frequency 369, 814
layer-crystalline materials 367
LiC
6
,LiC
12
384
LiCl·4D
2
O 403
LiCl·7H
2
O 881
line broadening in M¨oßbauer spec-
troscopy 68
line broadening in neutron scattering
68, 94
line narrowing in neutron scattering
104, 151
line narrowing in nuclear magnetic
resonance 374
linear response theory 150, 567, 858,
919
0.3Li
2
O·0.7B
2
O
3
884
lipid 473
lipid bilayer 475
lithium 370
lithium aluminosilicates 405
lithium intercalation compounds 384
lithium ion conductors 390
lithium niobate 394
lithium oxide 399
lithium titanium disulfide 386
local reptation model 538
localized motion 106, 134, 405, 528,
887
Longini mechanism 26, 193
low energy electron diffraction (LEED)
304
low energy electron microscopy (LEEM)
305
macroscopic diffusion methods 11–15,
65, 368
magnetic field gradient 421, 720
magnetic relaxation methods 16
magnetite 217, 231
magnetogyric ratio 369, 375, 517, 720
majority defect 213
Index 961
Mandelbrot dimension 793
Markovian process 70, 749, 802, 804
mass action law 25, 40, 211, 807
master curves of ionic conductivity
863
master equation 102, 748, 772
McLean’s isotherm 358
mean residence time 7, 17, 21, 68,
70–72, 80, 127, 322, 369, 816
mean square displacement 20, 252,
286, 418–449, 478, 516, 531, 555,
629, 751–777, 799, 816, 826, 868,
903, 929
long time tail 761
mean-field theory 808
mechanical relaxation methods 16
mechanical sectioning technique 11
membrane 441, 471, 733
biological 145, 473
lateral diffusion 477
polypropylene 441
transverse diffusion 500
memory effect 117, 127, 632, 643
mesoporous materials 437–439
MCM-41 438
metallic glasses 264
metalorganic chemical vapor deposition
(MOCVD) 187
Meyer-Neldel compensation rule 835
micelles 736
microemulsion 737
microporous materials 427, 925
microscopic diffusion methods 15–17,
65, 368
minority defect 212, 213
mismatch relaxation 866
mixed alkali effect 840
mixed conductor 216
mobility of ions 717, 729, 737
mode coupling theory 256, 275, 691
molecular beam epitaxy (MBE) 187
molecular dynamics simulations 118,
480, 534, 916, 922–925
molecular traffic control 437
molten salt mixtures 566
Monte Carlo simulations 325, 491,
759, 815, 821, 830, 836, 840, 909,
917, 922
M¨oßbauer spectroscopy 65–68
motional narrowing of NMR lines
374, 393, 395
moving grain boundary 362
multifractal 797
multiphase diffusion 53
multiple scattering 115, 135, 528
muon 30
muon spin resonance (µSR) 31
mutual diffusion 556, 569, 600
nanocrystalline BaF
2
394
nanocrystalline CaF
2
391
nanocrystalline composites 399, 908
nanocrystalline LiNbO
3
394
nanocrystalline LiTiS
2
397
nanocrystalline materials 352, 367,
390
Na
3
PO
4
154
nearly constant loss (NCL) behaviour
814, 835, 863, 888
Nernst field 227
Nernst-Einstein equation 126, 131,
817, 865, 880, 904
neutron backscattering (BSC)
spectrometer 106, 109, 111
neutron capture 382
neutron scattering 65, 68, 93, 514, 817
neutron spin-echo (NSE) spectrometer
519, 520
neutron spin-echo (NSE) spectroscopy
74, 516, 518
neutron time-of-flight (TOF) spectrom-
eter 106, 114
NiGa 82
Ni
3
Sb 86
NMR 368, 417, 717
correlation function 369, 818
correlation time 369, 373, 830
flow measurements 720
linewidth 373
PFG diffraction pattern 424–425
PFG effective observation time 426
PFG observation time 418, 421,
426, 427, 449, 455
pulsed field gradient (PFG) technique
417, 421–427
relaxation 369, 426, 814
relaxation techniques 375–380
962 Index
spectral density 369, 409, 818
spectrometer 379
spin echo 378, 379, 421, 721
spin-alignment echo technique 390
spin-echo attenuation 422, 424, 426,
440, 452
spin-locking experiment 378
static field gradient (SFG) technique
427
non-Arrhenius behaviour 767, 832
non-stoichiometric oxide 210, 219
normal diffusion 417–420, 426, 435,
450, 479, 555, 777, 798, 799
nuclear
magnetization 375, 421
methods in diffusion 16, 65, 368
polarization 380, 404
reactions for polarized β-emitters
381
spin-lattice relaxation 369
nuclear magnetic relaxation see NMR
relaxation
nuclear magnetic resonance see NMR
nuclear reaction analysis (NRA) 15
nuclear resonance scattering (NRS)
65
Onsager reciprocity relation 566, 919
Onsager regression hypothesis 579
Onsager transport coefficient 226, 566
O/Si(111) 307
O/W(110) 295
oxygen activity 209
oxygen deficit 211
oxygen excess 211
oxygen ion conductor 216
oxygen partial pressure 209
oxygen potential gradient 228
oxygen sublattice 209
paddle-wheel mechanism 153
pair correlation function 251, 575
particle distribution function 917
partition function 915, 919
Pb/Si(111) 313
percolation
bond 901
continuum 902
interface 908
site 895
percolation cluster 897
conductivity of 905
diffusion on 904
percolation model 755, 820, 895
percolation threshold 896
permeation 500
perovskite structure 225
petalite 405
phenomenological coefficient see
Onsager transport coefficient
phonon dispersion 125
phonon spectroscopy 77
photon correlation spectroscopy 579
plasma parameter 822
Poisson process 803
polarized neutron capture 382
polybutadiene 519, 528
polydimethylsiloxane (PDMS) 440,
443, 453, 531
polyethylene oxide (PEO) 451, 843
polyethylethylene (PEE) 453
polyisobutylene 528
polyisoprene 528
polymer
blends 697
diblock copolymer 453
electrolytes 843
reptation 449, 450
triblock copolymer 450, 451
polymeric systems 619
polypropylene membrane 441
polypropylene oxide (PPO) 451
polystyrene (PS) 440
polyvinylether 528
potential 922, 927
chemical 226
electric 226, 236
electrochemical 226
Lennard-Jones 923, 927, 932
square well 922
pre-exponential factor 18
pressure dependence of diffusion 268
principal diffusivities 4
propagator 419, 420, 422, 424, 429,
435, 798, 802, 928
mean 422–424, 935
proton conduction 139
Index 963
proton pump 146
proton tunneling 123
protonic conductor 131
pseudo Fermi level 782
pulsed field gradient (PFG) NMR
417, 421–427, 720
quantum diffusion 30
quasi-vacancies 261
quasielastic coherent structure factor
154
quasielastic helium scattering 293
quasielastic incoherent neutron
scattering (QINS) 136
quasielastic incoherent structure factor
141, 154
quasielastic light scattering 620
quasielastic linewidth 103, 105, 124,
151
quasielastic M¨oßbauer spectroscopy
67, 68
quasielastic methods 65, 66, 68, 73
quasielastic neutron scattering (QENS)
67, 68, 93
observation function 100, 105
observation time 100, 105, 133
observation volume 105
resolution function 105
radiotracer sectioning method 217,
340, see also tracer method
random barrier model 753, 867
random phase approximation 699
random trap model 754
random walk 747, 802, 806, 858, 865,
903
randomly blocked sites 755, 765
Rayleigh line 581
RbAg
4
I
5
878, 890
reaction constant 806
reaction rate 120, 143
reactive diffusion 54
reflection high energy electron
diffraction (RHEED) 324
renewal theory 847
reptation
crossover 543
diffusion 537
model 514, 537–540, 543
residence time see mean residence
time
residual activity method 217
rotational diffusion 138, 491, 635, 658
Rouse model 514, 529–536, 844
generalized 538
rubber-like model 538
Rutherford backscattering spectrome-
try (RBS) 14
scanning tunneling microscopy (STM)
306
scattering amplitude 622
scattering cross section 95
scattering function 94, 149, 523, 921
scattering length 95, 101
scattering strength 621
scattering vector 93
Schottky
defects 211
equilibrium 210, 224
secondary ion mass spectrometry
(SIMS) 13, 222
sedimentation 647
sediments 446–447
segregation 234
self-affine fractal 797
self-correlation function 66–76, 97,
102, 419
self-diffusion 31, 121, 127, 136, 144,
152, 370, 555, 557, 637, 943
self-diffusion coefficient 7, 120, 128,
135, 147, 152, 216, 227, 659
self-interstitial charge state 166
self-similarity 795, 897
short-range order 260
Siegert relation 584, 626
Sierpinski fractal 794
silicon self-diffusion 166
simulations
molecular dynamics (MD) 925, 941
Monte Carlo (MC) 815, 821, 915,
922
Sinai model 746, 769
single-file diffusion 434–437, 775
site energy
disorder 747
exponential distribution 766, 781
site exclusion model 771
964 Index
site occupancy 104, 150
site percolation 895
six-jump cycle mechanism 46, 81
Smoluchowski equation 675
Smoluchowski theory 807
Snoek effect 16
soft phonon modes 77, 86
solid rotator phase 156
solid-state protonic conductor 131
solute diffusion 35
solute-vacancy pair 215, 220
solvent diffusion 35
Soret effect 606
sound attenuation 604
sound velocity 461, 604
specific surface area 446
spectral density 921
spin diffusion 382, 400, 403
spin echo
neutron 74, 516
NMR 378, 379, 421, 721
spin incoherent scattering 115
spin-lattice relaxation 369, 818
disorder effects 372
frequency dependence 372, 386,
387, 398, 407
homogeneous 404
inhomogeneous 404
laboratory frame 377, 409
low-dimensionality effects 372
rate 370
rotating frame 379, 409
spin-spin relaxation 378, 409
spinel 217
spodumene 405, 406
sputter sectioning technique 12
SrCl
2
128
static field gradient (SFG) NMR 427
static structure factor 95, 150
stochastic process 800
stoichiometric point 212, 216, 228
Stokes-Einstein diffusion coefficient
630
Stokes-Einstein equation 254, 601,
660, 719
Stokesian dynamics simulation method
689
strain field 119, 130, 153
stretched polymers 849
structural relaxation 260
structure factor 153, 298, 919
dynamic 521–526, 921, 937
partial 652
static 918, 921
subdiffusive behaviour 417, 421, 801,
867
substitutional impurities 165
Summerfield scaling 863, 866
superlattice disordering 187
surface diffusion 285, 339
equilibrium measurements 297
non-equilibrium measurements 313
step 302
terrace 302
surface exchange coefficient 222
surface light scattering 608
surface tension 608
surface-to-volume ratio 444–447
synchrotron radiation 65, 73
thermal conductivity 597
thermal diffusivity 597
thermal grating 613
thermodynamic factor 10, 227, 243,
562
time correlation function 567, 920, see
also correlation function
time-dependent correlation factor 867
time-domain interferometry 76
time-temperature superposition
principle 863, 866
titanium 65, 77
titanium disulfide 386
topological distance 900
tortuosity 443, 454, 731
total scattering cross section 102
tracer diffusion 7, 230, 745, 771, 773,
816
tracer diffusion coefficient 7, 286
tracer method 11
tracer self-diffusion coefficient 7
transference number 227, 719, 729
transition rate 746, see also jump rate
transition state theory 943
transport coefficient 919–921, see also
Onsager transport coefficient
transport diffusion 432–434, 556, 943